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Volumn 20, Issue 18, 2001, Pages 3839-3841

Synthesis, structure, and hydrosilylation catalysis of a chiral a-frame rhodium(I) dimer with cis diphosphite ligands

Author keywords

[No Author keywords available]

Indexed keywords

CHIRAL; DIPHOSPHITE LIGANDS; HYDROSILYLATION CATALYSIS; RHODIUM DIMER;

EID: 0035802149     PISSN: 02767333     EISSN: None     Source Type: Journal    
DOI: 10.1021/om010428m     Document Type: Article
Times cited : (24)

References (25)
  • 1
    • 0011664501 scopus 로고    scopus 로고
    • note
    • To whom questions concerning X-ray crystallohgraphy should be addressed.
  • 11
    • 0032556244 scopus 로고    scopus 로고
    • note
    • Binuclear systems have become increasingly important in catalytic reactions. For example, Jacobsen and co-workers have demonstrated in the chromium-catalyzed asymmetric ring opening of epoxides that bimetallic systems can exhibit enhanced catalytic behavior relative to their monomeric analogues: Konsler, R. G.; Karl, J.; Jacobsen, E. N. J. Am. Chem. Soc. 1998, 120, 10780.
    • (1998) J. Am. Chem. Soc. , vol.120 , pp. 10780
    • Konsler, R.G.1    Karl, J.2    Jacobsen, E.N.3
  • 12
    • 0011595260 scopus 로고    scopus 로고
    • note
    • 4. Evaporation of the solvent gave the analytically pure desired product.
  • 13
    • 0011646895 scopus 로고    scopus 로고
    • note
    • 2. After the mixture was stirred for 1 h, the volatile materials were evaporated and the resulting solid was washed with ether followed by ethanol.
  • 15
    • 0011659090 scopus 로고    scopus 로고
    • note
    • See the Supporting Information.
  • 16
    • 0011597976 scopus 로고    scopus 로고
    • note
    • min = 0.59) based on a comparison of redundant and equivalent reflections was applied using SADABS (36 422 reflections measured). The final cycle of full-matrix least-squares refinement was based on 5851 observed reflections (I > 3.00σ(I)); R = 0.059.
  • 24
    • 0000421290 scopus 로고    scopus 로고
    • Jacobsen, E. N., Pfaltz, A., Yamamoto, H., Eds., Springer: Berlin, New York
    • Nishiyama, H. In Comprehensive Asymmetric Catalysis; Jacobsen, E. N., Pfaltz, A., Yamamoto, H., Eds., Springer: Berlin, New York, 1999; Vol. 1, pp 267-287.
    • (1999) Comprehensive Asymmetric Catalysis , vol.1 , pp. 267-287
    • Nishiyama, H.1


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.