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6 The reversibility of the indole additions observed in this work might similarly prove useful for the resolution of cationic complexes.
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0033597623
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During the preparation of this paper, the application of additional oxidative decomplexation methods (reaction with iodine or ceric ammonium nitrate) to (pyranyl)molybdenum complexes was reported; see: Yin, J.; Liebeskind, L. S. J. Am. Chem. Soc. 1999, 121, 5811.
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Proton assignments were based on NOESY experiments, which revealed correlations e.g. between the cyanoindolyl 2′-H and 3-H, 4-H, and anti-6-H as well as between 2-H and 3-H. The NOESY spectrum obtained was fully consistent with the conformation, having a pseudoaxial cyanoindolyl substituent, observed crystallographically.
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