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33847586861
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note
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Note this optimised extraction experiment uses a different concentration of dendritic branch compared with that in the preliminary communication (ref. [17]).
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86
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84962434220
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Increased proton transfer within a hydrogen bond in a more polar microenvironment would be expected theoretically: T. Liljefors, P.-O. Norrby, J. Am. Chem. Soc. 1997, 119, 1052-1058.
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33847583458
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note
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As discussed in the text, the amide groups can also become involved in hydrogen-bond interactions with the amines on proflavine. This leads to relatively poorly defined complexes. A single favoured stoichiometry of interaction could not, therefore, be identified.
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88
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0006570655
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note
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In these concentration-dependent experiments the solution was not diluted before filtration through the Biobeads gel.
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92
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0033204490
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33847586479
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This rate of transport was calculated by using the ε value for proflavine hydrochloride given in reference: K. Yamaoka, S. Noji, M. Yoshida, Bull. Chem. Soc. Jpn. 1981, 54, 31-34.
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We have recently developed a supramolecular dendritic gelling system for organic solvents by using exactly this methodology: K. S. Partridge, D. K. Smith, G. M. Dykes, P. T. McGrail, Chem. Commun. 2001, 319-320.
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