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0011459171
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note
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For the preparation of the alloy, sodium and potassium were place in a flask in an approximate weight ratio of Na/K = 1:10 under a dry argon atmosphere, and the flask was heated above the melting point of sodium (98 °C). When both of the metals melted, the flask was slowly swirled to prepare the alloy. After the flask was cooled to room temperature, THF predried by distillation from sodium was added into the flask.
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27
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0011459172
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note
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In ref 6, we described that the reaction of 3,3′-dilithio-5-5′-bis-(trimethylsilyl)-2,2′-bithiophene with diphenyldichlorosilane in ether afforded 4,4-diphenyl-2,6-bis(trimethylsilyl)dithienosilole. However, it should be carried out in a mixed solvent of ether/THF = 1:1-3:1 at the refluxing temperature.
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0004133516
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revision A.1; Gaussian, Inc.: Pittsburgh, PA
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