Organometallic compounds of the lanthanides Part CIXXX. Synthesis, structure and hydrolysis of 'moderately stable' hydrosilylation catalysts [(η5-C5H4SiMe3) 2Ln(μ-Me)]2 and [(η5-C5H4SiMet 2Bu)2Ln(μ-Me)]2

Journal of Organometallic Chemistry

Volumn 582, Issue 1, 1999, Pages 70-82

  Schumann, Herbert ^a   Keitsch, Markus R ^a   Demtschuk, Jörg ^a   Molander, Gary A ^b  

^a TECHNISCHE UNIVERSITÄT BERLIN   (Germany)

^b UNIVERSITY OF COLORADO   (United States)

Author keywords

Hydrosilylation; Metallocenes; Organolanthanide compounds; Organolutetium compounds; Organosamarium compounds; Organoyttrium compounds

Indexed keywords

STAPHYLOCOCCUS PHAGE 3A;

EID: 0001810242     PISSN: 0022328X     EISSN: None     Source Type: Journal    
DOI: 10.1016/S0022-328X(98)01188-7     Document Type: Article

References (48)

1. H. Schumann, E.C.E. Rosenthal, J. Demtschuk, G. Molander, Organometallics 17 (1998) 5324.
2. J.L. Speier, J.A. Webster, G.H. Barnes, J. Am. Chem. Soc. 79 (1957) 974.
3. B. Marciniec, in: B. Cornilis, W.A. Herrmann (Eds.), Applied Homogeneous Catalysis with Organometallic Compounds, vol. 1, VCH, Weinheim, 1996, p. 487.
4. I.P. Beletskaya, A.Z. Voskoboynikov, I.N. Parshina, G.K.I. Magomedov, Izv. Akad. Nauk. SSSR Ser. Khim. (1990) 693; Bull. Acad. Sci. USSR Div. Chem. Sci. (1990) 613.
5. I.P. Beletskaya, A.Z. Voskoboynikov, I.N. Parshina, G.K.I. Magomedov, Izv. Akad. Nauk. SSSR Ser. Khim. (1990) 693; Bull. Acad. Sci. USSR Div. Chem. Sci. (1990) 613.
6. T. Sakakura, H.J. Lautenschlager, M. Tanaka, J. Chem. Soc. Chem. Commun. (1991) 40.
7. G.A. Molander, M. Julius, J. Org. Chem. 57 (1992) 6347.
8. G.A. Molander, P.J. Nichols, J. Am. Chem. Soc. 117 (1995) 4415.
9. P.F. Fu, L. Brard, Y. Li, T.J. Marks, J. Am. Chem. Soc. 117 (1995) 7157.
10. G.A. Molander, W.H. Retsch, Organometallics 14 (1995) 4570.
11. G.A. Molander, P.J. Nichols, J. Org. Chem. 61 (1996) 6040.
12. G.A. Molander, J. Winterfeld, J. Organomet. Chem. 524 (1996) 275.
13. H. Schumann, M.R. Keitsch, J. Winterfeld, S. Mühle, G.A. Molander, J. Organomet. Chem. 559 (1998) 181.
14. G.A. Molander, W.H. Retsch, J. Am. Chem. Soc. 119 (1997) 8817.
15. S.P. Nolan, M. Porchia, T.J. Marks, Organometallics 10 (1991) 1450.
16. N.S. Radu, T.D. Tilley, J. Am. Chem. Soc. 117 (1995) 5863.
17. J.L. Atwood, W.E. Hunter, R.D. Rogers, J. Holton, J. McMeeking, R. Pearce, M.F. Lappert, J. Chem. Soc. Chem. Commun. (1978) 140.
18. M.F. Lappert, P.I.W. Yarrow, J.L. Atwood, R. Shakir, J. Holton, J. Chem. Soc. Chem. Commun. (1980) 987.
19. W.J. Evans, M.S. Sollberger, J.L. Shreeve, J.M. Olofson, J.H. Hain, J.W. Ziller, Inorg. Chem. 31 (1992) 2492.
