Time resolved coherent anti-Stokes Raman scattering of I2 isolated in matrix argon: Vibrational dynamics on the ground electronic state

Journal of Chemical Physics

Volumn 114, Issue 9, 2001, Pages 4131-4140

  Karavitis, M ^a   Zadoyan, R ^a   Apkarian, V Ara ^a  

^a UNIVERSITY OF CALIFORNIA   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

ARGON; GROUND STATE; HAMILTONIANS; LIGHT POLARIZATION; MATHEMATICAL MODELS; MOLECULAR VIBRATIONS; NONLINEAR OPTICS; PHONONS; RAMAN SCATTERING;

TIME RESOLVED COHERENT ANTI-STOKES RAMAN SCATTERING (TRCARS);

IODINE;

EID: 0035280771     PISSN: 00219606     EISSN: None     Source Type: Journal    
DOI: 10.1063/1.1346643     Document Type: Article

References (120)

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25. F. Lineberger, R. Stocl, B. P. Asthana, and A. Laubereau, J. Phys. Chem. A 103, 5655 (1999).
26. H. Okamoto, H. Hayashi, K. Yoshihara, and M. Tasumi, Chem. Phys. Lett. 182, 96 (1991).
27. W. E. Bron, J. Kuhl, and B. K. Rhee, Phys. Rev. B 34, 6961 (1986).
28. F. Geist, H. Pascher, N. Frank, G. Bauer, and M. Kriechbaum, Superlattices Microstruct. 12, 477 (1992).
29. A. Vierheilig, T. Chen, P. Waltner, W. Kiefer, M. Materny, and A. H. Zewail, Chem. Phys. Lett. 312, 349 (1999).
30. A. Zumbusch, G. R. Holton, and X. S. Xie, Phys. Rev. Lett. 82, 4142 (1999).
31. M. Schmitt. G. Knopp, A. Materny, and W. Kiefer, Chem. Phys. Lett. 280, 339 (1997); 270, 9 (1997); J. Phys. Chem. A 102, 4059 (1998); T. Siebert, M. Schmitt, A. Vierheilig, G. Flachenecker, V. Engel, A. Materny, and W. Kiefer, J. Raman Spectrosc. 31, 25 (2000); S. Meyer and V. Engel, ibid. 31, 33 (2000).
32. M. Schmitt. G. Knopp, A. Materny, and W. Kiefer, Chem. Phys. Lett. 280, 339 (1997); 270, 9 (1997); J. Phys. Chem. A 102, 4059 (1998); T. Siebert, M. Schmitt, A. Vierheilig, G. Flachenecker, V. Engel, A. Materny, and W. Kiefer, J. Raman Spectrosc. 31, 25 (2000); S. Meyer and V. Engel, ibid. 31, 33 (2000).
33. M. Schmitt. G. Knopp, A. Materny, and W. Kiefer, Chem. Phys. Lett. 280, 339 (1997); 270, 9 (1997); J. Phys. Chem. A 102, 4059 (1998); T. Siebert, M. Schmitt, A. Vierheilig, G. Flachenecker, V. Engel, A. Materny, and W. Kiefer, J. Raman Spectrosc. 31, 25 (2000); S. Meyer and V. Engel, ibid. 31, 33 (2000).
34. M. Schmitt. G. Knopp, A. Materny, and W. Kiefer, Chem. Phys. Lett. 280, 339 (1997); 270, 9 (1997); J. Phys. Chem. A 102, 4059 (1998); T. Siebert, M. Schmitt, A. Vierheilig, G. Flachenecker, V. Engel, A. Materny, and W. Kiefer, J. Raman Spectrosc. 31, 25 (2000); S. Meyer and V. Engel, ibid. 31, 33 (2000).
35. M. Schmitt. G. Knopp, A. Materny, and W. Kiefer, Chem. Phys. Lett. 280, 339 (1997); 270, 9 (1997); J. Phys. Chem. A 102, 4059 (1998); T. Siebert, M. Schmitt, A. Vierheilig, G. Flachenecker, V. Engel, A. Materny, and W. Kiefer, J. Raman Spectrosc. 31, 25 (2000); S. Meyer and V. Engel, ibid. 31, 33 (2000).
