Field measurement of high temperature bulk reaction rates II: Interpretation of results from a field site near simplon pass, Switzerland

American Journal of Science

Volumn 302, Issue 6, 2002, Pages 465-516

  Baxter, Ethan F ^a   DePaolo, Donald J ^a  

^a CALIFORNIA INSTITUTE OF TECHNOLOGY   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

EQUILIBRIUM; HIGH TEMPERATURE; METAMORPHISM; REACTION KINETICS; REACTION RATE;

EID: 0036623905     PISSN: 00029599     EISSN: None     Source Type: Journal    
DOI: 10.2475/ajs.302.6.465     Document Type: Article

References (105)

1. Thermodynamic and kinetic constraints on reaction rates among minerals and aqueous solutions. I. Theoretical considerations
2. Implications of kinetically controlled mineral-fluid exchange on the geometry of stable-isotope fronts
3. Mass transfer during Barrovian metamorphism of pelites, south central Connecticut. II: Channelized fluid flow and the growth of staurolite and kyanite
4. Simple models of coupled fluid infiltration and redox reactions in the crust
5. High-temperature embrittlement of extensional Alpine mylonite zones in the midcrustal ductile-brittle transition
6. Coupled mass transport and kinetically limited isotope exchange: Applications and exchange mechanisms
7. Transport of stable isotopes: I: Development of a kinetic continuum theory for stable isotope transport
8. Field measurement of slow metamorphic reaction rates at temperatures of 500° to 600°C
9. Field measurement of high temperature bulk reaction rates I: Theory and technique
10. Can metamorphic reactions proceed faster than bulk strain?
11. 39Ar "age" variations in biotites about a lithologic contact near Simplon Pass, Switzerland: A mechanistic explanation for excess Ar
12. Prograde temperature-time evolution in the Barrovian type-locality constrained by Sm/Nd garnet ages from Glen Glova, Scotland
13. Application of isotope doping techniques to evaluation of reaction kinetics and fluid/mineral distribution coefficients: An experimental study of calcite at elevated temperatures and pressures
14. Mixing properties of Ca-Mg-Fe-Mn garnets
15. Thermobarometry using multi-equilibrium calculations: A new technique, with petrological applications
16. Transport mechanisms by fluid-flow in metamorphic rocks: Oxygen and strontium decoupling in the Trois Seigneurs Massif- A consequence of kinetic dispersion?
17. Advective-diffusive transport of isotopic fronts: An example from Naxos, Greece
18. Strontium and oxygen isotope decoupling in the Hercynian Trois Seigneurs Massif, Pyrenees: Evidence for fluid circulation in a brittle regime
19. Strontium and oxygen isotope profiles across marble-silicate contacts, Lizzies Basin, East Humboldt Range, Nevada: Constraints on metamorphic permeability contrasts and fluid flow
20. Fluid flow and diffusion in the Waterville Limestone, south-central Maine: Constraints from strontium, oxygen and carbon isotopic profiles
21. Reference frames and diffusion coefficients
22. Metasomatic zones in metamorphic rocks
23. Intergranular diffusion in metamorphic rocks
24. Surface area and porosity of primary silicate minerals
25. The relative diffusion of Pb, Nd, Sr, and O in garnet
26. Steep oxygen-isotope gradients at marble-metagranite contacts in the northwest Adirondack Mountains, New York, USA: Products of fluid-hosted diffusion
27. A thermodynamic study of the pseudobinary join muscovite-paragonite in the system
28. A study of strontium diffusion in plagioclase using Rutherford backscattering spectroscopy
29. Disequilibrium for Ca during garnet growth
30. Rates of tectonometamorphic processes from rubidium and strontium isotopes in garnet
31. Correlation by Rb-Sr geochronology of garnet growth histories from different structural levels within the Tauern Window, Eastern Alps
32. Rates and mechanisms of isotopic exchange
33. Contact metamorphism surrounding the Alta stock: Finite-element model simulation of heat- and 180/160 mass transport during prograde metamorphism
34. Models of isotope exchange in reactive fluid-rock systems: Implications for geochronology in metamorphic systems
35. Closure temperature in cooling geochronological and petrological systems
36. An improved mean atomic number correction for quantitative microanalysis
37. Grain-scale stable isotope disequilibrium during fluid-rock interaction. 2: An example from the Penninic- Austroalpine tectonic contact in eastern Switzerland
38. Reaction progress: A monitor of fluid-rock interaction during metamorphic and hydrothermal events
39. Role of fluid flow in the contact metamorphism of siliceous dolomitic limestones
40. Patterns of mineral occurrence in metamorphic rocks
41. Formation of wollastonite by chemically reactive fluid flow during contact metamorphism, Mt. Morison Pendant, Sierra Nevada, California, USA
42. Metasomatic phase relations in dolomites of the Adamello Alps
43. Ternary-feldspar modeling and thermobarometry
44. Diffusion kinetics of samarium and neodymium in garnet, and a method for determining cooling rates of rocks
45. Are quartz dissolution rates proportional to BET surface areas?
