Aqueous phase oxidation of methane with hydrogen peroxide catalyzed by di-iron-substituted silicotungstate

Journal of Catalysis

Volumn 184, Issue 2, 1999, Pages 550-552

  Mizuno, Noritaka ^a   Seki, Yasuhiro ^a   Nishiyama, Yoshiyuki ^a   Kiyoto, Ikuro ^a   Misono, Makoto ^a  

^a UNIVERSITY OF TOKYO   (Japan)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0033542504     PISSN: 00219517     EISSN: None     Source Type: Journal    
DOI: 10.1006/jcat.1999.2455     Document Type: Article

References (54)

1. Kozhevnikov, I.V., Chem. Rev. 98, 171 (1998);
2. Mizuno, N., and Misono, M., Chem. Rev. 98, 199 (1998);
3. Neumann, R., Prog. Inorg. Chem. 47, 317 (1998);
4. Okuhara, T., Mizuno, N., and Misono, M., Adv. Catal. 41, 113 (1996);
5. Hill, C. L., and Prosser-McCartha, C. M., Coord. Chem. Rev. 143, 407 (1995).
6. Bösing, M., Nöh, A., Loose, I., and Krebs, B., J. Am. Chem. Soc. 120, 7252 (1998);
7. Zhang, X., Chen, Q., Duncan, D. C., Campana, C. F., and Hill, C. L., Inorg. Chem. 36, 4208 (1997);
8. Neumann, R., and Gara, M., J. Am. Chem. Soc. 116, 5509 (1994).
9. Mizuno, N., Nozaki, C., Kiyoto, I., and Misono, M., J. Am. Chem. Soc. 120, 9267 (1998).
10. Rozenzweig, A. C., Frederick, C. A., Lippard, S. J., and Nordlund, P., Nature 366, 537 (1993).
11. Pitchai, R., and Klier, K., Catal. Rev.-Sci. Eng. 28, 13 (1986);
12. Gesser, H. D., Hunter, N. R., and Prakash, C. B., Chem. Rev. 85, 235 (1985);
13. Hutchings, G. J., Scrrell, M. S., and Woodhouse, J. R., Chem. Soc. Rev. 18, 251 (1989);
14. Crabtree, R. H., Chem. Rev. 95, 987 (1995);
15. Srivastava, R. D., Gollakota, S. V., Stiegel, G. J., and Bose, A. C., "Methane and Alkane Conversion Chemistry," p. 291. Plenum, New York, 1995.
16. (a) Suss-Fink, G., Nizova, G. V., Stanislas, S., and Shul'pin, G. B., J. Mol. Catal. A: Chem. 130, 163 (1998).
17. (b) Seki, Y., Mizuno, N., and Misono, M., Appl. Catal. A: Gen. 157, L47 (1997).
18. (c) Basickes, N., Hogan, T. E., and Sen, A., J. Am. Chem. Soc. 118, 4574 (1996).
19. (d) Fujiwara, Y., Takaki, K., and Taniguchi, Y., Synlett 591 (1996).
20. (e) Yamanaka, I., Soma, M., and Otsuka, K., Chem. Lett. 565 (1996).
21. Moiseev, I. I., J. Mol. Catal. A: Chem. 127, 1 (1997);
22. Sheldon, R. A., Top. Curr. Chem. 164, 22 (1993);
23. Sobkowiak, A., Tung, H., and Sawyer, D. T., Prog. Inorg. Chem. 40, 291 (1992).
24. Joó, F., and Kathó, Á., J. Mol. Catal. A: Chem. 116, 3 (1997) and Refs. (7-11) therein;
25. Horváth, I. T., J. Mol. Catal. A: Chem. 116, 1 (1997);
26. Horváth, I. T., and Joó, F., NATOASI Ser. 35 (1995);
27. Sheldon, R. A., CHEMTECH 38 (1994);
28. Kuntz, E. G., CHEMTECH 570 (1987).
29. Zhang, X., O'Connor, C. J., Jameson, G. B., and Pope, M. T., Inorg. Chem. 35, 30 (1996).
30. Tézé, A., Hervé, G., and Pope, M. T., Inorg. Synth. 27, 85 (1990).
31. Zonnevijlle, F., Tourné, C. M., and Tourné, G. F., Inorg. Chem. 21, 2751 (1982).
