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The bond distance for Si(1A)...H(1A) (2.27(7) Å) is slightly longer than Si(1)...H(1). The dihedral angles C(1A)-Ru(1)-Ru(2)-Si-(1A), C(1A)-Ru(1)-Ru(2)-H(1A), and Si(1A)-Ru(1)-Ru(2)-H(1A) are 169.6(9)°, 102(3)°, and 88(3)°, respectively. These values are slightly different from the structure with high occupancy, but still imply weak interaction between the hydride and the bridging silicon atom. We are now investigating the presence of this agostic interaction between Si and H by MO calculation and will report in due course.
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