Self-assembly of a three-dimensional [Ga6(L2)6] metal-ligand 'cylinder'

Angewandte Chemie - International Edition

Volumn 38, Issue 19, 1999, Pages 2882-2885

  Johnson, Darren W ^b   Xu, Jide ^b   Saalfrank, Rolf W ^a   Raymond, Kenneth N ^b  

^a UNIVERSITY OF ERLANGEN NUREMBERG   (Germany)

^b UNIVERSITY OF CALIFORNIA   (United States)

Author keywords

Cage compounds; Cluster compounds; Gallium; Self assembly; Supramolecular chemistry

Indexed keywords

GALLIUM; LIGAND; METAL;

ARTICLE; CHEMICAL STRUCTURE; CRYSTAL STRUCTURE; GEOMETRY; LIGAND BINDING; METAL BINDING; PROTON NUCLEAR MAGNETIC RESONANCE; STRUCTURE ANALYSIS; SYNTHESIS; THERMODYNAMICS;

EID: 0033523715     PISSN: 14337851     EISSN: None     Source Type: Journal    
DOI: 10.1002/(SICI)1521-3773(19991004)38:19<2882::AID-ANIE2882>3.0.CO;2-T     Document Type: Article

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30. 4] species. This is the proper stoichiometry for a tetrahedron, however there is no other evidence for formation of this compound in solution (NMR spectroscopic measurements and TLC). We conclude that this a mass spectrometer fragmentation species.
31. 3. (The largest difference peaks correspond to noise near severely disordered solvent). Details of the disorder in the structure are contained in the Supporting Information. Crystallographic data (excluding structure factors) for the structure reported in this paper have been deposited with the Cambridge Crystallographic Data Centre as supplementary publication number CCDC-117432. Copies of the data can be obtained free of charge on application to CCDC, 12 Union Road, Cambridge CB2 1EZ, UK (fax: (+44)1223-336-033; email: deposit@ccdc.cam.ac.uk).
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