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0345252434
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note
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In a typical experiment, a dry round-bottom flask with a magnetic stir bar was charged with CuBr (0.13 g, 0.94 mmol), 2,2′-bipyridine (0.44 g, 2.8 mmol), styrene (10 mL, 0.087 mol), and diphenyl ether (10 mL). The flask was fitted with a rubber septum and degassed by three freeze-pump-thaw cycles. The flask was then immersed in an oil bath thermostated at 110°C. The polymerization was initiated by the addition of degassed 1-phenylethyl bromide (0.13 mL, 0.94 mmol). After 6.5 h, the polystyrene macroinitiator was obtained by precipitation into methanol.
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0032047460
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Ohno, K; Goto, A.; Fukuda, T.; Xia, J.; Matyjaszewski, K. Macromolecules 1998, 31, 2699.
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(1998)
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, pp. 2699
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Ohno, K.1
Goto, A.2
Fukuda, T.3
Xia, J.4
Matyjaszewski, K.5
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0345252435
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note
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In a typical experiment, a dry glass tube with a magnetic stir bar was charged with CuBr (10.0 mg, 0.07 mmol), ligand (0.07 or 0.14 mmol), polystyrene macroinitiator (0.2 g, 0.06 mmol), DVB, and anisole (∼1 mL). The glass tube was degassed by three freeze-pump-thaw cycles and sealed under vacuum. The glass tube was then immersed in an oil bath thermostated at 110°C. After a certain time, the glass tube was taken out and broken. The sample was dissolved in THF to measure conversion (GC) and molecular weight (SEC).
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