Activation of methane by oxygen and nitrogen oxides

Catalysis Reviews - Science and Engineering

Volumn 44, Issue 1, 2002, Pages 1-58

  Tabata, K ^b   Teng, Y ^b   Takemoto, T ^b   Suzuki, E ^b  

^a CSIC   (Spain)

^b RESEARCH INSTITUTE OF INNOVATIVE TECHNOLOGY FOR THE EARTH   (Japan)

Author keywords

Homogeneous and heterogeneous reactions; Mechanisms; Methane activation; Methanol and formaldehyde

Indexed keywords

EID: 0036476232     PISSN: 01614940     EISSN: None     Source Type: Journal    
DOI: 10.1081/CR-120001458     Document Type: Article

References (234)

1. Direct conversion of methane to methanol by controlled oxidation C.B.
2. Direct catalytic oxidation of methane to methanol
3. Dependence of the kinetics of gas-phase methane oxidation at high pressure on the concentration of oxygen and temperature
4. A review of C-1 conversion chemistry
5. Partial oxidation of methane: The role of the gas-phase reactions
6. Progress in the partial oxidation of methane to methanol and formaldehyde
7. 2 gas mixtures at atmospheric pressure
8. Partial oxidation of methane
9. 2-catalyzed methane partial oxidation with molecular oxygen
10. Factors controlling the reactivity of the silica surface in methane partial oxidation
11. Influence of mogeneous gas-phase reactions in the partial oxidation of methane to methanol and formaldehyde in the presence of oxide catalysts
12. 5 catalysts in the selective partial oxidation of methane
13. Direct conversion of methane to methanol in a flow reactor
14. Methanol formation at high pressure by the catalyzed oxidation of natural gas and by the sensitized oxidation of methane
15. 2 in a hot wire thermal diffusion column
16. Effects of NO and solids on the oxidation of methane to formaldehyde
17. Effect of the addition of nitrogen dioxide on the gas-phase partial oxidation of methane with oxygen under normal pressures
18. Kinetic and thermodynamic sensitivity of the NO-sensitized oxidation of methane
19. x in the gas phase
20. x in the gas phase
21. 2
22. 2 catalysts. Role of NO in the gas phase
23. 2 gaseous selective oxidation at 1 atm
24. 2-NO gaseous phase at atmospheric pressure
25. New catalytic routes for syngas and hydrogen production
26. Sulfur-passivated reforming process lowers syngas hydrogen/carbon ratio
27. Advances in methanol technology
28. Selective oxidation of methane to synthesis gas using transition metal catalysts
29. Partial oxidation of methane to carbon monoxide and hydrogen over a nickel/alumina catalyst
30. The different catalytic routes for methane valorization: An assessment of process for liquid fuels
31. Nonequilibrium oxidative conversion of methane to carbon monoxide and hydrogen with high selectivity and productivity over nickel/alumina at low temperature
32. Partial oxidation of methane to synthesis gas over some titanates based perovskite oxides
33. Status and future opportunities for conversion of synthesis gas to liquid fuels
34. 3 perovskites as catalyst precursors
35. Catalytic and thermodynamic approach of the oxyreforming reaction of methane
36. Synthesis gas formation by direct oxidation of methane over Pt monoliths
37. Production of syngas by direct catalytic oxidation of methane
38. Synthesis gas formation by catalytic oxidation of methane in fluidized bed reactors
39. Catalytic reactions of partial methane oxidation
40. Development of active oxide catalysts for the direct oxidation of methanol to formaldehyde
41. In situ Raman spectroscopy during the partial oxidation of methane to formaldehyde over supported-vanadium oxide catalysts
42. 2 systems
43. Partial oxidation of methane by oxygen over silica
44. Selective oxidation of methane over vycor glass, quartz glass and various silica, magnesia and alumina surfaces
45. Oxidation of methane to formaldehyde on porous catalysts
46. 2
47. Selective oxidation of methane with air over silica catalysts
48. 2 prepared from Si
49. FTIR spectroscopic investigation of the active sites of different types of silica catalysts for methane partial oxidation to formaldehyde
50. Hydroxyl groups in silica
51. Reactive silica. XVII. The nature of the reaction center
52. Infrared spectra of edge-shared silicate tetrahedral
53. Partial oxidation of methane to formaldehyde by means of molecular oxygen
54. Comparative study of the surface hydroxyl groups of fumed and precipitated silicas. 4. Infrared study of dehydroxylation by thermal treatments
55. 2 and Sn-W mixed oxides
56. Reductive activation of oxygen for partial oxidation of light alkanes
57. Reactive silicas. The role of Fe impurities in POM reaction
58. Oxidative synthesis of hydrocarbons from methane on zeolites
59. Oxidative of methane over H-ZSM5 and other catalysts
60. Hydrocarbons from methanol
61. Partial oxidation of methane on heterogeneous catalysts
62. Partial oxidation of methane by nitrous oxide over molybdenum on silica
63. A kinetic study of partial oxidation of methane with nitrous oxide on molybdena-silica catalyst
64. Catalytic oxidation of methane on molybdenum trioxide-silicon dioxide: Mechanism of oxidation with oxygen and nitrous oxide studied by surface potential measurements
65. The formation of molybdosilicic acid on molybdenum/silica catalysts and its relevance to methanol oxidation
