Recent highlights in hemicarcerand chemistry

Accounts of Chemical Research

Volumn 34, Issue 2, 2001, Pages 95-105

  Warmuth, R ^a   Yoon, Juyoung ^b  

^a KANSAS STATE UNIVERSITY   (United States)

^b Silla University   (South Korea)

Author keywords

[No Author keywords available]

Indexed keywords

HEMICARCERAND; ORGANIC COMPOUND; POLYMER; UNCLASSIFIED DRUG;

ARTICLE; CHEMICAL ANALYSIS; CHEMICAL BINDING; CHEMICAL STRUCTURE; INORGANIC CHEMISTRY; ORGANIC CHEMISTRY; STRUCTURE ANALYSIS; SYNTHESIS;

CHEMISTRY, INORGANIC; MOLECULAR STRUCTURE;

EID: 0035113944     PISSN: 00014842     EISSN: None     Source Type: Journal    
DOI: 10.1021/ar980082k     Document Type: Article

References (61)

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4. The Dendric box: Shape-selective liberation of encapsulated guests
5. Filled buckyballs: Recent developments from the endohedral metallofullerenes of lanthanides
6. 60
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9. A highly adaptive and strongly binding hemicarcerand
10. Hemicarcerands with interiors potentially capable of binding large guests
11. Templation in the formation of carceplexes
12. Study of templation and molecular encapsulation using highly stable and guest-selective self-assembling structures
13. Crystal structure and thermodynamics of reversible molecular capsules
14. Template effects in the formation of a tetramethylene-bridged hemicarceplex
15. Self-assembling capsules
16. Self-assembling cavities: Present and future
17. Self-assembly of benzyl alcohol derived deep-cavity cavitands: A new, highly efficient moiety for irreversible assemblies?
18. Molecular hosts and guests, and their complexes (Nobel address)
19. The mechanism of the slippage approach to rotaxanes. Origin of "all-or-nothing" substituent effect
20. Constrictive and intrinsic binding in a carcerand containing four portals
21. Elucidation of "twistomers" in container compounds
22. 4v tetraoxatetrathiahemicarceplexes
23. Gating as a control element in constrictive binding and guest release by hemicarcerands
24. Mechanism and thermodynamics of guest escape from a carcerand
25. Stepwise shell closures provide hosts that expose or protect guests from outer-phase reactants
26. Synthesis, binding properties, and structures of seven new hemicarcerands each composed of two bowls bridged by three tetramethylenedioxy groups and a fourth unique linkage
27. Dissymmetric new hemicarcerands containing four bridges of different lengths
28. Decomplexation rate comparisons of hemicarceplexes whose single unique host bridge is changed in length and blocking power
29. Correlations of structure with binding ability involving nine hemicarcerand hosts and twenty-four guests
30. Guest-assisted and guest-inhibited shell closures provide differently shaped carceplexes and hemicarceplexes
31. Stereoselectivity in guest release from constrictive binding in a hemicarceplexes
32. Chiral recognition properties in complexation of two asymmetric hemicarcerands
33. Chiral and somewhat hydrophilic hemicarceplexes
34. The first water-soluble hemicarceplexes
35. Highly organized spherical hosts that bind organic guests in aqueous solution with micromolar affinity: Microcalorimetry studies
36. The taming of cyclobutadiene
37. Cyclobutadiene
38. Phenyllithium, the key to a new chemistry of organo-metallic compounds
39. 14 with potassium amide
40. o-Benzyne: Strained alkyne or a cumulene? -NMR characterization in a molecular container
41. 13C NMR spectra of benzocyclopropenone in liquid solutions at 193 Κ
42. Theoretical structures, aromaticity, and magnetic properties of o-benzyne
43. First innermolecular diels-alder reaction of o-benzyne inside a molecular container compound
44. Chemistry, kinetics, and mechanisms of triplet carbene processes in low-temperature glasses and solids
45. Cycloaddition of o-benzyne to benzene and the inner phase of a hemicarcerand
46. 1,2,4,6-Cycloheptatetraene: Room-temperature stabilization inside a hemicarcerand
47. Chemistry and properties of cycloheptatetraene in the inner phase of a hemicarcerand
48. Strained cyclic cumulenes
49. 6 rearrangements
50. 6 potential energy surface revisited: Relative energies and IR assignment
51. Carbenes and the O-H bond: Cyclopentadienylidene and cycloheptatrienylidene
52. Through-shell oxidation and reduction reactions of guests in a hollow container single molecule
53. Syntheses of two kinds of dimeric hemicarcerand systems
54. Electrochemistry of encapsulated guests: Ferrocene inside Cram's hemicarcerands
55. Free energy dependence of intermolecular triplet energy transfer: Observation of the inverted region
56. Triplet energy transfer through the walls of hemicarcerands: Temperature dependence and the role of internal reorganization energy