Biomimetic catalysis of catechol cleavage by O2 in organic solvents - Role of accessibility of O2 to FeIII in 2,11-diaza[3,3](2,6)pyridinophane-type catalysts

European Journal of Inorganic Chemistry

Volumn , Issue 9, 2001, Pages 2249-2254

  Raffard, Nathalie ^a   Carina, Riccardo ^b   Simaan, A Jalila ^a   Sainton, Joëlle ^a   Rivière, Eric ^a   Tchertanov, Luba ^c   Bourcier, Sophie ^d   Bouchoux, Guy ^d   Delroisse, Michel ^b   Banse, Frédéric ^a   Girerd, Jean Jacques ^a  

^a CNRS   (France)

^b UNILEVER RESEARCH   (United Kingdom)

^c INSTITUT DE CHIMIE DES SUBSTANCES NATURELLES   (France)

^d LABORATOIRE HÉTÉROÉLÉMENTS ET COORDINATION   (France)

Author keywords

Catalysis; Enzyme models; Iron; N ligands; Oxygen

Indexed keywords

BIOMIMETIC PROCESSES; CATALYSIS; CHARGE TRANSFER; LIGANDS; ORGANIC SOLVENTS; OXYGEN; PHENOLS; REACTION RATES; SYNTHESIS (CHEMICAL); X RAY DIFFRACTION;

BIOMIMETIC CATALYSIS; CATALYSE; CATECHOLATE; ENZYME MODELS; MACRO-CYCLIC LIGANDS; N LIGANDS; N-LIGANDS; SYNTHESISED; TETRADENTATE MACROCYCLIC; ]+ CATALYST;

IRON;

CATECHOL; IRON; IRON COMPLEX; LIGAND; ORGANIC SOLVENT; OXYGEN; OXYGENASE;

ARTICLE; CATALYSIS; CATALYST; CHEMICAL REACTION KINETICS; CHEMOREACTIVITY; COMPLEX FORMATION; CRYSTAL STRUCTURE; ENZYME ACTIVITY; OXIDATION; SPECTROSCOPY; STEREOSPECIFICITY; STOICHIOMETRY; SYNTHESIS;

EID: 0034873243     PISSN: 14341948     EISSN: None     Source Type: Journal    
DOI: 10.1002/1099-0682(200109)2001:9<2249::AID-EJIC2249>3.0.CO;2-3     Document Type: Article

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