Preparation, structures and reactions of isomeric [Co(cyclen)(O2C2O2)]+ and [Co(cyclen)(O2CCH2CO2)]+ complexes (cyclen = 1,4,7,10-tetraazacyclododecane)

Journal of the Chemical Society. Dalton Transactions

Volumn , Issue 5, 2001, Pages 758-765

  Clarkson, Andrea J ^a   Blackman, Allan G ^a   Clark, Charles R ^a  

^a UNIVERSITY OF OTAGO   (New Zealand)

Author keywords

[No Author keywords available]

Indexed keywords

COBALT COMPOUNDS; COMPLEXATION; CRYSTAL STRUCTURE; CRYSTALLIZATION; HYDROLYSIS; SINGLE CRYSTALS; SYNTHESIS (CHEMICAL);

PROTON EXCHANGE;

ORGANOMETALLICS;

EID: 0035820145     PISSN: 14727773     EISSN: None     Source Type: Journal    
DOI: 10.1039/b008350j     Document Type: Article

References (47)

1. See, for example: R.B. Jordan, Reaction Mechanisms of Inorganic and Organometallic Systems, Oxford University Press, New York, 1998, pp. 42-45; F. Basolo and R.G. Pearson, Mechanisms or Inorganic Reactions, 2nd edn., Wiley, New York, 1968, pp. 177-193; R.G. Wilkins, Kinetics and Mechanism of Reactions of Transition Metal Complexes, 2nd edn., VCH, Weinheim, 1991, pp. 215-218; M.L. Tobe, Adv. Inorg. Bioorg. Mech. 1983, 2, 1.
2. See, for example: R.B. Jordan, Reaction Mechanisms of Inorganic and Organometallic Systems, Oxford University Press, New York, 1998, pp. 42-45; F. Basolo and R.G. Pearson, Mechanisms or Inorganic Reactions, 2nd edn., Wiley, New York, 1968, pp. 177-193; R.G. Wilkins, Kinetics and Mechanism of Reactions of Transition Metal Complexes, 2nd edn., VCH, Weinheim, 1991, pp. 215-218; M.L. Tobe, Adv. Inorg. Bioorg. Mech. 1983, 2, 1.
3. See, for example: R.B. Jordan, Reaction Mechanisms of Inorganic and Organometallic Systems, Oxford University Press, New York, 1998, pp. 42-45; F. Basolo and R.G. Pearson, Mechanisms or Inorganic Reactions, 2nd edn., Wiley, New York, 1968, pp. 177-193; R.G. Wilkins, Kinetics and Mechanism of Reactions of Transition Metal Complexes, 2nd edn., VCH, Weinheim, 1991, pp. 215-218; M.L. Tobe, Adv. Inorg. Bioorg. Mech. 1983, 2, 1.
4. See, for example: R.B. Jordan, Reaction Mechanisms of Inorganic and Organometallic Systems, Oxford University Press, New York, 1998, pp. 42-45; F. Basolo and R.G. Pearson, Mechanisms or Inorganic Reactions, 2nd edn., Wiley, New York, 1968, pp. 177-193; R.G. Wilkins, Kinetics and Mechanism of Reactions of Transition Metal Complexes, 2nd edn., VCH, Weinheim, 1991, pp. 215-218; M.L. Tobe, Adv. Inorg. Bioorg. Mech. 1983, 2, 1.
5. (a) G. Ma, T. Hibino, M. Kojima and J. Fujita, Bull. Chem. Soc. Jpn., 1989, 62, 1053.
6. (b) G. Ma, M. Kojima and J. Fujita, Bull. Chem. Soc. Jpn., 1989, 62, 2547.
7. (c) D.A. Buckingham, L.G. Marzilli and A.M. Sargeson, J Am. Chem. Soc., 1967, 89, 3428.
8. (d) D.A. Buckingham, L.G. Marzilli and A.M. Sargeson, J. Am. Chem. Soc., 1967, 89, 825.
9. (e) H. Kawaguchi, M. Matsuki, T. Ama and T. Yasui, Bull. Chem. Soc. Jpn., 1986, 59, 31.
10. (f) B. Halpern, A.M. Sargeson and K.R. Turnbull, J. Am. Chem. Soc., 1966, 88, 4630.
11. (g) D.A. Buckingham, P.J. Cresswell, R.J. Dellaca, M. Dwyer, G.J. Gainsford, L.G. Marzilli, I.E. Maxwell, W.T. Robinson, A.M. Sargeson and K.R. Turnbull, J. Am. Chem. Soc., 1974, 96, 1713.
