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23
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70350481046
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2,3,6,7,10,11-Hexakis(1-carboxypentyl-6-oxy)triphenylene and 2,3,6,7,10,-11-hexakis(1-carboxydecyl-6-oxy)triphenylene were obtained by coupling the benzyl ester protected 6-bromohexanoic acid and 11-bromoundecanoic acid, respectively, with 2,3,6,7,10,11-hexahydroxytriphenylene (N. Boden, R. C. Borner, R. J. Bushby, A. N. Cammidge, M. V. Jesudason, Liq. Cryst. 1993, 15, 851) and then removing the benzyl ester protecting groups by hydrogenolysis.
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24
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26
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0343121046
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note
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A is Avogadro's number.
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28
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0343121047
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note
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The following abbreviations are used: DCC = 1,3-dicyclohexylcarbodiimide, HOBT = 1-hydroxybenzotriazole, HOAT = 1-hydroxy-7-azabenzotriazole.
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