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Volumn 20, Issue 5, 2001, Pages 990-994

Preparation of cationic cyclopentadienyl diene molybdenum complexes through hydride abstraction effected by Di- or triarylmethyl halides in the presence of hexafluoro-2-propanol

Author keywords

[No Author keywords available]

Indexed keywords

CATIONIC CYCLOPENTADIENYL DIENE MOLYBDENUM COMPLEXES; HEXAFLUORO-PROPANOL; HYDRIDE ABSTRACTION; TRIARYLMETHYL HALIDES;

EID: 0035809945     PISSN: 02767333     EISSN: None     Source Type: Journal    
DOI: 10.1021/om000839n     Document Type: Article
Times cited : (3)

References (39)
  • 1
    • 0011485480 scopus 로고
    • Abel, E. W., Stone, E. G. A., Wilkinson, G., Eds.; Pergamon: Oxford, U.K.; Chapter 6.3
    • Pearson, A. J. In Comprehensive Organometallic Chemistry II; Abel, E. W., Stone, E. G. A., Wilkinson, G., Eds.; Pergamon: Oxford, U.K., 1995; Vol. 12, Chapter 6.3.
    • (1995) Comprehensive Organometallic Chemistry II , vol.12
    • Pearson, A.J.1
  • 22
    • 0011483054 scopus 로고    scopus 로고
    • note
    • The same factors preclude sequential 1,2-difunctionalisation in the analogous cyclohexadienyl iron series; e.g., see ref 1.
  • 30
    • 0011433025 scopus 로고    scopus 로고
    • note
    • Resonances were as follows: δ 8.29 (tt, J = 7.5, 1.2 Hz), 7.90 (t J = 7.5 Hz), 7.68 (dd, J = 1.2, 8.4 Hz).
  • 31
    • 0011440412 scopus 로고    scopus 로고
    • note
    • Complex fluorine-containingn counterions display reactivity, for example, toward silyl ethers:
  • 35
    • 0011483711 scopus 로고    scopus 로고
    • note
    • Product isolation was compromised by incomplete precipitation of the diene complex. However, addition of diethyl ether to the crude reaction mixture returned a 26% isolated yield of pure 7.
  • 39
    • 0011391959 scopus 로고    scopus 로고
    • note
    • Compound 6 may be similarly prepared from 2a or 2b.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.