36. R. Zadoyan and V. A. Apkarian, Chem. Phys. Lett. 326, 1 (2000).
37. D. J. Tannor, S. A. Rice, and P. Weber, J. Chem. Phys. 83, 6158 (1985).
38. W. Domcke and G. Stock, Adv. Chem. Phys. 100, 1 (1997).
39. Y. R. Shen, The Principles of Nonlinear Optics (Wiley, New York, 1984).
40. S. Mukamel, Principles of Nonlinear Spectroscopy (Oxford University Press, New York, 1999).
41. e, they lead to modulation of the many-body electronic origin, along with electronic dephasing.
42. N. Makri and K. Thompson, Chem. Phys. Lett. 291, 101 (1998); O. Kuhn and N. Makri, J. Phys. Chem. A 103, 9487 (1999).
43. N. Makri and K. Thompson, Chem. Phys. Lett. 291, 101 (1998); O. Kuhn and N. Makri, J. Phys. Chem. A 103, 9487 (1999).
44. X. Sun and W. H. Miller, J. Chem. Phys. 110, 6635 (1999).
45. S. Maeda, T. Kamisuki, and Y. Adachi, Adv. Nonlinear Spectrosc. 30, 807 (1999).
46. G. Herzberg, in Spectra of Diatomic Molecules (Van Nostrand Reinhold, New York, 1950).
47. T. Lang, K. L. Kompa. and M. Motzkus, Chem. Phys. Lett. 310, 65 (1999).
48. H. Eyring, S. H. Lin, and S. M. Lin, Basic Chemical Kinetics (Wiley-Interscience, New York, 1980).
49. G. J. Hoffman, D. G. Imre, R. Zadoyan, N. Schwentner, and V. A. Apkarian, J. Chem. Phys. 98, 9233 (1993).
50. A right-traveling packet on the X state cannot yield CARS signal. This is because, a right-traveling packet on the X state when projected to the B state will continue to travel right. According to energy conservation, to radiate an AS photon, it must return to the inner turning point of the B potential. However, the system will dephase prior to a period of evolution on the B state, therefore there will be no coherent radiation. A left going packet when promoted to the B state, will radiate at the left turning point, then turn around to stretch on the B state and dephase.
51. R. Zadoyan, D. Kohen, and V. A. Apkarian, Chem. Phys. (in press).
52. M. Ovchinnikov and V. A. Apkarian, J. Chem. Phys. 105, 10312 (1996).
53. R. Zadoyan, M. Sterling, and V. A. Apkarian, J. Chem. Soc., Faraday Trans. 92, 1821 (1996).
54. M. Ovchinnikov and V. A. Apkarian, J. Chem. Phys. 106, 5775 (1997).
55. J. W. Che, M. Messina, K. R. Wilson, V. A. Apkarian, Z. Li. C, C. Martens, R. Zadoyan, and Y. J. Yan, J. Phys. Chem. 100, 7873 (1996); C. J. Bardeen, J. Che, K. R. Wilson, V. V. Yakovlev, V. A. Apkarian, C. C. Martens, R. Zadoyan, B. Kohler, and M. Messina, J. Chem. Phys. 106, 8486 (1997).
56. J. W. Che, M. Messina, K. R. Wilson, V. A. Apkarian, Z. Li. C, C. Martens, R. Zadoyan, and Y. J. Yan, J. Phys. Chem. 100, 7873 (1996); C. J. Bardeen, J. Che, K. R. Wilson, V. V. Yakovlev, V. A. Apkarian, C. C. Martens, R. Zadoyan, B. Kohler, and M. Messina, J. Chem. Phys. 106, 8486 (1997).
57. M. Sterling, R. Zadoyan, and V. A. Apkarian, J. Chem. Phys. 104, 6497 (1996).
58. R. Zadoyan, N. Schwentner, and V. A. Apkarian, Chem. Phys. 233, 353 (1998).
