Polymeric organosilicon systems. 28. Preparation and properties of novel σ-π conjugated polymers with alternating disilanylene and 2,5-diethynylenesilole units in the backbone

Macromolecules

Volumn 31, Issue 22, 1998, Pages 7985-7987

  Ohshita, Joji ^a   Mimura, Nobuhisa ^a   Arase, Hidekazu ^a   Nodono, Mitsunori ^a   Kunai, Atsutaka ^a   Komaguchi, Kenji ^a   Shiotani, Masaru ^a   Ishikawa, Mitsuo ^b  

^a HIROSHIMA UNIVERSITY   (Japan)

^b KURASHIKI UNIVERSITY OF SCIENCE AND THE ARTS   (Japan)

Author keywords

[No Author keywords available]

Indexed keywords

CATALYSTS; COPPER COMPOUNDS; CYCLIC VOLTAMMETRY; ELECTRON ENERGY LEVELS; ENERGY GAP; MOLECULAR STRUCTURE; PALLADIUM COMPOUNDS; SILICON COMPOUNDS; THERMODYNAMIC STABILITY; THERMOGRAVIMETRIC ANALYSIS;

DEHYDROBROMINATION;

AROMATIC POLYMERS;

EID: 0032480690     PISSN: 00249297     EISSN: None     Source Type: Journal    
DOI: 10.1021/ma980107v     Document Type: Article

References (28)

