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Polynuclear metal complexes of nanometer size. A versatile synthetic strategy leading to luminescent and redox-active dendrimers made of an osmium (II)-based core and ruthenium (II)-based units in the branches
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•The complexation of divalent cations on the periphery of poly(propylene)imine dendrimers is reported here. Importantly, the availability and reactivity of the peripheral substituents is demonstrated by the impressively high incorporation of metals into the dendritic material
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Rational design of the first spherical supramolecular dendrimers self-organized in a novel thermotropic cubic liquid-crystalline phase and the determination of their shape by X-ray analysis
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25 aliphatic tails. The dendritic systems described self-assemble into supramolecular dendrimers, as thermotropic liquid crystals; the structural type of the assembly was found to depend on the substitution pattern of the dendron's peripheral aliphatic chains
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25 aliphatic tails. The dendritic systems described self-assemble into supramolecular dendrimers, as thermotropic liquid crystals; the structural type of the assembly was found to depend on the substitution pattern of the dendron's peripheral aliphatic chains.
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Direct visualization of individual cylindrical and spherical supramolecular dendrimers
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••The direct visualization of dendrimers by electron microscopy described here is a novel accomplishment in the field. It is shown that dendritic liquid crystalline assemblies can be patterned on various surfaces, while maintaining good positional order
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Self-encapsulation, acceleration, and control in the radical polymerization of monodendritic monomers via self-assembly
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••The unique polymerizations reported in this paper rely on the assembly of monomeric dendrons, bearing polymerizable groups, into "supramolecular reactors" to effect the reactions. The kinetic data reported suggests that the dendrimers assemble into "jacket-like" structures which greatly accelerate the propagation reactions
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••The unique polymerizations reported in this paper rely on the assembly of monomeric dendrons, bearing polymerizable groups, into "supramolecular reactors" to effect the reactions. The kinetic data reported suggests that the dendrimers assemble into "jacket-like" structures which greatly accelerate the propagation reactions.
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2 peripheral substituents of poly(amidoamine) dendrimers and the gold surface. The dendritic substrates were shown to assemble as compressed globs on the surface, as opposed to their more spherical shape in the bulk state. Interestingly, this flattened configuration was distorted to a more upright, prolate, conformation upon co-adsorption of hexadecane thiol into the dendritic monolayer. The authors note that a submonolayer hexadecane thiol coverage could not in itself account for this increased film thickness
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2 peripheral substituents of poly(amidoamine) dendrimers and the gold surface. The dendritic substrates were shown to assemble as compressed globs on the surface, as opposed to their more spherical shape in the bulk state. Interestingly, this flattened configuration was distorted to a more upright, prolate, conformation upon co-adsorption of hexadecane thiol into the dendritic monolayer. The authors note that a submonolayer hexadecane thiol coverage could not in itself account for this increased film thickness.
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