Mechanistic Studies on Halo-Ligand Substitution of Five-Coordinate Trigonal-Bipyramidal Palladium(II) Complexes of Tris(2-(diphenylphosphino)ethyl)phosphine with Trimethyl Phosphite in Chloroform at Various Temperatures and Pressures

Inorganic Chemistry

Volumn 35, Issue 18, 1996, Pages 5163-5167

  Aizawa, Sen Ichi ^a   Iida, Takashi ^a   Funahashi, Shigenobu ^a  

^a NAGOYA UNIVERSITY   (Japan)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0000534512     PISSN: 00201669     EISSN: None     Source Type: Journal    
DOI: 10.1021/ic9601596     Document Type: Article

References (18)

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11. Aizawa, S.; Funahashi, S. Anal. Sci. 1996, 12, 27.
12. It was confirmed by X-ray analyses of the sealed crystals that one acetonitrile molecule was contained in each formula unit of the halo complexes while elemental analyses of the air-dried samples did not show the corresponding nitrogen content with reproducible values. The loss of the acetonitrile molecules from the crystals hindered our density measurements.
13. Programs of a structure determination package from MAC Science, Yokohama, Japan, 1992.
14. International Tables for X-ray Crystallography, Kynoch: Birmingham, England, 1974; Vol. IV.
15. le Noble, W. J.; Schlott, R. Rev. Sci. Instrum. 1976, 47, 770.
16. Lever, A. B. P. Inorganic Electronic Spectroscopy, 2nd ed.; Elsevier: Amsterdam, 1984; Chapter 6.
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18. 2 should be much smaller than unity.