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Volumn 20, Issue 16, 2001, Pages 3406-3422

Reactions of diruthenium tetrahydride complex (η5-C5Me5)Ru(μ-H)4 Ru(η5-C5Me5) with vinylsilanes: Formation of a μ-silylene complex via successive Si-H and Si-C bond cleavage of dimethylvinylsilane

Author keywords

[No Author keywords available]

Indexed keywords

DIMETHYLVINYLSILANE; DIRUTHENIUM TETRAHYDRIDE COMPLEX; VINYLSILANES;

EID: 0035817666     PISSN: 02767333     EISSN: None     Source Type: Journal    
DOI: 10.1021/om010147e     Document Type: Article
Times cited : (29)

References (92)
  • 66
    • 0011487562 scopus 로고    scopus 로고
    • note
    • The bond distance for Si(1A)...H(1A) (2.27(7) Å) is slightly longer than Si(1)...H(1). The dihedral angles C(1A)-Ru(1)-Ru(2)-Si-(1A), C(1A)-Ru(1)-Ru(2)-H(1A), and Si(1A)-Ru(1)-Ru(2)-H(1A) are 169.6(9)°, 102(3)°, and 88(3)°, respectively. These values are slightly different from the structure with high occupancy, but still imply weak interaction between the hydride and the bridging silicon atom. We are now investigating the presence of this agostic interaction between Si and H by MO calculation and will report in due course.
  • 74
    • 0011440709 scopus 로고    scopus 로고
    • note; Manuscript in preparation
    • 4RuCp* with triphenylsilane with liberating benzene. Takao, T.; Amako, M.; Tanaka, M.; Suzuki, H. Manuscript in preparation.
    • Takao, T.1    Amako, M.2    Tanaka, M.3    Suzuki, H.4


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.