Synthesis, structure, and solution dynamics of indenyl rhodium complexes containing bulky phosphine ligands

Canadian Journal of Chemistry

Volumn 77, Issue 2, 1999, Pages 205-215

  Westcott, Stephen A ^a,c   Kakkar, Ashok K ^a,d   Taylor, Nicholas J ^a   Roe, D Christopher ^b   Marder, Todd B ^a,e  

^a UNIVERSITY OF WATERLOO   (Canada)

^b DUPONT COMPANY   (United States)

^c MOUNT ALLISON UNIVERSITY   (Canada)

^d MCGILL UNIVERSITY   (Canada)

^e DURHAM UNIVERSITY   (United Kingdom)

Author keywords

Indenyl; Phosphines; Rhodium; Ring slippage

Indexed keywords

INDENYL RHODIUM; LIGAND; PHOSPHINE; RHODIUM; UNCLASSIFIED DRUG;

ARTICLE; CHEMICAL ANALYSIS; CHEMICAL BINDING; CHEMICAL REACTION KINETICS; CHEMICAL STRUCTURE; COMPLEX FORMATION; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; PROTON NUCLEAR MAGNETIC RESONANCE; REACTION ANALYSIS; STRUCTURE ANALYSIS; SYNTHESIS; X RAY DIFFRACTION;

EID: 0033046780     PISSN: 00084042     EISSN: None     Source Type: Journal    
DOI: 10.1139/cjc-77-2-205     Document Type: Article

References (55)

