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MALDI-TOF spectra of multi-crown dendrimers 1-3 are available as Supporting Information; see footnote on the first page of this article.
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3) was lower than 1% under the experimental conditions used.
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At pH < 5, the solubility of lipophilic POPAM dendrimers in the aqueous phase is noticeably increased. This is obviously due to the higher hydrophilicity of the higher protonation state. Thus, dendrimers incorporating amino groups are rather unsuitable as extradants in more acidic media.
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85153187647
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note
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-4 M) extracts 42.1% of the pertechnetate into the organic phase. The analogous multi-crown dendrimer 3 extracts 54.1% of the pertechnetate under the same experimental conditions.
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