66. Effect of sodium on the molybdene-silica-catalyzed partial oxidation of methane
67. The partial oxidation of methane to formaldehyde: Role of different crystal planes of molybdenum trioxide
68. 1 sobre catalizadores de oxido de molibdeno-sílice
69. Selective oxidation of methane to formaldehyde on supported molybdate catalysts
70. 2. Their role in the partial oxidation of methane
71. 2 catalysts in an excess amount of water vapor
72. 3-USY zeolites
73. Silica-supported molybdena catalysts. Characterization and methane oxidation
74. 2 catalysts and its relevance to the selective oxidation of methane and methanol
75. Partial oxidation of methane over silica-supported molybdenum oxide catalysts
76. 2 catalysts in partial oxidation of methane to formaldehyde
77. 2 studied in the temporal analysis of products
78. Partial oxidation of methane over silica- and alumina-supported vanadia catalysts
79. On the nature of active sites of silica based oxide catalysts in the partial oxidation of methane to formaldehyde
80. Structural features of silica-supported vanadia catalysts and their relevance in the selective oxidation of methane to formaldehyde
81. 2 catalysts as a function of coverage
82. 2 catalyst in a single catalytic step
83. 5
84. Studies of the partial oxidation of methane over heterogeneous catalysts
85. Inhibition of methane combustion by halocompounds on Pd-alumina catalysts
86. The catalysts for the síntesis of formaldehyde by partial oxidation of methane
87. 2 gas mixture at atmospheric pressure
88. Partial oxidation of methane by reductively activated oxygen over iron phosphate catalyst
89. Methane partial oxidation by silica-supported iron-phosphate catalysts. Influence of iron phosphate content on selectivity and catalyst structure
90. Methane partial oxidation by silica-supported iron-phosphate catalysts. Influence of reaction conditions on co-feeding of water on activity and selectivity
91. Phase equilibria in the iron oxide-cobalt oxide-phosphorus oxide system
92. 2H system
93. 2 catalyzed by europium system under mild conditions
94. Activation of C-H bonds by metal complexes
95. Organometallic chemistry of electrophilic transition and lanthanide metal ions. The dominant pathways for reactions involving carbon-carbon double and single bonds and carbon-hydrogen bonds
96. Selective functionalization of alkanes by transition metal boryl complexes
97. Nickel and palladium-catalyzed cross-coupling that forms carbon-heteroatom and carbon-element bonds
98. C-H activation at Pt(II) to form stable Pt(IV) alkyl hydrides
99. The mechanism of a C-H bond activation reaction in room temperature alkane solution
100. A mercury-catalyzed, high-yield system for the oxidation of methane to methanol
101. Platinum catalysts for the high yield oxidation of methane to a methanol derivative
102. Homogeneous conversion of methane to methanol. 2. Catalytic activation of methane by cis- and trans-platin: A density functional study of the shilov type reaction
103. C-H activation by aqueous platinum complexes: A mechanistic study
104. Homogeneous oxidation of alkanes by electrophilic late transition metals
105. Hydrocarbon activation at a cationic Pt(II) diimine aqua complex under mild conditions in a hydroxylic solvent
106. Aqueous phase oxidation of methane with hydrogen peroxide catalyzed by di-iron-substituted silicotungstate
107. Comparison of catalytic activity and efficiency of hydrogen peroxide utilization by di-iron containing silicotungstate with tose o of iron containing complexes in oxidation of methane and ethane
108. 2) complexes in the presence of hydrogen peroxide
109. High yield liquid phase oxygenation of methane with hydrogen peroxide catalyzed by 12-molybdovanadophosphoric acid catalyst precursor
110. Alkane functionalization at (μ-oxo) diiron(III) centers
111. Substrate specificit of soluble methane monooxygenase. Mechanistic implications
112. Aspects of methane chemistry
113. Room temperature photo-activation of methane on titanium (IV) oxide supported molybdena
114. Selective photo-oxidation of light alkanes using solid metal oxide semiconductors
115. The selective photo-oxidation of methane and ethane with oxygen over zinc oxide and molybdenum-loaded zinc oxide catalysts
116. Selective photo-oxidation of light alkanes to oxygenates using supported molybdenum oxide catalysts
117. 2-based catalysts
118. New developments in the photocatalytic conversion of methane to methanol
119. The direct conversion of natural gas to methanol by the controlled oxidation at high pressure
120. Partial oxidation of methane to methanol in a flow reactor at elevated pressure
121. Partial oxidation of methane: The role of surface reactions
122. Catalytic partial oxidation of methane
123. Homogeneous gas-phase oxidation of methane using oxygen as oxidant in an annular reactor
124. Quantitative model of the oxidation of methane at high pressure
125. Direct conversion of methane into methanol
126. Partial oxidation of methane at high pressures
127. Slow combustion of methane at elevated pressures
128. Synthesis of ethylene via oxidative coupling of methane. I. Determination of the active catalysts
129. - clusters in the oxidative dimerization of methane
