The first one-dimensional heteropoly tungstovanadate coordination polymer: [(VVO4)W8VIM4 O36(VIVO)2]n- (M = 0.71VIV + 0.29WVI, n = 4.68)

Inorganic Chemistry Communications

Volumn 5, Issue 11, 2002, Pages 996-999

  Shivaiah, Vaddypally ^a   Hajeebu, Swapna ^a   Das, Samar K ^a  

^a UNIVERSITY OF HYDERABAD   (India)

Author keywords

One dimensional chain; Polyoxometalate; Reduction; Tungstovanadate heteropoly complex

Indexed keywords

AMMONIUM ACETATE; BUFFER; DITHIONITE; ION; POLYMER; TUNGSTEN DERIVATIVE; TUNGSTOVANADATE; UNCLASSIFIED DRUG; VANADIC ACID;

ACIDITY; AQUEOUS SOLUTION; ARTICLE; CHEMICAL ANALYSIS; COMPLEX FORMATION; CRYSTAL STRUCTURE; HEATING; HIGH TEMPERATURE; INFRARED SPECTROSCOPY; INORGANIC CHEMISTRY; OXIDATION REDUCTION REACTION; REACTION ANALYSIS; STRUCTURE ANALYSIS; TITRIMETRY; X RAY CRYSTALLOGRAPHY;

EID: 0036828339     PISSN: 13877003     EISSN: None     Source Type: Journal    
DOI: 10.1016/S1387-7003(02)00621-4     Document Type: Article

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23. IV centers) determined was 5 ± 0.2. Note: In the synthesis, small amount of block-shaped crystals appeared along with the needle-shaped crystals of 1. These blockshaped crystals were separated mechanically from the needleshaped crystals. The elemental analysis of these crystalline blocks were different from 1. Temperature less than 100 °C favors the formation of these block-shaped crystals.
24. int = 0.0248) were used. The structure was solved using SHELXS-97 [26] and refined using SHELXL-97 [27] to R1 = 0.0488, wR2 = 0.1318 for 2283 reflections with I > 2σ(1). Further details of the crystal structure determination may be obtained from the Fachinformationszentrum Karlsruhe, 76344 Eggenstein-Leopoldshafen, Germany, on quoting the depository no. CSD391193.
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