46. Simple mechanistic models for inhibition of a dissolution reaction
47. Timescales and mechanisms of fluid infiltration in a marble: An ion microprobe study
48. Two-dimensional thermal modeling of normal faulting: The Simplon Fault Zone, Central Alps, Switzerland
49. Time and metamorphic petrology: Calcite to aragonite experiments
50. Hydrodynamics of regional metamorphism due to continental collision
51. 2O
52. Thermodynamic and kinetic contraints on reaction rates among minerals and aqueous solutions. II. Rate constants, effective surface area, and the hydrolysis of feldspar
53. Morphology of intergranular pores and wetting angles in pelitic schists studied by transmission electron microscopy
54. Peristerite exsolution in metamorphic plagioclase from the Lepontine Alps: An analytical and transmission electron microscope study
55. Evolution of mineral assemblage zoning in diffusion metasomatism
56. Grain growth and grain-boundary diffusion in quartz from the Christmas Mountains (Texas) contact aureole
57. 2O: A model diagenetic reaction
58. Kinetics of heterogenous reactions
59. The dissolution kinetics of quartz as a function of pH and time at 70°C
60. Sr and Ba partitioning between plagioclase and aqueous chloride fluid at 550°-800°C and P = 1-2 Kbar
61. Metamorphic reaction rate laws and development of isograds
62. Variation of crystal dissolution rate based on a dissolution stepwave model
63. Fluid flow and chemical reaction kinetics in metamorphic systems
64. Ion microprobe study of marble from Naxos, Greece: Grain-scale fluid pathways and stable isotope equilibration during metamorphism
65. 2
66. 2: A comparison of rock-sample and of powder experiments
67. Thermobarometry of garnet-clinopyroxene-hornblende granulites from the Kapuskasing structural zone
68. Neogene lateral extension during convergence in the Central Alps: Evidence from interrelated faulting and backfolding around the Simplonpass (Switzerland)
69. Kinetics and mechanisms of the reaction of zoisite to anorthite under hydrothermal conditions: Reaction phenomenology away from the equilibrium region
70. Calibration of the SGAM thermobarometer for pelitic rocks using data from phase-equilibrium experiments and natural assemblages
71. Kinetics of coesite to quartz transformation
72. Calculation of the thermodynamic and transport properties of aqueous species at high pressures and temperatures: Aqueous tracer diffusion coefficients of ions to 1000°C and 5 kb
73. Numerical models for diagenesis and the Neogene Sr isotopic evolution of seawater from DSDP Site 590B
74. Kinetics of metamorphic reactions at elevated temperatures and pressures: An appraisal of available experimental data
75. The reaction muscovite + quartz = andalusite + k-feldspar + water. Part 1. Growth kinetics and mechanism
76. Fluid-flux and reaction rate from advective-diffusive carbonation of mafic sill margins in the Dalradian, southwest Scottish Highlands
77. The correlation of reaction and isotope fronts and the mechanism of metamorphic fluid flow
78. Quantitative P-T paths from zoned minerals: Theory and tectonic applications
79. The Tertiary structural and thermal evolution of the Central Alps compressional and extensional structures in an orogenic belt
80. Syndeformational recrystallization - Dynamic or compositionally induced?
81. Kinetics of calcite growth: Surface processes and relationships to macroscopic rate laws
82. Metamorphic field gradients in the Central Alps
83. Low-temperature carbonate concretions in the Martian meteorite ALH84001: Evidence from stable isotopes and mineralogy
84. Oxygen isotope record of fluid infiltration and mass transfer during regional metamorphism of pelitic schist, Connecticut, USA
85. Isotopic chronometry of zoned garnets: Growth kinetics and metamorphic histories
86. Prograde and retrograde thermal histories from the central Swiss Alps
87. Constancy of silicate-mineral weathering-rate ratios between natural and experimental weathering: Implications for hydrologic control of differences in absolute rates
88. Fluid-rock reactions during metamorphism at mid-crustal conditions
89. Fluid production and isograd reactions at contacts of carbonate-rich and carbonate-poor layers during progressive metamorphism
90. Rate and mechanism in prograde metamorphism
91. Mineral fluid reaction rates
92. Assessing the extent of disequilibrium and overstepping of the prograde metamorphic reactions in metapelites from the Bushveld Complex aureole, South Africa
93. Correlations between fluid composition and deep-seated structural style in the footwall of the Simplon low-angle normal fault, Switzerland
94. Styles of footwall uplift along the Simplon and Brenner normal fault systems, Central and Eastern Alps
95. Chemical weathering rates of silicate minerals
96. Rates of hydrothermal reactions
97. 16O and elemental concentrations in metamorphic garnet from southeastern Vermont, USA
98. Interdiffusion of NaSi-CaAl in peristerite
99. Compositional changes of minerals associated with dynamic recrystallization
100. Oxygen isotope exchange processes and disequilibrium between calcite and forsterite in an experimental COH fluid