CH bond activation in cations of the type {[(2,4,6-Me3 C6H2NCH2CH2)2NMe] ZrR}+ and a simple solution that yields a catalyst for the living polymerization of 1-hexene

Organometallics

Volumn 20, Issue 6, 2001, Pages 1056-1058

  Schrock, Richard R ^a   Bonitatebus Jr , Peter J ^a   Schrodi, Yann ^a  

^a Massachusetts Institute of Technology Cambridge   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

CHLOROBENZENE; HEXENE;

CATALYSTS; CHEMICAL ACTIVATION; CHEMICAL BONDS; CHLORINE COMPOUNDS; COMPLEXATION; CRYSTALLIZATION; DECOMPOSITION; MOLECULAR STRUCTURE; MOLECULAR WEIGHT; POLYMERIZATION; POSITIVE IONS; X RAY CRYSTALLOGRAPHY;

ZIRCONIUM COMPOUNDS;

EID: 0035911999     PISSN: 02767333     EISSN: None     Source Type: Journal    
DOI: 10.1021/om000972f     Document Type: Article

References (27)

1. Scollard, J. D.; McConville, D. H.; Vittal, J. J. Organometallics 1997, 16, 4415.
2. Scollard, J. D.; McConville, D. H.; Vittal, J. J.; Payne, N. C. J. Mol. Catal. A 1998, 128, 201.
3. Guérin, F.; Del Vecchio, G.; McConville, D. H. Polyhedron 1998, 17, 917.
4. Guérin, F.; McConville, D. H.; Vittal, J. J.; Yap, G. A. P. Organometallics 1998, 17, 5172.
5. Aoyagi, K.; Gantzel, P. K.; Kalai, K.; Tilley, T. D. Organometallics 1996, 15, 923.
6. Warren, T. H.; Schrock, R. R.; Davis, W. M. Organometallics 1998, 17, 308.
7. Cloke, F. G. N.; Geldbach, T. J.; Hitchcock, P. B.; Love, J. B. J. Organomet. Chem. 1996, 506, 343.
8. Clark, H. C. S.; Cloke, F. G. N.; Hitchcock, P. B.; Love, J. B.; Wainwright, A. P. J. Organomet. Chem. 1995, 501, 333.
9. Herrmann, W. A.; Denk, M.; Albach, R. W.; Behm, J.; Herdtweck, E. Chem. Ber. 1991, 124, 683.
10. Horton, A. D.; de With, J.; van der Linden, A. J.; van de Weg, H. Organometallics 1996, 15, 2672.
11. Friedrich, S.; Schubart, M.; Gade, L. H.; Scowen, I. J.; Edwards, A. J.; McPartlin, M. Chem. Ber. Rec. 1997, 130, 1751.
12. Jeon, Y.-M.; Park, S. J.; Heo, J.; Kim, K. Organometallics 1998, 17, 3161.
13. Male, N. A. H.; Thornton-Pett, M.; Bochmann, M. J. Chem. Soc., Dalton Trans. 1997, 2487.
14. Tinkler, S.; Deeth, R. J.; Duncalf, D. J.; McCamley, A. Chem. Commun. 1996, 2623.
15. Tsuie, B.; Swenson, D. C.; Jordan, R. F.; Petersen, J. L. Organometallics 1997, 16, 1392.
16. Kempe, R. Angew. Chem., Int. Ed. 2000, 39, 468.
17. Ziniuk, Z.; Goldberg, I.; Kol, M. Inorg. Chem. Commun. 1999, 2, 549.
18. Armistead, L. T.; White, P. S.; Gagne, M. R. Organometallics 1998, 17, 216.
19. Fryzuk, M. D.; Love, J. B.; Rettig, S. J. Organometallics 1998, 17, 846.
20. Baumann, R.; Schrock, R. R. J. Organomet. Chem. 1998, 557, 69.
21. Schrock, R. R.; Baumann, R.; Reid, S. M.; Goodman, J. T.; Stumpf, R.; Davis, W. M. Organometallics 1999, 18, 3649.
22. Aizenberg, M.; Turculet, L.; Davis, W. M.; Schattenmann, F. S.; Schrock, R. R. Organometallics 1998, 17, 4795.
23. Schrock, R. R.; Casado, A. L.; Goodman, J. T.; Liang, L.-C.; Bonitatebus, P. J., Jr.; Davis, W. M. Organometallics 2000, 19, 5325.
24. Liang, L.-C.; Schrock, R. R.; Davis, W.M.; McConville, D. H. J. Am. Chem. Soc. 1999, 120, 5797.
25. 2- ligands (R = isopropyl, cyclohexyl, or mesityl) appear to be catalysts only for the oligomerization of 1-hexene as a consequence of β hydride elimination.
26. -3.
27. T/k;(obs) vs [B] gives 1/k and K/k.