59. For an example of wave packet manipulation using TRCARS in the gas phase, see G. Knopp, I. Pinkas, and Y. Prior, J. Raman Spectrosc. 31, 51 (2000).
60. D. Kohen, C. C. Marston, and D. J. Tannor, J. Chem. Phys. 107, 5236 (1997).
61. R. Zadoyan, J. Almy, and V. A. Apkarian, J. Chem. Soc., Faraday Discuss. 108, 255 (1997), and references therein.
62. M. Bargheer, P. Dietrich, K. Donovang, and N. Schwentner, J. Chem. Phys. 111, 8556 (1999).
63. N. Bloembergen, Pure Appl. Chem. 10, 1229 (1987).
64. For a detailed discussion, see M. Ovchinnikov, V. A. Apkarian, and G. A. Voth, J. Chem. Phys. (submitted).
65. W. F. Howard and L. Andrews, J. Raman Spectrosc. 2, 442 (1974);
66. J. Grzybowski and L. Andrews, J. Raman Spectrosc. ibid. 4, 99 (1975);
67. L. Andrews, Appl. Spectrosc. Rev. 11, 125 (1976).
68. J. Almy, K. Kizer, R. Zadoyan, and V. A. Apkarian, J. Phys. Chem. 104, 3508 (2000).
69. R. J. Gordon and S. A. Rice, Annu. Rev. Phys. Chem. 48, 601 (1997).
70. C. S. Guiang, and R. E. Wyatt, J. Chem. Phys. 112, 3580 (2000).
71. Y. C. Chen and J. A. Cina, J. Chem. Phys. 110, 9793 (1999);
72. E. M. Hiller and J. A. Cina, J. Chem. Phys. ibid. 105, 3419 (1996);
73. T. J. Smith and J. A. Cina, J. Chem. Phys. ibid. 104, 1272 (1996);
74. L. W. Ungar and J. A. Cina, J. Lumin. 63, 345 (1995).
75. J. S. Cao, C. J. Bardeen, and K. R. Wilson, J. Chem. Phys. 113, 1898 (2000);
76. C. J. Bardeen, J. S. Cao, F. L. H. Brown, and K. R. Wilson, Chem. Phys. Lett. 302, 405 (1999);
77. J. S. Cao, M. Messina, and K. R. Wilson, J. Chem. Phys. 106, 5239 (1997).
78. V. A. Ermoshin, A. K. Kazansky, and V. Engel, J. Chem. Phys. 111, 7807 (1999);
79. H. Dietz and V. Engel, J. Chem. Phys. ibid. 110, 3335 (1999).
80. C. Meier and D. J. Tannor, J. Chem. Phys. 111, 3365 (1999).
81. R. Karmacharya, P. Gross, and S. D. Schwartz, J. Chem. Phys. 111, 6864 (1999).
82. J. J. Valentini, in Spectrometric Techniques (Academic, New York, 1985), Vol. 4.
83. S. Maeda, T. Kamisuki, and Y. Adachi, in Advances in Nonlinear Spectroscopy, edited by R. J. H. Clark and R. E. Hester (Wiley, New York, 1988), p. 253;
84. J. Nibler, Advances in Nonlinear Spectroscopy, ibid., p. 1.
85. F. Lineberger, R. Stocl, B. P. Asthana, and A. Laubereau, J. Phys. Chem. A 103, 5655 (1999).
86. H. Okamoto, H. Hayashi, K. Yoshihara, and M. Tasumi, Chem. Phys. Lett. 182, 96 (1991).
87. W. E. Bron, J. Kuhl, and B. K. Rhee, Phys. Rev. B 34, 6961 (1986).
88. F. Geist, H. Pascher, N. Frank, G. Bauer, and M. Kriechbaum, Superlattices Microstruct. 12, 477 (1992).
89. A. Vierheilig, T. Chen, P. Waltner, W. Kiefer, M. Materny, and A. H. Zewail, Chem. Phys. Lett. 312, 349 (1999).
90. A. Zumbusch, G. R. Holton, and X. S. Xie, Phys. Rev. Lett. 82, 4142 (1999).
91. M. Schmitt, G. Knopp, A. Materny, and W. Kiefer, Chem. Phys. Lett. 280, 339 (1997);
92. M. Schmitt, G. Knopp, A. Materny, and W. Kiefer, Chem. Phys. Lett. 270,9 (1997);
93. J. Phys. Chem. A 102, 4059 (1998);