130. The oxidative conversion of methane to higher hydrocarbons
131. The role of chlorine in chlorine-promoted methane coupling catalysts
132. Catalytic conversion of methane to more useful chemicals and fuels: Challenge for the 21st century
133. Catalytic oxidative conversion of alkanes to olefins and oxygenates
134. 3
135. The oxidative coupling of methane over alkali, alkaline earth, and rare earth oxides
136. Oxypyrolysis of natural gas
137. Oxidative coupling of methane over lanthana catalysts. I. Identification and role of specific active sites
138. The effect of oxygen-anion conductivity of metal-oxide doped lantanum oxide catalysts on hydrocarbon selectivity in the oxidative coupling of methane
139. Conversion of methyl radicals to methanol and formaldehyde over vanadia oxide catalysts
140. The role of subsurface oxygen in the silver-catalyzed oxidative coupling of methane
141. Catalytic properties of oxygen semipermeable perovskite-type ceramic membrane materials for oxidative coupling of methane
142. Oxygen permeation and oxidative coupling of methane in yttria doped bismuth oxide membrane reactor
143. Oxidative coupling of methane using oxygen-permeable dense membrane reactors
144. Methane oxidative coupling in fixed bed catalytic reactors with a distributed oxygen feed. A simulation study
145. A novel gas-recycle reactor-separator for the oxidative coupling of methane
146. Enhanced ethylene yields from methane oxidative coupling by means of a separative chemical reactor
147. Selective oxidative coupling of methane with membrane reactors
148. Oxidative coupling of methane with membrane reactors containing lead oxide
149. Oxidative coupling of methane in a mixed-conducting perovskite membrane reactor
150. Methane oxidative coupling using ceramic membrane reactors. I. Reactor development
151. Development of membrane reactors with a non-uniform permeation pattern. Application to methane oxidative coupling
152. 2O as an oxidant
153. -] clusters
154. 3
155. 3 catalyst
156. 2 gaseous phase at atmospheric pressure
157. Effects of pressures, third bodies, and temperature profiling on the non-catalytic partial oxidation of methane
158. Methane partial oxidation to methanol. 1. Effects of reaction conditions and additives
159. Modern state of direct high pressure partial oxidation of natural gas to methanol
160. Direct gas phase oxidation of natural gas to methanol and other oxygenates at high pressure
161. Symposium on natural gas upgrading II
162. CHEMECA 92
163. CHEMECA 91
164. Homogeneous gas-phase partial oxidation of methane to methanol and formaldehyde
165. Pressure, temperature and product yield relationships in direct oxidative methane conversion at elevated pressures and moderate temperatures
166. x (x = 1 or 2)
167. Symposium on natural gas upgrading II
168. Response to comments on direct oxidative methane conversion at elevated pressure and moderate temperature
169. The direct conversion of methane to methanol by a high pressure partial oxidation reaction
170. 2-NO at atmospheric pressure
171. Catalytic synthesis of methanol and formaldehyde by partial oxidation of methane
172. Selective oxidation of methane by nitrous oxide over silica-supported molybdenum oxide catalysts
173. 2 catalysts: Influence of the molybdenum content and type of oxidant
174. The oxidation of methane on heteropolyoxometalates. I. Catalytic properties of silica-supported heteropolyacids
175. A comparison of the performances of selected catalysts for the partial oxidation of methane to formaldehyde at elevated pressures
176. 3
177. Selective patterns in the partial oxidation of methane
178. Direct conversion of methane and ethane to the corresponding alcohols using nitrous oxide over iron phosphate catalysts
179. Selective oxidation of methane to methanol on a FeZSM-5 surface
180. Kinetic isotope effects and mechanism of biomimetic oxidation of methane and benzene on FeZSM-5 zeolite
181. 2O decomposition on ZSM-5 zeolite and reactivity of the surface oxygen formed
182. Oxidation of benzene to phenol by nitrous oxide over FeZSM-5 zeolites
183. 2O
184. 2O decomposition: The role of iron
185. Oxidative hydroxylation using dinitrogen monoxide: A possible route for organis synthesis over zeolites
186. Formation of an iron-oxo species upon decomposition of dinitrogen oxide on a modified Fe-ZSM5 zeolite
187. Direct methane-methanol and benzene-phenol conversion on Fe-ZSM-5 zeolite. Theoretical predictions on the reaction pathways and energetics
188. Quantitative model of the oxidation of methane at high pressure. I. Description of the model
189. Quantitative model of the oxidation of methane at high pressure. II. Mechanism of autoacceleration
190. Quantitative model of the oxidation of methane at high pressure. III. Mechanism of formation of reaction products
191. Quantitative model of the oxidation of methane at high pressure. IV. Ignition delays
192. Methane oxidation: Experimental and kinetic modeling study
193. The relevance of combustion theory to the homogeneous oxidation of methane
194. The relevance of thermokinetic interactions and numerical modeling to the homogeneous partial oxidation of methane
195. Experimental and kinetic modeling study of the oxidation of methane