Micellar catalysis for epoxidation reactions

Industrial and Engineering Chemistry Research

Volumn 40, Issue 23, 2001, Pages 5240-5245

  Van Den Brocke, L J P ^a   De Bruijn, V G ^a   Heijnen, J H M ^a   Keurentjes, J T F ^a  

^a EINDHOVEN UNIVERSITY OF TECHNOLOGY   (Netherlands)

Author keywords

[No Author keywords available]

Indexed keywords

CATALYSIS; HYDROGEN PEROXIDE; OXIDATION; PROPYLENE;

COCATALYSTS;

MICELLES;

ALKENE DERIVATIVE; DICHLOROMETHANE; HYDROGEN PEROXIDE; IMIDAZOLE; PORPHYRIN; PROPYLENE; TRITON X 100;

AQUEOUS SOLUTION; CATALYST; HYDROGEN PEROXIDE; OXIDATION; PROPYLENE;

AQUEOUS SOLUTION; CATALYSIS; CATALYST; CONFERENCE PAPER; EPOXIDATION; MICELLE; MOLECULAR STABILITY; SOLUBILITY;

EID: 0034747281     PISSN: 08885885     EISSN: None     Source Type: Journal    
DOI: 10.1021/ie001079j     Document Type: Conference Paper

References (19)

1. Surfactant-Based Separation Processes; Scamehorn, J. F., Harwell, J. H., Eds.; Surfactants Science Series; Marcel Dekker: New York, 1989; Vol. 33.
2. Fendler, J. H.; Fendler, E. J. Catalysis in Micellar and Macromolecular Systems; Academic Press: New York, 1975.
3. Rathman, J. F. Micellar Catalysis. Curr. Opln. Colloid Interface Sci. 1996, 1, 514.
4. Alexandris, P.; Hatton, T. A. Poly(Ethylene Oxide)-Poly(Propylene oxide)-Poly (Ethylene Oxide) Block Copolymer Surfactants in Aqueous Solutions and at Interfaces: Thermodynamics, Structure, Dynamics and Modeling. Colloid Surf. 1995, 96, 1.
5. Monti, D.; Tagliatesta, P.; Mancini, G.; Boschi, T. Micelle-Bound Metalloporphyrins as Highly Selective Catalysts for the Epoxidation of Alkenes. Angew. Chem., Int. Ed. Engl. 1998, 37, 1131.
6. 2 Catalyzed by Manganese Porphyrins and Imidazole: Selection of the Best Catalytic System and Nature of the Active Oxygen Species. J. Am. Chem. Soc. 1988, 110, 8462.
7. Iwanejko, R.; Battioni, P.; Mansuy, D.; Mlodnicka, T. Reactivity of Polyhalogenated Metalloporphyrins in Epoxidation of Propene with Magnesium Monoperoxyphthalate. J. Mol. Catal. A 1996, 111, 7.
8. Haber, J.; Iwanejko, R.; Poltowicz, J.; Battioni, P.; Mansuy, D. Pernitrated Metallo-porphyrins as Catalysts in Oxidation with Magnesium Monoperoxophthalate Part II. Epoxidation of Linear Olefins. J. Mol. Catal. A 2000, 152, 117.
9. 2 or NaOCl Alkene Epoxidation. J. Chem. Soc., Perkin Trans. 1 1993, 111, 1345.
10. Banfi, S.; Cavalieri, C.; Cavazzini, M.; Trebicka, A. Mn-Tetraarylporphyrins bearing N-Alkylsulphonamido Tails: Effect of the Length and Polarity of the Chains on Physical Properties and Reactivity. J. Mol. Catal. A 2000, 151, 17.
11. Katsuki, T. Mn-salen Catalyst, Competitor of Enzymes, for Asymmetric Epoxidation. J. Mol. Catal. A 1996, 113, 87.
12. Pietikäinen, P. Convenient Asymmetric (Salen)Mn(III)-catalyzed Epoxidation of Unfunctionalized Alkenes with Hydrogen Peroxide using Carboxylate Salt Cocatalysts. Tetrahedron 1998, 54, 4319.
13. Copéret, C.; Adolfsson, H.; Sharpless, K. B. A Simple and Efficient Method for Epoxidation of Terminal Alkenes. Chem. Commun. 1997, 1565.
14. 2 and Catalytic Methyltrioxorhenium/Pyridine: Pyridine-Mediated Ligand Acceleration. J. Am. Chem. Soc. 1997, 119, 6189.
15. Chen, L. Y.; Chuah, G. K.; Jaenicke, S. Propylene Epoxidation with Hydrogen Peroxide Catalyzed by Molecular Sieves containing Framework Titanium. J. Mol. Catal. A 1998, 132, 281.
16. 3. Russ. J. Phys. Chem. 1997, 71, 1084.
17. Nijhuis, T. A.; Huizinga, B. J.; Makkee, M.; Moulijn, J. A. Direct Epoxidation of Propene using Gold Dispersed on TS-1 and other Titanium-containg Supports. Ind. Eng. Chem. Res. 1999, 38, 884.
18. Thellend, A.; Battioni, P.; Mansuy, D. Ammonium Acetate as a very Simple and Efficient Cocatalyst for Manganese Porphyrin-catalysed Oxygenation of Hydrocarbons by Hydrogen Peroxide. J. Chem. Soc., Chem. Commun. 1994, 1035.
19. Kirk-Othmer Encyclopedia of Chemical Technology; KirkOthmer: New York, 1996; Vol. 20, p 271.