The Preparation, Stereochemistry and Reactions of Some [Co(cyclen)(NH3)X]3+/2+ Complexes (X = OH2, Cl, N3, OH)

Inorganic Chemistry

Volumn 37, Issue 14, 1998, Pages 3497-3504

  Buckingham, David A ^a   Clark, Charles R ^a   Rogers, Andrew J ^a   Simpson, Jim ^a  

^a UNIVERSITY OF OTAGO   (New Zealand)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0000067958     PISSN: 00201669     EISSN: None     Source Type: Journal    
DOI: 10.1021/ic971029f     Document Type: Article

References (56)

1. 4, Castillo-Blum, S. E.; Sosa-Torres, M. E. Polyhedron 1995, 14, 223.
2. 3, Clark, C. R.; Buckingham, D. A. Inorg. Chim. Acta 1997, 254, 339.
3. 3, Clark, C. R.; Buckingham, D. A. Inorg. Chim. Acta 1997, 254, 339.
4. 3, Curtis, N. J.; Hendry, P.; Lawrance, G. A. J. Chem. Soc., Dalton Trans. 1988, 47.
5. 4) isomers, Kojima, M.; Nakabayashi, K.; Ohba, S.; Okumoto, S.; Saito, Y.; Fujita, J. J. Bull. Chem. Soc. Jpn. 1986, 59, 277.
6. 2O (L = en, pic, pn, chxn, tn, bn).
7. 2O, Nonoyama, N.; Kurimoto, T. Polyhedron 1985, 4, 471.
8. 2O, Buckingham, D. A.; Clark, C. R. Inorg. Chem. 1994, 33, 6111.
9. (a) Melson, G. A. In Coordination Chemistry of Macrocyclic Compounds; Plenum Press: New York, 1979.
10. (b) Hung Y.; Busch, D. H. J. Am. Chem. Soc. 1977, 99, 4029, 4977.
11. 2O (green isomer), Kojima, M.; Nakabayashi, K.; Ohba, S.; Okumoto, S.; Saito, Y.; Fujita, J. Bull Chem. Soc. Jpn. 1986, 59, 277. The structures of a number of alkyl-substituted cyclen complexes have also been reported.
12. 2O (green isomer), Kojima, M.; Nakabayashi, K.; Ohba, S.; Okumoto, S.; Saito, Y.; Fujita, J. Bull Chem. Soc. Jpn. 1986, 59, 277. The structures of a number of alkyl-substituted cyclen complexes have also been reported.
13. Hay, R. W.; Norman, P. R. J. Chem. Soc. Chem Commun. 1980, 734.
14. Tobe, M. L. Adv. Inorg. Bioinorg. Mech. 1983, 2, 1.
15. Sosa, M. E.; Tobe, M. L. J. Chem. Soc., Dalton Trans. 1985, 475.
16. -1 (25 °C, I = 1.0 M), Buckingham, D. A.; Clark, C. R.; Rogers, A. J., unpublished data.
17. Kim, J. H.; Britten, J.; Chin, J. J. Am. Chem. Soc. 1993, 115, 3618.
18. Chin, J.; Banaszczyk, M.; Jubian, V.; Zou, X. J. Am. Chem. Soc. 1989, 111, 186.
19. Takasaki, B. K.; Kim, J. H.; Rubin, E.; Chin, J. J. Am. Chem. Soc. 1993, 115, 1157.
20. Jackson, W. G. Inorg. Chim. Acta 1974, 10, 51.
21. These authors, ref 1c, assumed, incorrectly, that the two dimethylformamide ligand sites were equivalent.
22. Buckingham, D. A.; Clark, C. R.; Rogers, A. J.; Simpson, J. Aust. J. Chem., in press.
23. Buckingham, D. A.; Clark, C. R.; Rogers, A. J; Simpson, J. Inorg. Chem. 1995, 34, 3646.
24. Collman, J. P.; Schneider, P. W. Inorg. Chem. 1996, 5, 1380.
25. For the preparation of this complex see: Buckingham, D. A.; Clark, C. R.; Rogers, A. J. Inorg. Chim. Acta 1995, 240, 125.
26. Ridd, J. H. Adv. Phys. Org. Chem. 1978, 16, 1.
27. Buckingham, D. A.; Clark, C. R.; Rogers, A. J. J. Am. Chem. Soc. 1997, 119, 4050.
28. obs(2); cf. Frost, A. A.; Pearson, R. G. In Kinetics and Mechanism; Wiley and Sons: New York, 1953; p 155.
29. obs (I = 1.0 M) for 1-Cl.
30. Posey, K A.; Taube, H. J. Am. Chem. Soc. 1957, 79, 255. Buckingham, D. A.; Olsen, I.I.; Sargeson, A. M. J. Am. Chem. Soc. 1968, 90, 6654. However, see Jackson, W. G. Inorg. Chim. Acta 1974, 10, 51.