1. (a) R. Cramer, J.B. Kline, and J.D. Roberts. J. Am. Chem. Soc. 91, 2519 (1969);
2. (b) H. Eshtiagh-Hosseini and J.F. Nixon. J. Less Common Met. 61, 107 (1978);
3. (c) A. Borrini, P. Diversi, G. Ingrosso, A. Lucherini, and G. Serra. J. Mol. Catal. 30, 181 (1985);
4. (d) J.M. O'Connor and C.P. Casey. Chem Rev. 87, 307 (1987), and refs. therein for early metal indenyl chemistry.
5. (a) M.E. Rerek and F. Basolo. Organometallics, 3, 740 (1984);
6. (b) J. Am. Chem. Soc. 106, 5908 (1984).
7. (a) A. Habib, R.S. Tanke, E.M. Holtz, and R.H. Crabtree. Organometallics, 8, 1225 (1989);
8. (b) J.S. Merola and R.T. Kacmarcik. Organometallics, 8, 778 (1989);
9. (c) L.P. Szajek, R.J. Lawson, and J.R. Shapley. Organometallics, 10, 357 (1991);
10. (d) T. Foo and R.G. Bergman. Organometallics, 11, 1811 (1992);
11. (e) F. Morandini, G. Pilloni, G. Consiglio, A. Sironi, and M. Moret. Organometallics, 12, 3495 (1993);
12. (f) D. Rau and U. Behrens. J. Organomet. Chem. 454, 151 (1993);
13. (g) Z. Zhou, C. Jablonski, and J. Bridson. J. Organomet. Chem. 461, 215 (1993);
14. (h) M. Bassetti, L. Mannina, and D. Monti. Organometallics, 13, 3293 (1994);
15. (i) E. Hauptman, S. Sabo-Etienne, P.S. White, M. Brookhart, J.M. Garner, P.J. Fagan, and J.C. Calabrese. J. Am. Chem. Soc. 116, 8038 (1994);
16. (j) T. Le Husebo and C. M. Jensen. Organometallics, 14, 1087 (1995);
17. (k) M. Bassetti, P. Casellato, M.P. Gamasa, J. Gimeno, C. González-Bernardo, and B. Martín-Vaca. Organometallics, 16, 5470 (1997);
18. (l) M. Stradiotto, D.W. Hughes, A.D. Bain, M.A. Brook, and M.J. McGlinchey. Organometallics, 16, 5563 (1997);
19. (m) M.C. Comstock and J. R. Shapley. Organometallics, 16, 4816 (1997);
20. (n) R. Vollmerhaus, F. Bélanger-Gariépy, and D. Zargarian. Organometallics, 16, 4762 (1997);
21. (o) S-M. Yang, M.C-W. Chan, S-M. Peng, and C-M. Che. Organometallics, 17, 151 (1998);
22. (p) C.E. Garrett and G.C. Fu. J. Org. Chem. 63, 1370 (1998);
23. (q) M.J. Calhorda, C.A. Gamelas, I.S. Conçalves, E. Herdtweck, C.C. Romão, and L.F. Veiros. Organometallics, 17, 2597 (1998).
24. (a) A. Ceccon, A. Gambaro, S. Santi, G. Valle, and A. Venzo. J. Chem. Soc. Chem. Commun. 51 (1989);
25. (b) A. Ceccon, C.J. Elsevier, J.M. Ernsting, A. Gambaro, S. Santi, and A. Venzo. Inorg. Chim. Acta, 204, 15 (1993);
26. (c) C. Bonifaci, A. Ceccon, A. Gambaro, P. Ganis, L. Mantovani, and S. Santi. J. Organomet. Chem. 475, 267 (1994);
27. (d) C. Bonifaci, A. Ceccon, A. Gambaro, P. Ganis, S. Santi, G. Valle, and A. Venzo. J. Organomet. Chem. 492, 35 (1995);
28. (e) C. Bonifaci, A. Ceccon, A. Gambaro, P. Ganis, S. Santi, and A. Venzo. Organometallics, 14, 2430 (1995);
29. (f) C. Bonifaci, G. Carta, A. Ceccon, A. Gambaro, S. Santi, P. Ganis, and A. Venzo. Organometallics, 15, 1630 (1996);
30. (g) L. Mantovani, A. Ceccon, A. Gambaro, S. Santi, P. Ganis, and A. Venzo. Organometallics, 16, 2682 (1997);
31. (h) C. Amatore, A. Ceccon, S. Santi, and J.-N. Verpeaux. Chem. Eur. J. 3, 279 (1997);
32. (i) P. Cecchetto, A. Ceccon, A. Gambaro, S. Santi, P. Ganis, R. Gobetto, G. Valle, and A. Venzo. Organometallics, 17, 752 (1998).
33. (a) A.K. Kakkar, N.J. Taylor, and T.B. Marder. Organometallics, 8, 1765 (1989);
34. (b) S.A. Westcott, A.K. Kakkar, G. Stringer, N.J. Taylor, and T.B. Marder. J. Organomet. Chem. 394, 777 (1990), and refs. therein;
35. (c) A.K. Kakkar, N.J. Taylor, T.B. Marder, J.K. Shen, N. Hallinan, and F. Basolo. Inorg. Chim. Acta, 198-200, 219 (1992);
36. (d) D. O'Hare, J.C. Green, T.B. Marder, S. Collins, G. Stringer, A.K. Kakkar, N. Kaltsoyannis, A. Kuhn, R. Lewis, C. Mehnert, P. Scott, and S. Pugh. Organometallics, 11, 48 (1992);
37. (e) T.M. Frankcom, J.C. Green, A. Nagy, A.K. Kakkar, and T.B. Marder. Organometallics, 12, 3688 (1993);
38. (f) S.A. Westcott, G. Stringer, S. Anderson, N.J. Taylor, and T.B. Marder. Inorg. Chem. 33, 4589 (1994);
39. (g) A.K. Kakkar, G. Stringer, N.J. Taylor, and T.B. Marder. Can. J. Chem. 73, 981 (1995).
40. (a) R.D. Barr, M. Green, T.B. Marder, and F.G.A. Stone. J. Chem. Soc. Dalton Trans. 1261 (1984);
41. (b) R.T. Baker and T.H. Tulip. Organometallics, 5, 839 (1986);
42. (c) M. Mlekuz, P. Bougeard, B.G. Sayer, M.J. McGlinchey, C.A. Rodger, M.R. Churchill, J.W. Ziller, S-K. Kang, and T.A. Albright. Organometallics, 5, 1656 (1986);
43. (d) T.B. Marder, J.C. Calabrese, D.C. Roe, and T.H. Tulip. Organometallics, 6, 2012 (1987);
44. (e) A.K. Kakkar, N.J. Taylor, J.C. Calabrese, W.A. Nugent, D.C. Roe, E.A. Connaway, and T.B. Marder. J. Chem. Soc. Chem. Commun. 990 (1989);
45. (f) A. Ceccon, A. Gambaro, S. Santi, A. Venzo. J. Mol. Catal. 69, L1 (1991);
46. (g) L.P. Szajek, and J.R. Shapley. Organometallics, 13, 1395 (1994);
47. (h) T.A. Huber, M. Bayrakdarian, S. Dion, I. Dubuc, F. Bélanger-Gariépy, and D. Zargarian. Organometallics, 16, 5811 (1997).
48. (a) T.A. Albright and R. Hoffmann. Chem. Ber. 111, 1578 (1978);
49. (b) D.M.P. Mingos, M.I. Forsyth, and A.J. Welch. J. Chem. Soc. Dalton Trans. 1363 (1978).
50. D.T. Cromer and J.T. Waber. International Tables for X-ray Crystallography. Vol. 4. Kynoch Press, Birmingham. 1974. Table 2.2B.
51. P. Caddy, M. Green, L.E. Smart, and N. White. J. Chem. Soc. Chem. Commun. 839 (1978).
52. J. Chatt and L.A. Duncanson. J. Chem. Soc. 2939 (1953).
53. P.L. Holland, M.E. Smith, R.A. Anderson, and R.G. Bergman. J. Am. Chem. Soc. 119, 12 815 (1997).
54. F.H. Köhler. Chem. Ber. 107, 570 (1974).
55. J.S. Merola, R.T. Kacmarcik, and D. Van Engen. J. Am. Chem. Soc. 108, 329 (1986).