Hydrogen hydroperoxide oxidation of ethane and other alkanes catalyzed by chromium compounds

Petroleum Chemistry

Volumn 42, Issue 1, 2002, Pages 15-19

  Suss Fink G ^a   Shul'Pin, G B ^b  

^a UNIVERSITY OF NEUCHÂTEL   (Switzerland)

^b SEMENOV INSTITUTE OF CHEMICAL PHYSICS   (Russian Federation)

Author keywords

[No Author keywords available]

Indexed keywords

ACETALDEHYDE; ACETIC ACID; ACETONITRILE; ALCOHOL; ALCOHOL DERIVATIVE; ALDEHYDE; ALKANE; ALKYL GROUP; CHROMIUM DERIVATIVE; ETHANE; HYDROCARBON; HYDROGEN PEROXIDE; HYDROPEROXIDE; KETONE; OXYGEN DERIVATIVE; TERT BUTYL HYDROPEROXIDE;

ARTICLE; CATALYSIS; CHEMICAL REACTION KINETICS; CONCENTRATION RESPONSE; HIGH TEMPERATURE; OXIDATION; REACTION TIME;

EID: 0036460977     PISSN: 09655441     EISSN: None     Source Type: Journal    
DOI: None     Document Type: Article

References (34)

1. Shilov, A.E. and Shul'pin, G.B., Aktivatsiya i kataliticheskie reaktsii uglevodorodov (Activation and Catalytic Reactions of Hydrocarbons), Moscow: Nauka, 1995.
2. Shilov, A.E. and Shul'pin, G.B., Activation of C-H Bonds by Metal Complexes, Chem. Rev., 1997, vol. 97, p. 2879.
3. Shilov, A.E. and Shul'pin, G.B., Activation and Catalytic Reactions of Saturated Hydrocarbons in the Presence of Metal Complexes, Dordrecht: Kluwer, 2000.
4. Maravin, G.B., Avdeev, M.V., and Bagrii, E.I., Oxidative Functionalization of Saturated Hydrocarbons on Porphyrin Metal Complex Catalysts (A Review), Neftekhimiya, 2000, vol. 40, no. 1, p. 3 [Pet. Chem. (Engl. transl.), 2000, vol. 40, no. 1, p. 1].
5. Muzart, J., Chromium-Catalyzed Oxidations in Organic Synthesis, Chem. Rev., 1992, vol. 92, p. 113.
6. Cainelli, G. and Cardillo, G., Chromium Oxidations in Organic Chemistry, Berlin: Springer, 1984.
7. Adam, W., Gelalcha, F.G., Saha-Moller, C.R., and Stegmann, V.R., Chemoselective C-H Oxidation of Alcohols to Carbonyl Compounds with Iodosobenzene Catalyzed by (Salen)chromium Complex, J. Org. Chem., 2000, vol. 65, p. 1915.
8. Shapley, P.A., Zhang, N., Allen, J.L., Pool, D.H., and Liang, H.-C., Selective Alcohol Oxidation with Molecular Oxygen Catalyzed by Os-Cr and Ru-Cr Complexes, J. Am. Chem. Soc., 2000, vol. 122, p. 1079.
9. Bakac, A. and Wang, W.-D., Generation of a Macrocyclic Cr(V) Complex and Its Reactivity Toward Organic and Inorganic Reductants and DNA, Inorg. Chim. Acta, 2000, vol. 297, p. 27.
10. Muzart, J. and N'Ait Ajjou, A., Chromium(VI)-Catalyzed Benzylic Oxidations with Commercial t-Butylhydroperoxide or Hydrogen Peroxide, J. Mol. Catal., 1991, vol. 66, p. 155.
11. Muzart, J. and N'Ait Ajjou, A., Chromium-Catalyzed Homolytic Scission of Organic Peroxides with t-Butyl Hydroperoxide and Its Relation to Benzylic Oxidation, J. Mol. Catal., 1994, vol. 92, p. 141.
12. Muzart, J. and N'Ait Ajjou, A., Highly Efficient Oxygen Transfer from t-Butyl Hydroperoxide to Benzylic Carbons Catalyzed by Chromium(VI) Oxide Under High Substrate/Hydroperoxide Ratios, J. Mol. Catal., 1994, vol. 92, p. 277.
13. Delaval, N., Bouquillon, S., Henin, F., and Muzart, J., Use of Benzotrifluoride as Solvent for Chromium-Catalysed Oxidations with Sodium Percarbonate, J. Chem. Res. (S), 1999, p. 286.
