17O NMR Study of Solvent Exchange in Some Aqueous [Co(tren)(X)(OH2/OH)]n+, [Co(cyclen)(X)(OH2/OH)]n+, and [Co(N-Mecyclen)(X)(OH2/OH)]n+ Systems (X = NH3, OH2/OH; n = 3, 2, 1)1

Inorganic Chemistry

Volumn 37, Issue 19, 1998, Pages 4865-4871

  Brasch, Nicola E ^a   Buckingham, David A ^a   Clark, Charles R ^a   Rogers, Andrew J ^a  

^a UNIVERSITY OF OTAGO   (New Zealand)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0001598318     PISSN: 00201669     EISSN: None     Source Type: Journal    
DOI: 10.1021/ic980221u     Document Type: Article

References (30)

1. Abstracted in part from the Ph.D. theses of N. E. Brasch and A. J. Rogers: Brasch, N. E. Ph.D. Thesis, University of Otago, 1993. Rogers, A. J. Ph.D. Thesis, University of Otago, 1995.
2. Burgess, J. In Metal Ions in Solution; Ellis Horwood: Chichester, U.K.; 1978, Chapters 11 and 12.
3. Lincoln, S. F.; Merbach, A. E. Substitution Reactions of Solvated Metal Ions. In Advances in Inorganic Chemistry; Sykes, A. G., Ed.; Academic Press: San Diego, 1995; pp 1-88.
4. Richens, D. T. The Chemistry of Aqua Ions; John Wiley: Chichester, U.K., 1997, p 73.
5. Wilkins, R. G. Kinetics and Mechanism of Reactions of Transition Metal Complexes; VCH: Weinheim, 1991.
6. Jordan, R. B. Reaction Mechanisms of Inorganic and Organometallic Systems; Oxford University Press: Oxford, U.K., 1991.
7. For the most recent summary account (and references) on Co(III) substitution, see: Tobe, M. L. In Comprehensive Coordination Chemistry; Wilkinson, G., Ed.; Pergamon Press: Oxford, U.K., 1987; Vol. 1, Section 7.1.5, p 300.
8. 2O exchange.
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17. Näsänen, R.; Meriläinen, P. Suom. Kemistil. 1960, 33B, 149; quoted in: Sillen, L. G.; Martell, A. G. Stability Constants of Metal-Ion Complexes; The Chemical Society: London, 1964.
18. Näsänen, R.; Meriläinen, P. Suom. Kemistil. 1960, 33B, 149; quoted in: Sillen, L. G.; Martell, A. G. Stability Constants of Metal-Ion Complexes; The Chemical Society: London, 1964.
19. Albert, A.; Serjeant, E. P. Ionisation Constants of Acids and Bases: Wiley and Son: New York, 1962.
20. El-Awady, A. A.; Harris, G. M. Inorg. Chem. 1981, 20, 1660.
21. -1.
22. obs(t) calculated as given in ref 20.
23. Buckingham, D. A.; Clark, C. R.; Rogers, A. J.; Simpson, J. Inorg. Chem. 1995, 34, 3646.
24. Buckingham, D. A.; Clark, C. R.; Rogers, A. J. Inorg. Chim. Acta 1995, 240, 125.
25. Chin, J.; Banaszezyk, M.; Jubian, V.; Zou, X. J. Am. Chem. Soc. 1989, 111, 186.
26. Hunt, J. P.; Taube, H. J. Am. Chem. Soc. 1958, 80, 2642.
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