94. T. Siebert, M. Schmitt, A. Vierheilig, G. Flachenecker, V. Engel, A. Materny, and W. Kiefer, J. Raman Spectrosc. 31, 25 (2000);
95. S. Meyer and V. Engel, J. Raman Spectrosc. ibid. 31, 33 (2000).
96. R. Zadoyan and V. A. Apkarian, Chem. Phys. Lett. 326, 1 (2000).
97. D. J. Tannor, S. A. Rice, and P. Weber, J. Chem. Phys. 83, 6158 (1985).
98. W. Domcke and G. Stock, Adv. Chem. Phys. 100, 1 (1997).
99. Y. R. Shen, The Principles of Nonlinear Optics (Wiley, New York, 1984).
100. S. Mukamel, Principles of Nonlinear Spectroscopy (Oxford University Press, New York, 1999).
101. e, they lead to modulation of the many-body electronic origin, along with electronic dephasing.
102. N. Makri and K. Thompson, Chem. Phys. Lett. 291, 101 (1998);
103. O. Kuhn and N. Makri, J. Phys. Chem. A 103, 9487 (1999).
104. X. Sun and W. H. Miller, J. Chem. Phys. 110, 6635 (1999).
105. S. Maeda, T. Kamisuki, and Y. Adachi, Adv. Nonlinear Spectrosc. 30, 807 (1999).
106. G. Herzberg, in Spectra of Diatomic Molecules (Van Nostrand Reinhold, New York, 1950).
107. T. Lang, K. L. Kompa, and M. Motzkus, Chem. Phys. Lett. 310, 65 (1999).
108. H. Eyring, S. H. Lin, and S. M. Lin, Basic Chemical Kinetics (Wiley-Interscience, New York, 1980).
109. G. J. Hoffman, D. G. Imre, R. Zadoyan, N. Schwentner, and V. A. Apkarian, J. Chem. Phys. 98, 9233 (1993).
110. A right-traveling packet on the X state cannot yield CARS signal. This is because, a right-traveling packet on the X state when projected to the B state will continue to travel right. According to energy conservation, to radiate an AS photon, it must return to the inner turning point of the B potential. However, the system will dephase prior to a period of evolution on the B state, therefore there will be no coherent radiation. A left going packet when promoted to the B state, will radiate at the left turning point, then turn around to stretch on the B state and dephase.
111. R. Zadoyan, D. Kohen, and V. A. Apkarian, Chem. Phys. (in press).
112. M. Ovchinnikov and V. A. Apkarian, J. Chem. Phys. 105, 10312 (1996).
113. R. Zadoyan, M. Sterling, and V. A. Apkarian, J. Chem. Soc., Faraday Trans. 92, 1821 (1996).
114. M. Ovchinnikov and V. A. Apkarian, J. Chem. Phys. 106, 5775 (1997).
115. J. W. Che, M. Messina, K. R. Wilson, V. A. Apkarian, Z. Li, C. C. Martens, R. Zadoyan, and Y. J. Yan, J. Phys. Chem. 100, 7873 (1996);
116. C. J. Bardeen, J. Che, K. R. Wilson, V. V. Yakovlev, V. A. Apkarian, C. C. Martens, R. Zadoyan, B. Kohler, and M. Messina, J. Chem. Phys. 106, 8486 (1997).
117. M. Sterling, R. Zadoyan, and V. A. Apkarian, J. Chem. Phys. 104, 6497 (1996).
118. R. Zadoyan, N. Schwentner, and V. A. Apkarian, Chem. Phys. 233, 353 (1998).
119. For an example of wave packet manipulation using TRCARS in the gas phase, see G. Knopp, I. Pinkas, and Y. Prior, J. Raman Spectrosc. 31, 51 (2000).
120. D. Kohen, C. C. Marston, and D. J. Tannor, J. Chem. Phys. 107, 5236 (1997).