14. Muzart, J. and N'Ait Ajjou, A., Chromium(VI)-Catalyzed Oxidation of Adamantane by t-Butylhydroperoxide, J. Mol. Catal., 1993, vol. 84, p. 15.
15. Chisem, I.C., Rafelt, J., Shieh, M.T., Chisem, J., Clark, J.H., Jachuck, R., Marcquarrie, D., Ramshaw, C., and Scott, K., Catalytic Oxidation of Alkyl Aromatics Using a Novel Silica Supported Schiff Base Complex, J. Chem. Soc., Chem. Commun, 1998, p. 1949.
16. 3-Catalyzed Oxidation of Ethylbenzene with Ambient Oxygen and Iodosobenzene, Izv. Akad. Nauk SSSR, Ser. Khim., 1989, p. 1185.
17. Shul'pin, G.B., Druzhinina, A.N., and Kats, M.M., Oxidation of Hydrocarbons with Iodosobenzene Catalyzed by Chromium and Vanadium Oxo Compounds, Neftekhimiya, 1989, vol. 29, no. 5, p. 697.
18. Shul'pin, G.B., Matsova, E., and Lederer, P., Oxidation of Alkanes and Alkylbenzenes with Cr(VI) Oxo Compounds upon Light Irradiation, Zh. Obshch. Khim., 1989, vol. 59, p. 2604.
19. Shul'pin, G.B. and Kitaigorodskii, A.N., Relative Rates of Methyl Group Oxidation in Substituted Toluenes with Cr(VI) Oxo Compounds in Thermal and Photochemical Reactions, Zh. Obshch. Khim., 1989, vol. 59, p. 2612.
20. + System, Zh. Obshch. Khim., 1989, vol. 59, p. 2615.
21. 2, Izv. Akad. Nauk SSSR, Ser. Khim., 1990, p. 212.
22. 3 upon Irradiation, Zh. Obshch. Khim., 1991, vol. 61, p. 754.
23. 2 Catalyzed by Polyoxochromates, Izv. Akad. Nauk SSSR, Ser. Khim., 1991, p. 2463.
24. Shul'pin, G.B. and Nizova, G.V., Contribution of Air Oxygen to Photooxidation of Alkanes by V(V) and Cr(VI) Oxocomplexes, React. Kinet. Catal. Lett., 1991, vol. 45, p. 7.
25. 3Cl, React. Kinet. Catal. Lett., 1991, vol. 45, p. 27.
26. 2 in the Presence of the System Chromium Oxocomplex-Iodosylbenzene, React. Kinet. Catal. Lett., 1991, vol. 45, p. 173.
27. Muzart, J., Druzhinina, A.N., and Shul'pin, G.B., Oxidation of Saturated Hydrocarbons with Air in Methylene Chloride Catalyzed by Cr(VI) Oxo Complexes, Neftekhimiya, 1993, vol. 33, no. 2, p. 124.
28. Druzhinina, A.N., Nizova, G.V., and Shul'pin, G.B., Oxidation of Hydrocarbons with Hydrogen Peroxide Catalyzed by Cr(VI) Oxo Compounds, Izv. Akad. Nauk SSSR, Ser. Khim., 1990, p. 210.
29. 2, Izv. Akad. Nauk SSSR, Ser. Khim., 1991, p. 1454.
30. 2 Catalyzed by Transition Metal Complexes, React. Kinet. Catal. Lett., 1992, vol. 48, p. 333.
31. 2 Oxidation of Alkanes and Arenes to Alkyl Peroxides and Phenols Catalyzed by the System VanadatePyrazine-2-Carboxylic Acid, J. Catal., 1993, vol. 142, p. 147.
32. Shul'pin, G.B., Bochkova, M.M., and Nizova, G.V., Aerobic Oxidation of Saturated Hydrocarbons into Alkyl Hydroperoxides Induced by Visible Light and Catalysed by a "Quinone-Copper Acetate" System, J. Chem. Soc., Perkin Trans. 2, 1995, p. 1465.
33. Shul'pin, G.B., Nizova, G.V., and Kozlov, Yu.N., Photochemical Aerobic Oxidation of Alkanes Promoted by Iron Complexes, New J. Chem., 1996, vol. 20, p. 1243.
34. 2-Vanadium Complex-Pyrazine-2-Carboxylic Acid: Part 7. Hydroperoxidation of Higher Alkanes, Tetrahedron, 1996, vol. 52, p. 13051.