Mechanistic and thermodynamic aspects of methylene transfer from CH2N2 to MHCl(CO)L2 (M = Ru, Os; L = tertiary phosphine): Non-least motion behavior and extreme dependence on phosphine identity

New Journal of Chemistry

Volumn 22, Issue 10, 1998, Pages 1023-1025

  Huang, Dejian ^a   Spivak, Greg J ^a   Caulton, Kenneth G ^a  

^a INDIANA UNIVERSITY   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0000705575     PISSN: 11440546     EISSN: None     Source Type: Journal    
DOI: 10.1039/a803432j     Document Type: Article

References (13)

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2. -1): v(CO) = 1883s).
3. 2Me).
4. D. Huang, W. E. Streib, O. Eisenstein and K. G. Caulton, Angew. Chem., Int. Ed. Engl., 1997, 36, 2004.
5. D. White and N. J. Coville, Adv. Organomet. Chem., 1994, 36, 95.
6. i methine hydrogens. See M. A. Esteruelas and H. Werner, J. Organomet. Chem., 1986, 303, 221.
7. 2 and MeLi. D. Huang and K. G. Caulton, to be submitted.
8. 2Me. See C. Li, M. Oliván, S. P. Nolan and K. G. Caulton, Organometallics, 1997, 16, 4223;
9. C. Li, M. Ogasawara, S. P. Nolan and K. G. Caulton, Organometallics, 1996, 15, 4900.
10. 3.
11. G. J. Spivak, J. N. Coalter, M. Oliván, O. Eisenstein and K. G. Caulton, Organometallics, 1998, 17, 999.
12. D. Huang and K. G. Caulton, J. Am. Chem. Soc., 1997, 119, 3185.
13. E. L. Dias, S. T. Nguyen and R. H. Grubbs, J. Am. Chem. Soc., 1997, 119, 3887.