20. M.R. Spirlet, J. Goffart, J. Organomet. Chem. 493 (1995) 149.
21. P.L. Watson, J.F. Whitney, R.L. Harlow, Inorg. Chem. 20 (1981) 3271.
22. A.Z. Voskoboynikov, I.N. Parshina, A.K. Shestakova, K.P. Butin, I.P. Beletskaya, L.G. Kuzmina, J.A.K. Howard, Organometallics 16 (1997) 4041.
23. D.G.H. Ballard, A. Courtis, J. Holton, J. McMeeking, R. Pearce, J. Chem. Soc. Chem. Commun. (1978) 994.
24. W.J. Evans, M.A. Hozbor, S.G. Bott, G.H. Robinson, J.L. Atwood, Inorg. Chem. 27 (1988) 1990.
25. W.A. Herrmann, R. Anwander, M. Kleine, K. Öfele, J. Riede, W. Scherer, Chem. Ber. 125 (1992) 2391.
26. H. Schumann, F.H. Görlitz, F.E. Hahn, J. Pickardt, S. Qian, Z. Xie, Z. Anorg. Allg. Chem. 609 (1992) 131.
27. P.B. Hitchcock, M.F. Lappert, S. Prashar, J. Organomet. Chem. 413 (1991) 79.
28. I.P. Beletskaya, A.Z. Voskoboynikov, E.B. Chuklanova, N.I. Kirillova, A.K. Shestakova, I.N. Parshina, A.I. Gusev, G.K.I. Magomedov, J. Am. Chem. Soc. 115 (1993) 3156.
29. D. Deng, F. Song, Z. Wang, C. Qian, G. Wu, P. Zheng, Polyhedron 11 (1992) 2883.
30. D. Deng, Y. Jiang, C. Qian, G. Wu, P. Zheng, J. Organomet. Chem. 470 (1994) 99.
31. H. Schumann, J. Loebel, J. Pickardt, C. Qian, Z. Xie, Organometallics 10 (1991) 215.
32. L. Zsolnai, H. Pritzkow, ZORTEP, ORTEP Program for PC, Universität Heidelberg, 1994.
33. M.F. Lappert, A. Singh, J.L. Atwood, W.E. Hunter, J. Chem. Soc. Chem. Commun. (1981) 1190.
34. J. Holton, M.F. Lappert, D.G. Ballard, R. Pearce, J.L. Atwood, W.E. Hunter, J. Chem. Soc. Dalton Trans. (1979) 54.
35. W.J. Evans, D.K. Drummond, T.P. Hanusa, R.J. Doedens, Organometallics 6 (1987) 2279.
36. M.A. Edelmann, P.B. Hitchcock, M.F. Lappert, D.S. Liu, S. Tian, J. Organomet. Chem. 550 (1989) 397.
37. R.B. King, F.G.A. Stone, Inorg. Synth. 7 (1963) 99.
38. E.W. Abel, M.O. Dunster, A. Waters, J. Organomet. Chem. 49 (1973) 287.
39. x adducts with the given amount of THF.
40. M. Veith, H. Bärninghausen, Acta Crystallogr. B 30 (1974) 1806.
41. M. Kretschmar, CAD4/PC-Version 1994, University of Tübingen.
42. G.M. Sheldrick, SHELXS 86 Program for Crystal Structure Determination, Universität Göttingen, 1986.
43. G.M. Sheldrick, SHELXL 93 Program for Crystal Structure Determination, Universität Göttingen, 1993.
44. (a) D.T. Cromer, J.B. Mann, Acta Crystallogr. A 24 (1986) 321.
45. (b) D.T. Cromer, D. Libermann, J. Chem. Phys. 53 (1970) 1891.
46. (c) R.F. Stewart, E.R. Davidson, W.T. Simpson, J. Chem. Phys. 42 (1965) 3175.
47. N. Walker, D. Stuart, Acta Crystallogr. A 39 (1983) 158.
48. A.L. Spek, PLUTON, University of Utrecht, 1992.