12. (h) D.A. Buckingham, M. Dwyer, G.J. Gainsford, V. Jason Ho, L.G. Marzilli, W.T. Robinson, A.M. Sargeson and K.R. Turnbull, Inorg. Chem., 1975, 14, 1739.
13. (i) G.H. Searle and F.R. Keene, Inorg. Chem., 1972, 11, 1006.
14. (j) D.A. Buckingham, P.A. Marzilli and A.M. Sargeson, Inorg. Chem., 1969, 8, 1595.
15. (k) D.A. Buckingham, C.R. Clark and A.J. Rogers, J. Am. Chem. Soc., 1997, 119, 4050.
16. (a) D.A. Buckingham, C.R. Clark, A.J. Rogers and J. Simpson, Aust. J. Chem., 1998, 51, 461.
17. (b) D.A. Buckingham, C.R. Clark, A.J. Rogers and J. Simpson, Inorg. Chem., 1998, 37, 3497.
18. (c) N.E. Brasch, D.A. Buckingham, C.R. Clark and A.J. Rogers, Inorg. Chem., 1998, 37, 4865.
19. (d) C.R. Clark and D.A. Buckingham, Inorg. Chim. Acta, 1997, 254, 339.
20. (e) A.J. Clarkson, D.A. Buckingham, A.J. Rogers, A.G. Blackman and C.R. Clark, Inorg. Chem., 2000, 39, 4769.
21. 2]Cl, Y. Iitaka, M. Shina and E. Kimura, Inorg. Chem.,1974, 13, 2886.
22. 4], see ref. 3(a).
23. 2O, J.H. Loehlin and E.B. Fleischer, Acta Crystallogr., Sect. B, 1976, 32, 3063.
24. 2O, N. Matsumoto, A. Hirano, T. Hara and A. Ohyoshi, J. Chem. Soc., Dalton Trans., 1983, 2405.
25. 2O (green isomer), M. Kojima, K. Nakabayashi, S. Ohba, S. Okumoto, Y. Saito and J. Fujita, Bull. Chem. Soc. Jpn., 1986, 59, 277.
26. 2O, see ref. 3(b).
27. 4, S.J. Carrington, D.A. Buckingham, J. Simpson, A.G. Blackman and C.R. Clark, J. Chem. Soc., Dalton Trans., 1999, 3809.
28. J.G. Sime, J.C. Speakman and R. Parthasarathy, J. Chem. Soc. A, 1970, 1919.
29. B. Briggman and A. Oskarsson, Acta Crystallogr., Sect. B, 1978, 34, 3357.
30. U.C. Sinha and S. Ojha, Z. Kristallogr, 1980, 152, 157.
31. M. Eigen, W. Kruse, G. Maass and L. De Maeyer, Prog. React. Kinet., 1963, 2, 308.
32. C.J. Bunton and V.J. Shiner, J. Am. Chem. Soc., 1961, 83, 3207.
33. S.F. Nelsen, J.T. Ippoliti, T.B. Frigo and P.A. Petillo, J. Am. Chem. Soc., 1989, 111, 1776; J.B. Lambert, Top. Stereochem., 1971, 6, 19.
34. S.F. Nelsen, J.T. Ippoliti, T.B. Frigo and P.A. Petillo, J. Am. Chem. Soc., 1989, 111, 1776; J.B. Lambert, Top. Stereochem., 1971, 6, 19.
35. G.M. Miskelly, D.A. Buckingham and C.R. Clark, J. Am. Chem. Soc., 1986, 108, 5202.
36. V. Carunchio, F. Giannetta and G. Grassini Strazza, J. Inorg. Nucl. Chem., 1971, 33, 3025.
37. R.B. Jordan, Reaction Mechanisms of Inorganic and Organometallic Systems, Oxford University Press, New York, 1998, pp. 93-96.
38. J.P. Collman and P.W. Schneider, Inorg. Chem., 1966, 4, 1380.
39. N. Linnet, pH Measurements in Theory and Practice, Radiometer, Copenhagen, 1970.
40. P.K. Glascoe and F.A. Long, J. Chem. Phys., 1960, 64, 188.
41. P.R. Marshall and J. Katz, J. Inorg. Nucl. Chem., 1974, 36, 1589.
42. R.E. Mesmer and D.L. Herting, J. Solution Chem., 1978, 7, 901.
43. R.D. Purves, J. Pharm. Pharmacol., 1993, 45, 934.
44. J.H. Espenson, Chemical Kinetics and Reaction Mechanisms, 2nd edn., McGraw-Hill, New York, 1995, p. 71.
45. SAINT, Version 4, Siemens Analytical X-Ray Systems, Inc., Madison, WI, 1996.
46. G.M. Sheldrick, SHELXS 97, Program for the solution of crystal structures, University of Göttingen, 1997.
47. G.M. Sheldrick, SHELXL 97, Program for the refinement of crystal structures, University of Göttingen, 1997.