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Binuclear systems have become increasingly important in catalytic reactions. For example, Jacobsen and co-workers have demonstrated in the chromium-catalyzed asymmetric ring opening of epoxides that bimetallic systems can exhibit enhanced catalytic behavior relative to their monomeric analogues: Konsler, R. G.; Karl, J.; Jacobsen, E. N. J. Am. Chem. Soc. 1998, 120, 10780.
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4. Evaporation of the solvent gave the analytically pure desired product.
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13
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0011646895
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2. After the mixture was stirred for 1 h, the volatile materials were evaporated and the resulting solid was washed with ether followed by ethanol.
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15
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0011659090
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note
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See the Supporting Information.
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16
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0011597976
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note
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min = 0.59) based on a comparison of redundant and equivalent reflections was applied using SADABS (36 422 reflections measured). The final cycle of full-matrix least-squares refinement was based on 5851 observed reflections (I > 3.00σ(I)); R = 0.059.
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