CH bond activation in cations of the type {[(2,4,6-Me3 C6H2NCH2CH2)2NMe] ZrR}+ and a simple solution that yields a catalyst for the living polymerization of 1-hexene

Organometallics

Volumn 20, Issue 6, 2001, Pages 1056-1058

  Schrock, Richard R ^a   Bonitatebus Jr , Peter J ^a   Schrodi, Yann ^a  

^a USA   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

CHLOROBENZENE; HEXENE;

CATALYSTS; CHEMICAL ACTIVATION; CHEMICAL BONDS; CHLORINE COMPOUNDS; COMPLEXATION; CRYSTALLIZATION; DECOMPOSITION; MOLECULAR STRUCTURE; MOLECULAR WEIGHT; POLYMERIZATION; POSITIVE IONS; X RAY CRYSTALLOGRAPHY;

ZIRCONIUM COMPOUNDS;

EID: 0035911999     PISSN: 02767333     EISSN: None     Source Type: Journal    
DOI: 10.1021/om000972f     Document Type: Article

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25. 2- ligands (R = isopropyl, cyclohexyl, or mesityl) appear to be catalysts only for the oligomerization of 1-hexene as a consequence of β hydride elimination.
26. -3.
27. T/k;(obs) vs [B] gives 1/k and K/k.