31. Posey, K A.; Taube, H. J. Am. Chem. Soc. 1957, 79, 255. Buckingham, D. A.; Olsen, I.I.; Sargeson, A. M. J. Am. Chem. Soc. 1968, 90, 6654. However, see Jackson, W. G. Inorg. Chim. Acta 1974, 10, 51.
32. Posey, K A.; Taube, H. J. Am. Chem. Soc. 1957, 79, 255. Buckingham, D. A.; Olsen, I.I.; Sargeson, A. M. J. Am. Chem. Soc. 1968, 90, 6654. However, see Jackson, W. G. Inorg. Chim. Acta 1974, 10, 51.
33. Buckingham, D. A.; Clark, C. R.; Webley, W. S. Aust. J. Chem. 1980, 33, 263.
34. Palenik, G. J. Acta Crystallogr. 1964, 17, 360. Restivo, R. J.; Ferguson, G.; Hay, R. W.; Piplani, D. P. J. Chem. Soc., Dalton Trans. 1978, 1131. Comba, P.; House, D. A.; Jackson, W. G.; Marty, M.; Stoeckli-Evans, H.; Zipper, L. Helv. Chim. Acta 1992, 75, 1130.
35. Palenik, G. J. Acta Crystallogr. 1964, 17, 360. Restivo, R. J.; Ferguson, G.; Hay, R. W.; Piplani, D. P. J. Chem. Soc., Dalton Trans. 1978, 1131. Comba, P.; House, D. A.; Jackson, W. G.; Marty, M.; Stoeckli-Evans, H.; Zipper, L. Helv. Chim. Acta 1992, 75, 1130.
36. Palenik, G. J. Acta Crystallogr. 1964, 17, 360. Restivo, R. J.; Ferguson, G.; Hay, R. W.; Piplani, D. P. J. Chem. Soc., Dalton Trans. 1978, 1131. Comba, P.; House, D. A.; Jackson, W. G.; Marty, M.; Stoeckli-Evans, H.; Zipper, L. Helv. Chim. Acta 1992, 75, 1130.
37. Tobe, M. L. In Comprehensive Coordination Chemistry; Wilkinson, G., Ed.; Pergammon: Elmsford, NY, 1987; Vol. 1, Sect. 7.1.5, p 300.
38. Clark, C. R.; Buckingham, D. A. Inorg. Chim. Acta 1997, 254, 339.
39. Rogers, A. J. Ph.D. Thesis, University of Otago, 1995.
40. -1) is now rate limiting.
41. Jackson, W. G. Inorg. Chem. 1991, 30, 4813.
42. Rotzinger, F. P.; Weber, J.; Daul, C. Helv. Chim. Acta 1991, 74, 1247.
43. Buckingham, D. A.; Marty, W.; Sargeson, A. M. Helv. Chim. Acta 1978, 61, 2223.
44. Jackson, W. G. In The Stereochemistry of Organometallic and Inorganic Compounds; Bernal, I., Ed.; Elsevier: Amsterdam, 1986; Vol. 1, p 255.
45. Comba, P.; Jackson, W. G.; Marty, M.; Zipper, L. Helv. Chim. Acta 1992, 75, 1147.
46. Buckingham, D. A.; Cresswell, P. J.; Sargeson, A. M. Inorg. Chem. 1975, 14, 1485.
47. -1 reported by Cresswell, P. J. Ph.D. Thesis, Australian National University, 1974.
48. Gahan, L. R.; Lawrance, G. A.; Sargeson, A. M. Aust. J. Chem. 1982, 35, 1119.
49. Cresswell, P. J. Ph.D. Thesis, Australian National University, 1974.
50. Pearson, R. G.; Basolo, F. M. J. Am. Chem. Soc. 1956, 78, 4878. Mechanisms of Inorganic Reactions, 2nd ed.; Wiley: New York, 1967.
51. Pearson, R. G.; Basolo, F. M. J. Am. Chem. Soc. 1956, 78, 4878. Mechanisms of Inorganic Reactions, 2nd ed.; Wiley: New York, 1967.
52. Ahmed, E.; Chatterjee, C.; Cooksey, C. J.; Tobe, M. L.; Williams, G. J. Chem. Soc., Dalton Trans. 1989, 645.
53. Kruse, W.; Tobe, M. L. J. Am. Chem. Soc. 1961, 83, 1280. Poon, C. K.; Tobe, M. L. Inorg. Chem. 1968, 7, 2398; 1971, 10, 225.
54. Kruse, W.; Tobe, M. L. J. Am. Chem. Soc. 1961, 83, 1280. Poon, C. K.; Tobe, M. L. Inorg. Chem. 1968, 7, 2398; 1971, 10, 225.
55. Kruse, W.; Tobe, M. L. J. Am. Chem. Soc. 1961, 83, 1280. Poon, C. K.; Tobe, M. L. Inorg. Chem. 1968, 7, 2398; 1971, 10, 225.
56. Jackson, W. G.; Sargeson, A. M. In Rearrangements in Ground and Excited Stares; de Mayo, P., Ed., Academic Press: NY, 1980; p 273.