Use of benzotrifluoride as solvent for chromium-catalysed oxidations with sodium percarbonate

Journal of Chemical Research - Part S

Volumn , Issue 4, 1999, Pages 286-287

  Delaval, Nicolas ^a   Bouquillon, Sandrine ^a   Hénin, Françoise ^a   Muzart, Jacques ^a  

^a UNIVERSITÉ DE REIMS CHAMPAGNE ARDENNE   (France)

Author keywords

[No Author keywords available]

Indexed keywords

ALCOHOL; BENZOTRIFLUORIDE; CHROMIUM DERIVATIVE; DICHLOROETHANE; FLUORIDE; HYDROGEN PEROXIDE; SOLVENT; UNCLASSIFIED DRUG;

ARTICLE; CATALYSIS; CHEMICAL STRUCTURE; OXIDATION; REACTION ANALYSIS; STRUCTURE ANALYSIS;

EID: 0032988243     PISSN: 03082342     EISSN: None     Source Type: Journal    
DOI: 10.1039/a809937e     Document Type: Article

References (23)

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22. Selectivity represents the yield based on the amount of substrate consumed.
23. Following a referee's remark regarding the recoverability of the solvent, preparative experiments were carried out using 8 mmol of indan-1-ol in 80 ml of BTF. Some BTF (55-60 ml) was thus recovered by distillation of the filtrate under atmospheric pressure. After complete evaporation of the solvent under reduced pressure, the residue was subjected to flash chromatography, eluting with EtOAc-light petroleum (bp 30-60°C) (20/80).