Direct epoxidation of propene using gold dispersed on TS-1 and other titanium-containing supports

Industrial and Engineering Chemistry Research

Volumn 38, Issue 3, 1999, Pages 884-891

  Nijhuis, T Alexander ^a   Huizinga, Bart J ^a   Makkee, Michiel ^a   Moulijn, Jacob A ^a  

^a DELFT UNIVERSITY OF TECHNOLOGY   (Netherlands)

Author keywords

[No Author keywords available]

Indexed keywords

ADSORPTION; CATALYST ACTIVITY; CATALYST DEACTIVATION; CATALYST SUPPORTS; GOLD; HYDROGEN; OXYGEN; TITANIUM;

EPOXIDATION;

PROPYLENE;

GOLD; HYDROGEN; PROPYLENE; TITANIUM;

ARTICLE; CATALYSIS; CATALYST; CHEMICAL REACTION KINETICS; EPOXIDATION; LOW TEMPERATURE; MOLECULAR INTERACTION; REACTION ANALYSIS;

EID: 0033104030     PISSN: 08885885     EISSN: None     Source Type: Journal    
DOI: 10.1021/ie980494x     Document Type: Article

References (16)

1. 2 catalysts. Appl. Catal. B 1996, 8, 417.
2. 2 Catalysts. Am. Chem. Soc., Div. Pet. Chem. 1996, 41, 71.
3. 2 systems Catal. Lett. 1997, 43, 51.
4. 2 by vacuum calcination. Res. Chem. Int. 1993, 19, 1.
5. 4. J. Catal. 1993, 144, 175.
6. 2. Nucl. Instrum. Methods Phys. Res., Sect. B 1997, 121, 503.
7. Thangaraj, A.; Aepen, M. J.; Sivasanker, S.; Ratnasami, P. Studies on the synthesis of titanium silicalite, TS-1. Zeolites 1992, 12, 943.
8. Rajadhyaksha, R. A.; Hausinger, G.; Zeilinger, H.; Ramstetter, A.; Schmelz, H.; Knozinger, H. Vanadium supported on titanium-silica. Physical characterization and activity for the selective reduction on nitric oxide. Appl. Catal. 1989, 51, 67.
9. Kooyman, P. Titanium-silicalite-1 and related systems. Ph.D. Thesis, Delft University of Technology, Delft, The Netherlands, 1993 (in English).
10. Thangaraj, A.; Kumar, R.; Mirajkar, S. P.; Ratnasamy, P. Catalytic properties of crystalline titanium silicates. I. Synthesis and characterization of titanium-rich zeolites with MFI structure. J. Catal. 1991, 130, 1.
11. Haas, J.; Kulawik, K.; Schulz-Ekloff, G.; Jaeger, N. I. Comparative spectroscopic study of TS-1 and zeolite-hosted extraframework titanium oxide dispersions. Stud. Surf. Sci. Catal. 1994, 84, 2261.
12. Clerici, M. G.; Bellussi, G.; Romano, U. Synthesis of propylene oxide from propylene and hydrogen peroxide catalyzed by titanium silicalite. J. Catal. 1991, 129, 159.
13. Clerici, M. G.; Ingalla, P. Epoxidation of lower olefins with hydrogen peroxide and titanium silicalite. J. Catal. 1993, 140, 71.
14. Naito, S.; Tanimoto, M. Oxygen enhanced exchange and hydrogenation over supported gold catalysts. J. Chem. Soc., Chem. Commun. 1988, 832.
15. Olivera, P. P.; Patrito, E. M.; Sellers, H. Hydrogen peroxide synthesis over metallic catalysts. Surf. Sci. 1994, 313, 25.
16. Haruta, M. Gold as a low-temperature oxidation catalyst: factors controlling activity and selectivity. Stud. Surf. Sci. Catal. 1997, 110, 123.