Five-coordinate 16-electron carbene- and vinylideneruthenium(II) complexes prepared from [RuCl2(C8H12)]n or from the new dihydridoruthenium(IV) compound [RuH2Cl2(PiPr3)2]

Organometallics

Volumn 15, Issue 8, 1996, Pages 1960-1962

  Grünwald, Claus ^a   Gevert, Olaf ^a   Wolf, Justin ^a   González Herrero, Pablo ^a,b   Werner, Helmut ^a  

^a UNIVERSITY OF WÜRZBURG   (Germany)

^b UNIVERSITY OF MURCIA   (Spain)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0000851147     PISSN: 02767333     EISSN: None     Source Type: Journal    
DOI: 10.1021/om9509554     Document Type: Article

References (34)

1. (a) Aracama, M.; Esteruelas, M. A.; Lahoz, F. J.; Lopez, J. A.; Meyer, U.; Oro, L. A.; Werner, H. Inorg. Chem. 1991, 30, 288-293.
2. (b) Meyer, U. Dissertation, University of Würzburg, 1988.
3. Espuelas, J.; Esteruelas, M. A.; Lahoz, F. J.; Oro, L. A.; Ruiz, N. J. Am. Chem. Soc. 1993, 115, 4683-4689.
4. (a) Werner, H.; Stark, A.; Schulz, M.; Wolf, J. Organometallics 1992, 11, 1126-1130.
5. (b) Werner, H.; Stark, A.; Steinert, P.; Grünwald, C.; Wolf, J. Chem. Ber. 1995, 128, 49-62.
6. (c) Martin, M.; Gevert, O.; Werner, H. J. Chem. Soc., Dalton Trans., in press.
7. Albers, M. O.; Singleton, E.; Yates, J. E. Inorg. Synth. 1989, 26, 253.
8. 2): δ 103.2 (s).
9. 6c and dimeric hydridoruthenium compounds.
10. (b) Burrow, T.; Sabo-Etienne, S.; Chaudret, B. Inorg. Chem. 1995, 34, 2470-2472.
11. (c) Christ, M. L.; Sabo-Etienne, S.; Chaudret, B. Organometallics 1994, 13, 3800-3804.
12. Esteruelas, M. A.; Werner, H. J. Organomet. Chem. 1986, 303, 221-231.
13. -3.
14. (b) Sheldrick, G. M. SHELXS-86; Universität Göttingen, Göttingen, Germany, 1986.
15. (c) Sheldrick, G. M. SHELXL-93; Universität Göttingen, Göttingen, Germany, 1993.
16. 2)/3.
17. (a) Pertici, P.; Vitulli, G.; Porzio, W.; Zocchi, M. Inorg. Chim. Acta 1979, 37, L521-L522.
18. (b) Bruno, J. W.; Huffman, J. C.; Caulton, K. G. Inorg. Chim. Acta 1984, 89, 167-173.
19. (c) Suzuki, H.; Lee, D. H.; Oshima, N.; Moro-oka, Y. Organometallics 1987, 6, 1569-1575.
20. (d) Jia, G.; Meek, D. W.; Gallucci, J. C. Inorg. Chem. 1991, 30, 403-410.
21. (e) Hartwig, J. F.; Andersen, R. A.; Bergman, R. G. Organometallics 1991, 10, 1875-1887.
22. 6): δ 29.0 (s).
23. Bruce, M. I. Chem. Rev. 1991, 91, 197-257.
24. Wakatsuki, Y.; Yamazaki, H.; Kumegawa, N.; Satoh, T.; Satoh, J. Y. J. Am. Chem. Soc. 1991, 113, 9604-9610.
25. 6): δ 44.7 (s).
26. (a) Nguyen, S. T.; Johnson, L. K.; Grubbs, R. H. J. Am. Chem. Soc. 1992, 114, 3974-3975.
27. (b) Schwab, P.; France, M. B.; Ziller, J. W.; Grubbs, R. H. Angew. Chem. 1995, 107, 2179-2181; Angew. Chem., Int. Ed. Engl. 1995, 34, 2039-2041.
28. (b) Schwab, P.; France, M. B.; Ziller, J. W.; Grubbs, R. H. Angew. Chem. 1995, 107, 2179-2181; Angew. Chem., Int. Ed. Engl. 1995, 34, 2039-2041.
29. Nguyen, S. T.; Grubbs, R. H.; Ziller, J. W. J: Am. Chem. Soc. 1993, 115, 9858-9859.
30. -3.
31. Esteruelas, M. A.; Lahoz, F. J.; Onate, E.; Oro, L. A.; Valero, C.; Zeier, B. J. Am. Chem. Soc. 1995, 117, 7935-7942.
32. 6): δ 45.35 (s).
33. (a) Bohle; D. S.; Clark, G. R.; Rickard, C. E. F.; Roper, W. R.; Wright, L. J. J. Organomet. Chem. 1988, 358, 411-447.
34. (b) Clark, G. R.; Hodgson, D. J.; Ng, M. M. P.; Rickard, C. E. F.; Roper, W. R.; Wright, L. J. J. Chem. Soc., Chem. Commun. 1988, 1552-1554.