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Volumn 20, Issue 24, 2001, Pages 4996-4998

Ruthenium amidinato-carbene complexes containing a Ru-Si bond: Formation and reversible α-silyl group migration from the metal to the carbene ligand

Author keywords

[No Author keywords available]

Indexed keywords

CARBENE LIGAND; PHOTOCHEMICAL DISSOCIATION; RUTHENIUM AMIDINATO CARBENE COMPLEXES;

EID: 0035956446     PISSN: 02767333     EISSN: None     Source Type: Journal    
DOI: 10.1021/om010775w     Document Type: Article
Times cited : (17)

References (45)
  • 1
    • 0000714026 scopus 로고    scopus 로고
    • Poli, R. Chem. Rev. 1996, 96, 2135-2204.
    • (1996) Chem. Rev. , vol.96 , pp. 2135-2204
    • Poli, R.1
  • 17
    • 0001089904 scopus 로고
    • (b) Sutton, D. Chem. Rev. 1993, 93, 995-1022.
    • (1993) Chem. Rev. , vol.93 , pp. 995-1022
    • Sutton, D.1
  • 29
    • 0025511284 scopus 로고
    • Although α-silyl migration is well investigated in main group organometallic chemistry, it is rarely observed in the organotransition metal chemistry. The only example for silyl group migration from a metal to a carbene ligand: Berry, D. H.; Koloski, T. S.; Carroll, P. J. Organometallics 1990, 9, 2952-2962.
    • (1990) Organometallics , vol.9 , pp. 2952-2962
    • Berry, D.H.1    Koloski, T.S.2    Carroll, P.J.3
  • 30
    • 0000835395 scopus 로고
    • Reversible migration reactions of a silyl group from a metal to a silylene ligand: Sharma, H. K.; Pannell, K. H. Chem. Rev. 1995, 95, 1351-1374.
    • (1995) Chem. Rev. , vol.95 , pp. 1351-1374
    • Sharma, H.K.1    Pannell, K.H.2
  • 31
    • 0011510680 scopus 로고    scopus 로고
    • note
    • 3), 10.7 (s, 1H; Ru=CH). Other data are given in the Supporting Information.
  • 32
    • 0011414396 scopus 로고    scopus 로고
    • note
    • int = 0.000), 4542 observed (>2σ), final residuals R1 = 0.0601, wR2 = 0.1581 (I > 2σ(I)); R1 = 0.0869, wR2 = 0.1782 (all data).
  • 40
    • 0011465651 scopus 로고    scopus 로고
    • note
    • -1 (CO). Other data are given in the Supporting Information.
  • 41
    • 0011504626 scopus 로고    scopus 로고
    • note
    • int = 0.000), 2155 observed (>2σ), final residuals R1 = 0.0498, wR2 = 0.1263 (I > 2σ(I)); R1 = 0.1777, wR2 = 0.1730 (all data).
  • 42
    • 0011465652 scopus 로고    scopus 로고
    • note
    • 1H NMR measurement at -80 °C. Only 3a was observed as the organometallic product.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.