1. For reviews, see (a) Ishikawa, M.; Ohshita, J. Silicon and Germanium Containing Conductive Polymers. In Handbook of Organic Conductive Molecules and Polymers; Nalwa, H. S., Ed.; Wiley New York, 1997; Vol. 2, Chapter 15. (b) Inorganic and Organometallic Polymers; Zeldin, M., Wynne, H. K. J., Allcock, R., Eds.; ACS Symposium Series 368; American Chemical Society: Washington, DC, 1988. (c) Silicon-Based Polymer Science; Zeigler, J. M., Fearon, F. W. G., Eds.; Advances in Chemistry Series 224; American Chemical Society: Washington, DC, 1990. (d) Ohshita, J.; Kunai, A. Acta Polym. 1998, 49, 379.
2. For reviews, see (a) Ishikawa, M.; Ohshita, J. Silicon and Germanium Containing Conductive Polymers. In Handbook of Organic Conductive Molecules and Polymers; Nalwa, H. S., Ed.; Wiley New York, 1997; Vol. 2, Chapter 15. (b) Inorganic and Organometallic Polymers; Zeldin, M., Wynne, H. K. J., Allcock, R., Eds.; ACS Symposium Series 368; American Chemical Society: Washington, DC, 1988. (c) Silicon-Based Polymer Science; Zeigler, J. M., Fearon, F. W. G., Eds.; Advances in Chemistry Series 224; American Chemical Society: Washington, DC, 1990. (d) Ohshita, J.; Kunai, A. Acta Polym. 1998, 49, 379.
3. For reviews, see (a) Ishikawa, M.; Ohshita, J. Silicon and Germanium Containing Conductive Polymers. In Handbook of Organic Conductive Molecules and Polymers; Nalwa, H. S., Ed.; Wiley New York, 1997; Vol. 2, Chapter 15. (b) Inorganic and Organometallic Polymers; Zeldin, M., Wynne, H. K. J., Allcock, R., Eds.; ACS Symposium Series 368; American Chemical Society: Washington, DC, 1988. (c) Silicon-Based Polymer Science; Zeigler, J. M., Fearon, F. W. G., Eds.; Advances in Chemistry Series 224; American Chemical Society: Washington, DC, 1990. (d) Ohshita, J.; Kunai, A. Acta Polym. 1998, 49, 379.
4. For reviews, see (a) Ishikawa, M.; Ohshita, J. Silicon and Germanium Containing Conductive Polymers. In Handbook of Organic Conductive Molecules and Polymers; Nalwa, H. S., Ed.; Wiley New York, 1997; Vol. 2, Chapter 15. (b) Inorganic and Organometallic Polymers; Zeldin, M., Wynne, H. K. J., Allcock, R., Eds.; ACS Symposium Series 368; American Chemical Society: Washington, DC, 1988. (c) Silicon-Based Polymer Science; Zeigler, J. M., Fearon, F. W. G., Eds.; Advances in Chemistry Series 224; American Chemical Society: Washington, DC, 1990. (d) Ohshita, J.; Kunai, A. Acta Polym. 1998, 49, 379.
5. (a) Ishikawa, M.; Nate, K. In Inorganic and Organometallic Polymers; Zeldin, M., Wynne, K. J., Allcock, H. R., Eds.; ACS Symposium Series 360, American Chemical Society: Washington, DC, 1988; Chapter 16.
6. (b) Ohshita, J.; Ishikawa, M. In Polymeric Materials Encyclopedia; Salamone, J. C., Ed.; CRC Press: New York, 1996; p 892, and references therein.
7. Ijadi-Maghsoodi, S.; Pang, Y.; Barton, T. J. J. Polym. Sci., Part A, Polym. Chem. 1990, 28, 955.
8. (a) Tamao K.; Ohno, S.; Yamaguchi, S. Chem. Commun. 1996, 1873.
9. (b) Tamao, K.; Uchida, M.; Izumikawa, T.; Furukawa, K.; Yamaguchi, S. J. Am. Chem. Soc. 1996, 118, 11974.
10. (c) Yamaguchi, S.; Tamao, K. Bull. Chem. Soc. Jpn. 1996, 69, 2327.
11. (d) Yamaguchi, S. Synth. Met. 1996, 82, 149.
12. For example, see (a) Corriu, R. J. P.; Douglas, W. E.; Yang, Z.-X. J. Organomet. Chem. 1993, 456, 35. (b) Corriu, R. J. P.; Nevylder, N.; Guérin, C.; Henner, B.; Jean, A. Organometallics 1994, 13, 3194. (c) Yamaguchi, S.; Jin, R. Z.; Tamao, K.; Shiro, M. Organometallics 1997, 16, 2486.
13. For example, see (a) Corriu, R. J. P.; Douglas, W. E.; Yang, Z.-X. J. Organomet. Chem. 1993, 456, 35. (b) Corriu, R. J. P.; Nevylder, N.; Guérin, C.; Henner, B.; Jean, A. Organometallics 1994, 13, 3194. (c) Yamaguchi, S.; Jin, R. Z.; Tamao, K.; Shiro, M. Organometallics 1997, 16, 2486.
14. For example, see (a) Corriu, R. J. P.; Douglas, W. E.; Yang, Z.-X. J. Organomet. Chem. 1993, 456, 35. (b) Corriu, R. J. P.; Nevylder, N.; Guérin, C.; Henner, B.; Jean, A. Organometallics 1994, 13, 3194. (c) Yamaguchi, S.; Jin, R. Z.; Tamao, K.; Shiro, M. Organometallics 1997, 16, 2486.
15. (a) Tamao, K.; Yamaguchi, S.; Shiozaki, M.; Nakagawa, Y.; Ito, Y. J. Am. Chem. Soc. 1992, 114, 5867.
16. (b) Tamao, K.; Yamaguchi, S.; Shiro, M. J. Am. Chem. Soc. 1994, 116, 11715.
17. (c) Tamao, K.; Yamaguchi, S.; Ito, Y.; Matsuzaki, Y.; Yamabe T.; Fukushima, M.; Mori, S. Macromolecules 1995, 28, 8668.
18. (d) Hong, S. Y.; Song, J. M. Chem. Mater. 1997, 9, 297.
19. Toyoda, E.; Kunai, A.; Ishikawa, M. Organometallics 1995, 14, 1089.
20. Ohshita J.; Nodono, M.; Watanabe, T.; Ueno, Y.; Kunai, A.; Harima, Y.; Yamashita, K.; Ishikawa, M. J. Organomet. Chem. 1998, 553, 487.
21. Synthesis of polymers having 2,5-diethynylenesuole units by Pd-catalyzed dehalostannylation of 2,5-dibromosilole with bis(stannylethynyl) derivatives has been reported, recently. See (a) Chen, W.; Ijadi-Maghsoodi, S.; Barton T. J. Polym. Prepr. (Am. Chem. Soc., Div. Polym. Chem.) 1997, 38, 189. (b) Yamaguchi, S.; Iimura, K.; Tamao, K. Chem. Lett. 1998, 89.
22. Synthesis of polymers having 2,5-diethynylenesuole units by Pd-catalyzed dehalostannylation of 2,5-dibromosilole with bis(stannylethynyl) derivatives has been reported, recently. See (a) Chen, W.; Ijadi-Maghsoodi, S.; Barton T. J. Polym. Prepr. (Am. Chem. Soc., Div. Polym. Chem.) 1997, 38, 189. (b) Yamaguchi, S.; Iimura, K.; Tamao, K. Chem. Lett. 1998, 89.
23. (a) Chen, R.-M.; Chien, K.-M.; Wong, K.-T.; Jin, B.-Y.; Luh, T. Y. J. Am. Chem. Soc. 1997, 119, 11321.
24. (b) van Walree, C. A.; Roest, M. R.; Schuddeboom, W.; Jenneskens, L. W.; Verhoeven J. W.; Warman, J. M.; Kooijman, H.; Spek, A. L. J. Am. Chem. Soc. 1996, 118, 8395.
25. Kunai, A.; Ueda, T.; Horata, K.; Toyoda, E.; Ohshita, J.; Ishikawa, M.; Tanaka, K. Organometallics 1996, 15, 2000.
26. Ohshita, J.; Watanabe, T.; Kanaya, D.; Ohsaki, H.; Ishikawa, M.; Ago, H.; Tanaka, K.; Yamabe, T. Organometallics 1994, 13, 5002.
27. The redox potential of Fe(III)/Fe(II) in an aqueous media is at 0.5 V vs SCE. See Handbook of Chemistry and Physics, 76th ed.; Lide, D. R., Ed.; CRC Press: Boca Raton, FL, 1995.
28. Yuan, C.-H.; West, R. Appl. Organomet. Chem. 1994, 8, 423.