Synthesis and properties of [Cu(L5)2][ClO4]2 ·H2O having square planar and pseudo-octahedral geometries in the same unit cell, and anion-bound complexes [Cu(L5)2X][ClO4] (X = Cl-, NCS-, N3-) [L5 = 2-(3,5-dimethylpyrazol-1-ylmethyl)pyridine]

Polyhedron

Volumn 21, Issue 12-13, 2002, Pages 1245-1253

  Gupta, Rajeev ^a   Lal, Tapan Kumar ^a   Mukherjee, Rabindranath ^a  

^a INDIAN INSTITUTE OF TECHNOLOGY KANPUR   (India)

Author keywords

2 (3,5 Dimethylpyrazol 1 ylmethyl)pyridine; Absorption and EPR spectra; Bis ligand and anion bound copper(II) complexes; Cyclic voltammetry; X ray structure

Indexed keywords

CHELATION; COPPER COMPOUNDS; CYCLIC VOLTAMMETRY; ELECTRON SPIN RESONANCE SPECTROSCOPY; GROUND STATE; IONS; MOLECULES; PYRIDINE; SPECTRUM ANALYSIS; STRUCTURAL ANALYSIS; SYNTHESIS (CHEMICAL);

2-(3,5-DIMETHYLPYRAZOL-1-YLMETHYL)PYRIDINE; ABSORPTION AND EPR SPECTRUM; BIS-LIGAND AND ANION-BOUND COPPER(II) COMPLEX; EPR SPECTRUM; HETEROCYCLIC LIGANDS; NITROGEN DONORS; PROPERTY; PSEUDO-OCTAHEDRAL GEOMETRIES; UNIT CELLS; X-RAY STRUCTURE;

LIGANDS;

2 (3,5 DIMETHYLPYRAZOL 1 YLMETHYL)PYRIDINE; ACETONITRILE; ANION; CHLORIDE; COORDINATION COMPOUND; COPPER COMPLEX; HETEROCYCLIC COMPOUND; LIGAND; MERCUROUS CHLORIDE; NITROGEN; PYRAZOLE DERIVATIVE; PYRIDINE DERIVATIVE; SULFUR; THIOCYANATE; UNCLASSIFIED DRUG; WATER;

ABSORPTION SPECTROSCOPY; ARTICLE; CRYSTAL STRUCTURE; CYCLIC POTENTIOMETRY; ELECTRON SPIN RESONANCE; GEOMETRY; MOLECULAR INTERACTION; OXIDATION REDUCTION POTENTIAL; SOLID STATE; STEREOCHEMISTRY; STOICHIOMETRY; SYNTHESIS; X RAY ANALYSIS;

EID: 0036609391     PISSN: 02775387     EISSN: None     Source Type: Journal    
DOI: 10.1016/S0277-5387(02)01014-8     Document Type: Article

References (36)