32. Liu, J., Ortéga, F., Sethuraman, P., Katsoulis, D. E., Costello, C. E., and Pope, M. T., J. Chem. Soc., Dalton Trans. 1901 (1992).
33. Vogel, A. I., "A Textbook of Quantitative Inorganic Analysis Including Elementary Instrumental Analysis." Longman, New York, 1978.
34. The yield could be increased by a factor of 6 by increasing the volume of the reaction solution. No products were observed in blank experiments without hydrogen peroxide or without catalysts.
35. Khenkin, A. M., and Shilov, A. E., New J. Chem. 13, 659 (1989).
36. Fish, R. H., Konings, M. S., Oberhausen, K. J., Fong, R. H., Yu, W. M., Christou, G., Vincent, J. B., Coggin, D. K., and Buchanan, R. M., Inorg. Chem. 30, 3002 (1991).
37. (a) Rabion, A., Buchanan, R. M., Seris, J.-L., and Fish, R. H., J. Mol. Catal. 116, 43 (1997).
38. (b) Duboc-Toia, C., Ménage, S., Lambeaux, C., and Fontecave, M., Tetrahedron Lett. 38, 3727 (1997).
39. (c) Itoh, S., Okuno, T., Matsushima, H., Tokii, T., and Nishida, Y., J. Chem. Soc., Dalton Trans. 4479 (1996).
40. (d) Dong, Y., Yan, S., Yong, V. G., Jr., and Que, L., Jr., Angew. Chem., Int. Ed. Engl. 35, 618 (1996).
41. (e) Ménage, S., Galey, J.-B., Hussler, G., Seité, M., and Fontecave, M., Angew. Chem., Int. Ed. Engl. 35, 2353 (1996).
42. (f) Rabion, A., Chen, S., Wang, J., Buchanan, R. M., Seris, J.-L., and Fish, R. H., J. Am. Chem. Soc. 117, 12356 (1995).
43. (g) Ménage, S., Vincent, J. M., Lambeaux, C., and Fontecave, M., J. Chem. Soc., Dalton Trans. 2081 (1994).
44. (h) Leising, R. A., Kim, J., Perez, M. A., and Que, L., Jr., J. Am. Chem. Soc. 115, 9524 (1993).
45. (i) Anderson, K. K., Froland, W. A., Lee, S. K., and Lipscomb, J. D., New J. Chem. 15, 411 (1991).
46. (j) Kitajima, N., Ito, M., Fukui, H., and Moro-oka, Y., J. Chem. Soc., Chem. Commun. 102 (1991).
47. (k) Fontecave, M., Roy, B., and Lambeaux, C., J. Chem. Soc., Chem. Commun. 939 (1991).
48. (l) Barton, D. H. R., Csubai, E., Doller, D., Ozbalik, N., and Balavoine, G., Proc. Natl. Acad. Sci. U.S.A. 87, 3401 (1990).
49. (m) Sheu, C., Richert, S. A., Cofre, P., Ross, B., Jr., Sobkowiak, A., Sawyer, D. T., and Kanofsky, J. R., J. Am. Chem. Soc. 112, 1936 (1990).
50. (n) Nam, W., and Valentine, J. S., New J. Chem. 13, 677 (1989).
51. (o) Vincent, J. B., Huffman, J. C., Christou, G., Li, Q., Nanny, M. A., Hendrickson, D. N., Fong, R. H., and Fish, R. H., J. Am. Chem. Soc. 110, 6898 (1988).
52. (p) Barton, D. H. R., Boivin, J., Gastiger, M., Morzycki, J., Hay-Motherwell, R. S., Motherwell, W. B., Ozbalik, N., and Schwartzentruber, K. M., J. Chem. Soc., Perkin Trans. 1 947 (1986).
53. Studies to elucidate the nature of active species and to examine the stability of I under reaction conditions in more detail are in progress.
54. It was confirmed that no oxidation of the solvent, acetonitrile, proceeded at 303 K.