Novel O- and N-linked inositol oligomers: A new class of unnatural saccharide mimics

Synthesis

Volumn , Issue 6, 2001, Pages 952-956

  Paul, Bernhard J ^a   Martinot, Theodore A ^a   Willis, Jerremey ^a   Hudlicky, Tomas ^a  

^a University of Florida ^*  (United States)

Author keywords

Aziridines; Epoxides; Inositols; Oligosaccharides; Ring opening

Indexed keywords

BENZENE; CATALYSIS; CELLS; ENZYMES; FERMENTATION; SYNTHESIS (CHEMICAL);

CHEMO-ENZYMATIC APPROACH;

OLIGOMERS;

AZIRIDINE DERIVATIVE; BROMOBENZENE; CARBOHYDRATE; EPOXIDE; INOSITOL; OLIGOMER;

ARTICLE; CHIRALITY; ESCHERICHIA COLI; FERMENTATION; MOLECULAR MODEL; PROTON NUCLEAR MAGNETIC RESONANCE; STRUCTURE ANALYSIS; SYNTHESIS;

EID: 0035033663     PISSN: 00397881     EISSN: None     Source Type: Journal    
DOI: 10.1055/s-2001-13397     Document Type: Article

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15. The ratio of 18a:18b seems to vary considerably with the reaction scale. Although we have separated 18a and 18b to establish their regiochemistry, it is not necessary to do so for preparative runs, since both ultimately yield 20.
16. These results will be reported in an upcoming full paper.
17. Restrepo-Sanchez, N. PhD dissertation; University of Cali: Columbia, 2001, work performed at the University of Florida.
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