Inducing and observing the abstraction of a single hydrogen atom in bimolecular reactions with a scanning tunneling microscope

Journal of Physical Chemistry B

Volumn 105, Issue 18, 2001, Pages 3987-3992

  Lauhon, L J ^a   Ho, W ^a  

^a Laboratory of Atomic and Solid State Physics and Sibley School of Mechanical and Aerospace Engineering   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

BIMOLECULAR RECATIONS; HYDROGEN ABSTRACTION; HYDROGEN ATOMS;

COPPER; ELECTRONS; HYDROGEN; HYDROGEN SULFIDE; REACTION KINETICS; SCANNING TUNNELING MICROSCOPY; TEMPERATURE; THERMAL DIFFUSION; WATER;

ATOMS;

EID: 0035837982     PISSN: 10895647     EISSN: None     Source Type: Journal    
DOI: 10.1021/jp002484r     Document Type: Article

References (38)

1. Thiel, P. A.; Madey, T. E. Surf. Sci. Rep. 1987, 7, 211.
2. Newsome, D. S. Catal. Rev.-Sci. Eng. 1980, 21, 275.
3. Besenbacher, F. Rep. Prog. Phys. 1996, 59, 1737.
4. Gaigneaux, E. M. Curr. Opin. Solid State Mater. Sci. 1998, 3, 343.
5. Ho, W. Acc. Chem. Res. 1998, 31, 567.
6. Ertl, G.; Freund, H. J. Phys. Today 1999, 52, 32.
7. Leibsle, F. M.; Murray, P. W.; Francis, S. M.; Thornton, G.; Bowker, M. Nature 1993, 363, 706.
8. Leibsle, F. M.; Francis, S. M.; Davis, R.; Xiang, N.; Haq, S.; Bowker, M. Phys. Rev. Lett. 1994, 72, 2569.
9. Ruan, L.; Besenbacher, F.; Stensgaard, I.; Lægsgaard, E. Phys. Rev. Lett. 1992, 69, 3523.
10. Ruan, L.; Stensgaard, I.; Lægsgaard, E.; Besenbacher, F. Surf. Sci. 1994, 314, L873.
11. Völkening, S.; Bedürftig, K.; Jacobi, K.; Wintterlin, J.; Ertl, G. Phys. Rev. Lett. 1999, 83, 2672.
12. Bedürftig, K.; Völkening, S.; Wang, Y.; Wintterlin, J.; Jacobi, K.; Ertl, G. J. Chem. Phys. 1999, 111, 11147.
13. Wintterlin, J.; Völkening, S.; Janssens, T. V. W.; Zambelli, T.; Ertl, G. Science 1997, 278, 1931.
14. Crew, W. W.; Madix, R. J. Surf. Sci. 1994, 319, L34.
15. Zambelli, T.; Wintterlin, J.; Trost, J.; Ertl, G. Science 1996, 273, 1688.
16. Rezaei, M. A.; Stipe, B. C.; Ho, W. J. Phys. Chem. B 1998, 102, 10941.
17. Stipe, B. C.; Rezaei, M. A.; Ho, W. J. Chem. Phys. 1997, 107, 6443.
18. Stipe, B. C.; Rezaei, M. A.; Ho, W. Science 1998, 280, 1732.
19. Lauhon, L. J.; Ho, W. Phys. Rev. Lett. 2000, 84, 1527.
20. Stipe, B. C.; Rezaei, M. A.; Ho, W. Rev. Sci. Instrum. 1999, 70, 137.
21. Lauhon, L. J.; Ho, W. J. Chem. Phys. 1999, 111, 5633.
22. The charge density at the Cu(001) surface is very smooth, and as a result, the lattice is usually not resolved in STM images. Occasionally, adsorption of an unknown impurity at the end of the tip led to enhanced corrugation in the STM image and resolution of the copper lattice atoms. The adsorption sites of adsorbates were thereby determined.
23. Rodriguez, J. A. Surf. Sci. 1990, 234, 421.
24. Andersson, S.; Nyberg, C.; Tengstål, C. G. Chem. Phys. Lett. 1984, 104, 305.
25. Brosseau, R.; Brustein, M. R.; Ellis, T. H. Surf. Sci. 1993, 294, 243.
26. Ellis, T. H.; Kruus, E. J.; Wang, H. J. Vac. Sci. Technol., A 1993, 11, 2117.
27. Ikemiya, N.; Gewirth, A. A. J. Am. Chem. Soc. 1997, 119, 9919.
28. Sueyoshi, T.; Sasaki, T.; Iwasawa, Y. J. Phys. Chem. B 1997, 101, 4648.
29. Lauhon, L. J.; Ho, W. Phys. Rev. Lett. 2000, 85, 4566.
30. Yang, H.; Whitten, J. L. Surf. Sci. 1997, 370, 136.
31. Au, C.-T.; Liao, M.-S.; Ng, C.-F. J. Phys. Chem. A 1998, 102, 3959.
32. 2O molecules, have also been observed.
33. 2O during imaging. The preexponential was assumed.
34. Rempala, K.; Ervin, K. M. J. Chem. Phys. 2000, 112, 4579.
35. Leung, K. T.; Zhang, X. S.; Shirley, D. A. J. Phys. Chem. 1989, 93, 6164.
36. Ignaczak, A.; Gomes, J. A. N. F. J. Electroanal. Chem. 1997, 420, 209.
37. Lorente, N.; Olsson, F.; Persson, M. Manuscript to be published.
38. Olsson, F.; Lorente, N.; Persson, M.; Lauhon, L. J.; Ho, W. Manuscript to be published.