-
5
-
-
0030110164
-
-
L. A. Bumm, J. J. Arnold, M. T. Cygan, T. D. Dunbar, T. P. Burgin, L. Jones, II, D. L. Allara, J. M. Tour, P. S. Weiss Science 1996 271 1705.
-
(1996)
Science
, vol.271
, pp. 1705
-
-
Bumm, L.A.1
Arnold, J.J.2
Cygan, M.T.3
Dunbar, T.D.4
Burgin, T.P.5
Jones, L.6
Allara, D.L.7
Tour, J.M.8
Weiss, P.S.9
-
6
-
-
27944487323
-
Molecular-level Electronics
-
V. Balzani, Ed., Wiley, New York
-
A. P. deSilva Ed., Molecular-level Electronics. In: Electron Transfer in Chemistry, V. Balzani, Ed., vol. 5, Wiley, New York, 2001.
-
(2001)
Electron Transfer in Chemistry
, vol.5
-
-
DeSilva, A.P.1
-
9
-
-
0034682887
-
-
C. P. Collier, G. Mattersteig, E. W. Wong, Y. Luo, K. Beverly, J. Sampaio, F. M. Raymo, J. F. Stoddart, J. R. Heath Science 2000 289 1172.
-
(2000)
Science
, vol.289
, pp. 1172
-
-
Collier, C.P.1
Mattersteig, G.2
Wong, E.W.3
Luo, Y.4
Beverly, K.5
Sampaio, J.6
Raymo, F.M.7
Stoddart, J.F.8
Heath, J.R.9
-
10
-
-
0031191655
-
-
A. P. de Silva, H. Q. N. Gunaratne, T. Gunnlaugsson, A. J. M. Huxley, C. P. McCoy, J. T. Rademacher, T. E. Rice Chem. Rev. 1997 97 1515.
-
(1997)
Chem. Rev.
, vol.97
, pp. 1515
-
-
De Silva, A.P.1
Gunaratne, H.Q.N.2
Gunnlaugsson, T.3
Huxley, A.J.M.4
McCoy, C.P.5
Rademacher, J.T.6
Rice, T.E.7
-
19
-
-
11344284526
-
-
F. H. Allen, O. Kennard, D. G. Watson, L. Brammer, A. G. Orpen, R. Taylor J. Chem. Soc., Perkin Trans. 2 1987 S1.
-
(1987)
J. Chem. Soc., Perkin Trans.
, vol.2
, pp. S1
-
-
Allen, F.H.1
Kennard, O.2
Watson, D.G.3
Brammer, L.4
Orpen, A.G.5
Taylor, R.6
-
23
-
-
85032759535
-
-
Although the cation–radical of Awas stable in solution (as established by the reversible CV), it was not sufficiently persistent to allow isolation of the cation–radical salt A+ SbCl6−. Thus B++ and not A+ was used to establish the geometrical (bond-length) change in Dupon 1-electron oxidation to the cation–radical D+ with q = 1
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Although the cation–radical of A was stable in solution (as established by the reversible CV), it was not sufficiently persistent to allow isolation of the cation–radical salt A + SbCl6−. Thus B ++ and not A + was used to establish the geometrical (bond-length) change in D upon 1-electron oxidation to the cation–radical D+ with q = 1.
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-
-
-
24
-
-
85032770304
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All the aromatic donors in Classes I–III show chemically reversible cyclic voltammograms with anodic/cathodic peak current ratio in the value: 0.9, 1.1. The quantitative electrode behavior relative to the electrochemical reversibility of these interesting redox couples will be addressed in a later study
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All the aromatic donors in Classes I–III show chemically reversible cyclic voltammograms with anodic/cathodic peak current ratio in the value: 0.9, 1.1. The quantitative electrode behavior relative to the electrochemical reversibility of these interesting redox couples will be addressed in a later study.
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-
-
-
25
-
-
38549170136
-
-
Such a stabilization energy may be described in quantum mechanical terms, as the electronic coupling element HAB. See, e.g
-
C. Creutz, M. D. Newton, N. Sutin J. Photochem. Photobiol. A: Chem. 1994 82 47 Such a stabilization energy may be described in quantum mechanical terms, as the electronic coupling element HAB. See, e.g. The comproportionation constants (and hence the free energy changes) between cation–radicals and their dications will be presented separately.
-
(1994)
J. Photochem. Photobiol. A: Chem.
, vol.82
, pp. 47
-
-
Creutz, C.1
Newton, M.D.2
Sutin, N.3
-
26
-
-
0003438540
-
-
Cornell University Press, Ithaca, New York
-
L. Pauling Nature of the Chemical Bond, Cornell University Press, Ithaca, New York, 1960 280.
-
(1960)
Nature of the Chemical Bond
, pp. 280
-
-
Pauling, L.1
-
32
-
-
0001179176
-
-
Wiley, New York
-
R. N. McDonald and T. W. Campbell Organic Syntheses, Wiley, New York, 1973, vol. 5, p. 499.
-
(1973)
Organic Syntheses
, vol.5
, pp. 499
-
-
McDonald, R.N.1
Campbell, T.W.2
-
36
-
-
0004055425
-
-
2nd edn., Pergamon, New York
-
D. D. Perrin, W. L. F. Armarego and D. R. Perrin Purification of Laboratory Chemicals, 2nd edn., Pergamon, New York, 1980.
-
(1980)
Purification of Laboratory Chemicals
-
-
Perrin, D.D.1
Armarego, W.L.F.2
Perrin, D.R.3
-
37
-
-
84918678077
-
-
references therein
-
K. Kumada Pure Appl. Chem. 1980 52 669 and references therein.
-
(1980)
Pure Appl. Chem.
, vol.52
, pp. 669
-
-
Kumada, K.1
-
39
-
-
85032760442
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5 was prepared by the coupling between 2,5-dimethoxy-4-methyl-4″-bromo-1,1′:4′,1″-terphenyl and its Grignard derivative
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5 was prepared by the coupling between 2,5-dimethoxy-4-methyl-4″-bromo-1,1′:4′,1″-terphenyl and its Grignard derivative.
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41
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85032759534
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Note that the UV-Vis-NIR absorption of various polyphenylene cation–radicals generated by triethyloxonium hexachloroantimonate (Et3O+ SbCl6) were identical in all respect to those generated by OMN+ SbCl6 in anhydrous dichloromethane
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Note that the UV-Vis-NIR absorption of various polyphenylene cation–radicals generated by triethyloxonium hexachloroantimonate (Et3O+ SbCl6) were identical in all respect to those generated by OMN+ SbCl6 in anhydrous dichloromethane.
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