Evidence for a continuous transition from nonadiabatic to adiabatic proton transfer dynamics in protic liquids

Journal of Physical Chemistry A

Volumn 105, Issue 13, 2001, Pages 2980-2988

  Cohen, Boiko ^a   Huppert, Dan ^a  

^a TEL AVIV UNIVERSITY   (Israel)

Author keywords

[No Author keywords available]

Indexed keywords

ADIABATIC PROTON TRANSFER; REVERSIBLE REACTIONS;

ACIDS; ALCOHOLS; APPROXIMATION THEORY; BOUNDARY CONDITIONS; GLYCEROL; LIQUIDS; NUMERICAL METHODS; PROTONS; RATE CONSTANTS; SOLVENTS; THERMAL EFFECTS;

DISSOCIATION;

EID: 0035810447     PISSN: 10895639     EISSN: None     Source Type: Journal    
DOI: 10.1021/jp002979g     Document Type: Article

References (54)

1. Ireland, J. F.; Wyatt, P. A. H. Adv. Phys. Org. Chem. 1976, 12, 131.
2. Huppert, D.; Gutman, M.; Kaufmann, K. J. In Advances in Chemical Physics; Jortner, J., Levine, R. D., Rice, S. A., Eds.; Wiley: New York, 1981; Vol. 47, 681.
3. Koswer, E.; Huppert, D. In Annual Reviews of Physical Chemistry; Strauss, H. L.; Babcok, G. T., Moore, C. B., Eds.; Annual Reviews Inc: 1986; Vol. 37, 122.
4. Lee, J.; Robinson, G. W.; Webb, S. P.; Philips, L. A.; Clark, J. H. J. Am. Chem. Soc. 1986, 705, 6538.
5. Gutman, M.; Nachliel, E. Biochim. Biophys. Ada 1990,391, 1015.
6. Forster, T. Z. Natuwissenschaft 1949, 36, 186.
7. Weller, A. Progress Reaction Kinetics 1961, 1, 189.
8. Kolodny, E.; Huppert, D. J. Chem. Phys. 1981, 63, 401.
9. Ando, K.; Hynes, J. T. In Structure, Energetics and Reactivity in Aqueous Solution; Cramer, C. J., Truhlar, D. G., Eds.; ACS Books: Washington, DC, 1994.
10. Agmon, N.; Huppert, D.; Masad, A.; Pines, E. J. Phys. Chem. 1991, 96, 952.
11. Knochenmuss, R. Chem. Phys. Lett. 1998, 293, 191.
12. Hineman, M. F.; Brucker, G. A.; Kelley, D. F.; Bernstein, E. R. J. Chem. Phys. 1992, 97, 3341.
13. Peters, K. S.; Cashin, A.; Timbers, P. J. Am. Chem. Soc. 2000, 122, 107.
14. Syage, J. A. J. Phys. Chem. 1995, 99, 5772.
15. Gandour, R. D.; Schowen, R. L. Transition States of Biochemical Processes; Plenum: New York, 1978.
16. Bell, R. P. The Tunnel Effect in Chemistry; Chapman and Hall; London, 1980.
17. Westheimer, F. H. Chem. Rev. 1961, 61, 265.
18. Bell, R. P. The Proton in Chemistry; Cornell University Press: Ithaca, 1973.
19. German, E. D.; Kuznetsov, A. M.; Dogonadze, R. R. J. Chem. Soc., Faraday Trans. 2 1980, 76, 1128.
20. Ulstrup, J. Charge-Transfer Processes in Condensed Media; Springer: Berlin, 1979.
21. Borgis, D.; Hynes, J. T. J. Phys. Chem. 1996, 700, 1118.
22. Borgis, D. C.; Lee, S.; Hynes, J. T. Chem. Phys. Lett. 1989, 762, 19.
23. Borgis, D.; Hynes, J. T. J. Chem. Phys. 1991, 94, 3619.
24. Cukier, R. I.; Morillo, M. J. Chem. Phys. 1989, 91, 857.
25. Morillo, M.; Cukier, R. I. J. Chem. Phys. 1990, 92, 4833.
26. Li, D.; Voth, G. A. J. Phys. Chem. 1991, 95, 10425.
27. Lobaugh, J.; Voth, G. A. J. Chem. Phys. 1994, 700, 3039.
28. Cohen, B.; Huppert, D. J. Phys. Chem. A 2000, 104, 2663.
29. Tolbert, L. M.; Haubrich, J. E. J. Am. Chem. Soc. 1990, 772,8163.
30. Tolbert, L. M.; Haubrich, J. E. 7. Am. Chem. Soc. 1994, 770, 10 593.
31. Pines, E.; Huppert, D.; Agmon, N. J. Chem. Phys. 1988,88,5620.
32. Agmon, N.; Pines, E.; Huppert, D. J. Chem. Phys. 1988, 88, 5631.
33. Debye, P. Trans. Electrochem. Soc. 1942, 82,265.
34. Carmeli, I.; Huppert, D.; Tolbert, L. M.; Haubrich, J. E. Chem. Phys. Lett. 1996, 260, 109
35. Erdey-Gruz, T.; Lengyel, S. In Modem Aspects of Electrochemistry, Bockris, J. O'M., Conway, B. E., Eds.; Plenum: New York, 1964; Vol. 12, pp 1-40.
36. Dolgin, B. MSc Thesis, Ben-Gurion University, Beer Sheva, 1997.
37. Landolt-Bornstein, Vol.2, Part 5a: Andrussow, L.; Schramm, B. Eds.; K. Schaffer, Springer, Berlin, 1969.
38. Kichert, R. unpublished results; Botcher, C. J. F.; Bordevik, P. Theory of Electric Polarization; Elsevier, Amsterdam, 1978; Vol. II, p 254.
39. Bertolini, D.; Cassettari, M.; Salvetti, G. J. Chem. Phys. 1983, 78, 365.
40. Garg, S. K.; Smyth, C. P. J. Phys. Chem. 1965, 69, 1294.
41. Agmon, N.; Goldberg, S. Y.; Huppert, D. J. Molecular Liquids 1995, 64, 161.
42. Kreevoy, M. M.; Kotchevar, A. T. J. Am. Chem. Soc. 1990, 112, 3579;
43. Kotchevar, A. T.; Kreevoy, M. M. /. Phys. Chem. 1991, 95, 10 345.
44. Poles, E.; Cohen, B.; Huppert, D. Israel J of Chem 1999,39: (34) 347.
45. Agmon, N.; Levine, R. D. Chem. Phys. Lett. 1977,52,197.
46. Agmon, N.; Levine, R. D. Israel J. Chem. 1980, 19, 330.
47. Pines, E.; Fleming, G. R. Chem. Phys. Lett. 1994,183, 393.
48. Pines, E.; Magnes, B.; Lang, M. J.; Fleming, G. R. Chem. Phys. Lett. 1997, 281, 413.
49. Solntsev, K.; Huppert, D.; Agmon, N. J. Phys. Chem. A 1999,103, 6984.
50. Jimenez, R.; Fleming, G. R.; Kumar, P. V.; Maroncelli, M. Nature 1994, 309, 471.
51. Agmon, N.; Rabinovich, S. J. Phys. Chem. 1992, 97, 7270.
52. Bicout, D. J.; Szabo, A. J. Chem. Phys. 1998, 109, 2325.
53. Chudoba, C.; Riedle, E.; Pfeiffer, M.; Elsaesser, T. Chem. Phys. Lett. 1996, 263, 622.
54. Rips, L; Jortner, J. J. Chem. Phys. 1987, 87, 2090.