Organizational forms of matter: An inorganic super fullerene and keplerate based on molybdenum oxide

Angewandte Chemie - International Edition

Volumn 37, Issue 24, 1999, Pages 3359-3363

  Müller, Achim ^a   Krickemeyer, Erich ^a   Bögge, Hartmut ^a   Schmidtmann, Marc ^a   Peters, Frank ^a  

^a BIELEFELD UNIVERSITY   (Germany)

Author keywords

Cage compounds; Clusters; Fullerenes; Polyoxometalates; Supramolecular chemistry

Indexed keywords

FULLERENE DERIVATIVE; MOLYBDENUM;

ARTICLE; CHEMICAL STRUCTURE; CHEMISTRY; CRYSTALLIZATION; MACROMOLECULE;

EID: 0033521684     PISSN: 14337851     EISSN: None     Source Type: Journal    
DOI: 10.1002/(sici)1521-3773(19981231)37:24<3359::aid-anie3359>3.0.co;2-j     Document Type: Article

References (14)

1. 2O molecules); 2) the possibility of an easy structural change of the building units, of the uptake of hetero atoms, of the formation of larger and variably linkable fragments (especially with energetically low-lying unoccupied molecular orbitals), of a template-driven structure formation, of the generation of defects in reaction intermediates (with the consequence of different types of linking), of the localization and delocalization of valence electrons in different ways and the variation and control of the charge (for example by protonation, electron transfer reactions, and substitution of certain building units), b) In this context a novel (polyoxometalate) nucleation growth process has even been discovered inside a ring-shaped cluster compartment (A. Müller, S. Q. N. Shah, H. Bögge, M. Schmidtmann, Nature, in press). Aspects of related limited growth have been discussed: P. Ball, Nature 1998, 395, 745-748.
2. 2O molecules); 2) the possibility of an easy structural change of the building units, of the uptake of hetero atoms, of the formation of larger and variably linkable fragments (especially with energetically low-lying unoccupied molecular orbitals), of a template-driven structure formation, of the generation of defects in reaction intermediates (with the consequence of different types of linking), of the localization and delocalization of valence electrons in different ways and the variation and control of the charge (for example by protonation, electron transfer reactions, and substitution of certain building units), b) In this context a novel (polyoxometalate) nucleation growth process has even been discovered inside a ring-shaped cluster compartment (A. Müller, S. Q. N. Shah, H. Bögge, M. Schmidtmann, Nature, in press). Aspects of related limited growth have been discussed: P. Ball, Nature 1998, 395, 745-748.
3. See A. Müller, F. Peters, M. T. Pope, D. Gatteschi, Chem. Rev. 1998, 98, 239-271.
4. A. Müller, J. Meyer, E. Krickemeyer, C. Beugholt, H. Bögge, F. Peters, M. Schmidtmann, P. Kögerler, M. J. Koop, Chem. Eur. J. 1998, 4, 1000-1006; A. Müller, S. Dillinger, E. Krickemeyer, H. Bögge, W. Plass, A. Stammler, R. C. Haushalter, Z. Naturforsch. B 1997, 52, 1301-1306; M. I. Khan, J. Zubieta, Progr. Inorg. Chem. 1995, 43, 1-149; H. K. Chae, W. G. Klemperer, T. A. Marquart, Coord. Chem. Rev. 1993, 128, 209-224.
5. A. Müller, J. Meyer, E. Krickemeyer, C. Beugholt, H. Bögge, F. Peters, M. Schmidtmann, P. Kögerler, M. J. Koop, Chem. Eur. J. 1998, 4, 1000-1006; A. Müller, S. Dillinger, E. Krickemeyer, H. Bögge, W. Plass, A. Stammler, R. C. Haushalter, Z. Naturforsch. B 1997, 52, 1301-1306; M. I. Khan, J. Zubieta, Progr. Inorg. Chem. 1995, 43, 1-149; H. K. Chae, W. G. Klemperer, T. A. Marquart, Coord. Chem. Rev. 1993, 128, 209-224.
6. A. Müller, J. Meyer, E. Krickemeyer, C. Beugholt, H. Bögge, F. Peters, M. Schmidtmann, P. Kögerler, M. J. Koop, Chem. Eur. J. 1998, 4, 1000-1006; A. Müller, S. Dillinger, E. Krickemeyer, H. Bögge, W. Plass, A. Stammler, R. C. Haushalter, Z. Naturforsch. B 1997, 52, 1301-1306; M. I. Khan, J. Zubieta, Progr. Inorg. Chem. 1995, 43, 1-149; H. K. Chae, W. G. Klemperer, T. A. Marquart, Coord. Chem. Rev. 1993, 128, 209-224.
7. A. Müller, J. Meyer, E. Krickemeyer, C. Beugholt, H. Bögge, F. Peters, M. Schmidtmann, P. Kögerler, M. J. Koop, Chem. Eur. J. 1998, 4, 1000-1006; A. Müller, S. Dillinger, E. Krickemeyer, H. Bögge, W. Plass, A. Stammler, R. C. Haushalter, Z. Naturforsch. B 1997, 52, 1301-1306; M. I. Khan, J. Zubieta, Progr. Inorg. Chem. 1995, 43, 1-149; H. K. Chae, W. G. Klemperer, T. A. Marquart, Coord. Chem. Rev. 1993, 128, 209-224.
8. A. Müller, M. Koop, H. Bögge, M. Schmidtmann, C. Beugholt, Chem. Commun. 1998, 1501-1502, and references therein.
9. I. D. Brown in Structure and Bonding in Crystals, Vol. II (Eds.: M. O'Keeffe, A. Navrotsky), Academic Press, New York, 1981, pp. 1-30.
10. 132}-type cluster that contains formate instead of acetate ligands.) The structures were solved with the program SHELXS-96 and refined with the program SHELXL-93 (G. M. Sheldrick, University of Göttingen, 1996 and 1993, respectively). Further details on the crystal structure investigation may be obtained from the Fachinformationszentrum Karlsruhe, D-76344 Eggenstein-Leopoldshafen, Germany (fax: (+49)7247-808-666; e-mail: crysdata@fiz-karlsruhe.de), on quoting the depository number CSD-410097.
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