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Volumn 122, Issue 6, 2000, Pages 1079-1091

Selective alcohol oxidation with molecular oxygen catalyzed by Os-Cr and Ru-Cr complexes

Author keywords

[No Author keywords available]

Indexed keywords

ALCOHOL; CHROMIUM; OSMIUM; OXYGEN; RUTHENIUM;

EID: 0034673313     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja982171y     Document Type: Article
Times cited : (111)

References (92)
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    • The kinetic isotope effect on the decomposition of many metal alkyl complexes is in the range 1.4-2.3, but Boncella et al. found a deuterium isotope effect 6.5 for a β hydrogen elimination in a tungsten complex. See: (a) Wang, S.-Y. S.; Abboud, K. A.; Boncella, J. M. J. Am. Chem. Soc. 1997, 119, 11990-11991. (b) Burger, B. J.; Thompson, M.E.; Cotter, W. D.; Bercaw, J. E. J. Am. Chem. Soc. 1990, 112, 1566-1577. (c) Whitesides, G. M. Pure Appl. Chem. 1981, 53, 287. (d) McCarthy, T. J.; Nuzzo, R. G.; Whitesides, G. M. J. Am. Chem. Soc. 1981, 103, 1676; 3396; 3404. (e) Ozawa, F.; Ito, T.; Yamamoto, A. J. Am. Chem. Soc. 1980, 102, 6457. (f) Ikariya, T.; Yamamoto, A. J. Organomet. Chem. 1976, 120, 257- 284. (g) Evans, J.; Schwarts, J.; Urguhart, P. W. J. Organomet. Chem. 1974, 81, C37-C39.
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    • The kinetic isotope effect on the decomposition of many metal alkyl complexes is in the range 1.4-2.3, but Boncella et al. found a deuterium isotope effect 6.5 for a β hydrogen elimination in a tungsten complex. See: (a) Wang, S.-Y. S.; Abboud, K. A.; Boncella, J. M. J. Am. Chem. Soc. 1997, 119, 11990-11991. (b) Burger, B. J.; Thompson, M.E.; Cotter, W. D.; Bercaw, J. E. J. Am. Chem. Soc. 1990, 112, 1566-1577. (c) Whitesides, G. M. Pure Appl. Chem. 1981, 53, 287. (d) McCarthy, T. J.; Nuzzo, R. G.; Whitesides, G. M. J. Am. Chem. Soc. 1981, 103, 1676; 3396; 3404. (e) Ozawa, F.; Ito, T.; Yamamoto, A. J. Am. Chem. Soc. 1980, 102, 6457. (f) Ikariya, T.; Yamamoto, A. J. Organomet. Chem. 1976, 120, 257- 284. (g) Evans, J.; Schwarts, J.; Urguhart, P. W. J. Organomet. Chem. 1974, 81, C37-C39.
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    • The kinetic isotope effect on the decomposition of many metal alkyl complexes is in the range 1.4-2.3, but Boncella et al. found a deuterium isotope effect 6.5 for a β hydrogen elimination in a tungsten complex. See: (a) Wang, S.-Y. S.; Abboud, K. A.; Boncella, J. M. J. Am. Chem. Soc. 1997, 119, 11990-11991. (b) Burger, B. J.; Thompson, M.E.; Cotter, W. D.; Bercaw, J. E. J. Am. Chem. Soc. 1990, 112, 1566-1577. (c) Whitesides, G. M. Pure Appl. Chem. 1981, 53, 287. (d) McCarthy, T. J.; Nuzzo, R. G.; Whitesides, G. M. J. Am. Chem. Soc. 1981, 103, 1676; 3396; 3404. (e) Ozawa, F.; Ito, T.; Yamamoto, A. J. Am. Chem. Soc. 1980, 102, 6457. (f) Ikariya, T.; Yamamoto, A. J. Organomet. Chem. 1976, 120, 257- 284. (g) Evans, J.; Schwarts, J.; Urguhart, P. W. J. Organomet. Chem. 1974, 81, C37-C39.
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    • The kinetic isotope effect on the decomposition of many metal alkyl complexes is in the range 1.4-2.3, but Boncella et al. found a deuterium isotope effect 6.5 for a β hydrogen elimination in a tungsten complex. See: (a) Wang, S.-Y. S.; Abboud, K. A.; Boncella, J. M. J. Am. Chem. Soc. 1997, 119, 11990-11991. (b) Burger, B. J.; Thompson, M.E.; Cotter, W. D.; Bercaw, J. E. J. Am. Chem. Soc. 1990, 112, 1566-1577. (c) Whitesides, G. M. Pure Appl. Chem. 1981, 53, 287. (d) McCarthy, T. J.; Nuzzo, R. G.; Whitesides, G. M. J. Am. Chem. Soc. 1981, 103, 1676; 3396; 3404. (e) Ozawa, F.; Ito, T.; Yamamoto, A. J. Am. Chem. Soc. 1980, 102, 6457. (f) Ikariya, T.; Yamamoto, A. J. Organomet. Chem. 1976, 120, 257- 284. (g) Evans, J.; Schwarts, J.; Urguhart, P. W. J. Organomet. Chem. 1974, 81, C37-C39.
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    • Ikariya, T.1    Yamamoto, A.2
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    • The kinetic isotope effect on the decomposition of many metal alkyl complexes is in the range 1.4-2.3, but Boncella et al. found a deuterium isotope effect 6.5 for a β hydrogen elimination in a tungsten complex. See: (a) Wang, S.-Y. S.; Abboud, K. A.; Boncella, J. M. J. Am. Chem. Soc. 1997, 119, 11990-11991. (b) Burger, B. J.; Thompson, M.E.; Cotter, W. D.; Bercaw, J. E. J. Am. Chem. Soc. 1990, 112, 1566-1577. (c) Whitesides, G. M. Pure Appl. Chem. 1981, 53, 287. (d) McCarthy, T. J.; Nuzzo, R. G.; Whitesides, G. M. J. Am. Chem. Soc. 1981, 103, 1676; 3396; 3404. (e) Ozawa, F.; Ito, T.; Yamamoto, A. J. Am. Chem. Soc. 1980, 102, 6457. (f) Ikariya, T.; Yamamoto, A. J. Organomet. Chem. 1976, 120, 257- 284. (g) Evans, J.; Schwarts, J.; Urguhart, P. W. J. Organomet. Chem. 1974, 81, C37-C39.
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