Kinetic trapping of host-guest complexes in a polymeric matrix

Chemical Communications

Volumn , Issue 6, 2000, Pages 447-448

  Ilhan, Faysal ^a   Diamondis, Laura ^a   Gautreau, Leigh ^a   Rotello, Vincent M ^a  

^a UNIVERSITY OF MASSACHUSETTS   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

FLAVINE NUCLEOTIDE; POLYMER; POLYSTYRENE; TRIAZINE DERIVATIVE;

ARTICLE; CHEMICAL REACTION KINETICS; COMPLEX FORMATION; FILM; MOLECULAR INTERACTION; SPIN TRAPPING;

EID: 0034696596     PISSN: 13597345     EISSN: None     Source Type: Journal    
DOI: 10.1039/a909454g     Document Type: Article

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13. For other studies utilizing spin-coating technique, see: C. J. Durning, B. O'Shaughnessy, U. Sawhney, D. Nguyen, J. Majewski and G. S. Smith, Macromolecules, 1999, 32, 6772; R. J. Jackman, D. C. Duffy, O. Cherniavskaya and G. M. Whitesides, Langmuir, 1999, 15, 2973; N. Tirelli, U. W. Suter, A Altomare, R. Solaro, F. Ciardelli, S. Follonier, Ch. Bosshard and P. Günter, Macromolecules, 1998, 31, 2152.
14. For other studies utilizing spin-coating technique, see: C. J. Durning, B. O'Shaughnessy, U. Sawhney, D. Nguyen, J. Majewski and G. S. Smith, Macromolecules, 1999, 32, 6772; R. J. Jackman, D. C. Duffy, O. Cherniavskaya and G. M. Whitesides, Langmuir, 1999, 15, 2973; N. Tirelli, U. W. Suter, A Altomare, R. Solaro, F. Ciardelli, S. Follonier, Ch. Bosshard and P. Günter, Macromolecules, 1998, 31, 2152.
15. For other studies utilizing spin-coating technique, see: C. J. Durning, B. O'Shaughnessy, U. Sawhney, D. Nguyen, J. Majewski and G. S. Smith, Macromolecules, 1999, 32, 6772; R. J. Jackman, D. C. Duffy, O. Cherniavskaya and G. M. Whitesides, Langmuir, 1999, 15, 2973; N. Tirelli, U. W. Suter, A Altomare, R. Solaro, F. Ciardelli, S. Follonier, Ch. Bosshard and P. Günter, Macromolecules, 1998, 31, 2152.
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17. 4 dessicator. After casting, films were dried in vacuo for 16 h prior to spectroscopic observations.
18. -2 M flavin 1 showed 96% transmittance at 445 nm.
19. Fluorescence measurements were performed using a machined slide holder. The slides were vertically set, with the polymer coated surface at an angle of 60° to the excitation beam.
20. The spin-coated films were homogeneous, indicating the lack of macroscopic phase separation.
21. For other examples of similar host-guest complexes, see: R. Deans and V. M. Rotello, J. Org. Chem., 1997, 62, 4528; E. Breinlinger, A. Niemz and V. M. Rotello, J. Am. Chem. Soc., 1995, 117, 5379; A. D. Hamilton and D. Van Engen, J. Am. Chem. Soc., 1987, 109, 5035; A. V. Muehldorf, D. Van Engen, J. C. Warner and A. D. Hamilton, J. Am. Chem. Soc., 1988, 110, 6561.
22. For other examples of similar host-guest complexes, see: R. Deans and V. M. Rotello, J. Org. Chem., 1997, 62, 4528; E. Breinlinger, A. Niemz and V. M. Rotello, J. Am. Chem. Soc., 1995, 117, 5379; A. D. Hamilton and D. Van Engen, J. Am. Chem. Soc., 1987, 109, 5035; A. V. Muehldorf, D. Van Engen, J. C. Warner and A. D. Hamilton, J. Am. Chem. Soc., 1988, 110, 6561.
23. For other examples of similar host-guest complexes, see: R. Deans and V. M. Rotello, J. Org. Chem., 1997, 62, 4528; E. Breinlinger, A. Niemz and V. M. Rotello, J. Am. Chem. Soc., 1995, 117, 5379; A. D. Hamilton and D. Van Engen, J. Am. Chem. Soc., 1987, 109, 5035; A. V. Muehldorf, D. Van Engen, J. C. Warner and A. D. Hamilton, J. Am. Chem. Soc., 1988, 110, 6561.
24. For other examples of similar host-guest complexes, see: R. Deans and V. M. Rotello, J. Org. Chem., 1997, 62, 4528; E. Breinlinger, A. Niemz and V. M. Rotello, J. Am. Chem. Soc., 1995, 117, 5379; A. D. Hamilton and D. Van Engen, J. Am. Chem. Soc., 1987, 109, 5035; A. V. Muehldorf, D. Van Engen, J. C. Warner and A. D. Hamilton, J. Am. Chem. Soc., 1988, 110, 6561.
25. For binding experiments utilizing fluorescent probes, see: M. D. Greaves and V. M. Rotello, J. Am. Chem. Soc., 1997, 119, 10569; D. C. Myles and K. Motesharei, J. Am. Chem. Soc., 1994, 116 ,7413; K. Inoue, K. Kinoshita, H. Nakahara and T. Tanigaki, Macromolecules, 1990, 23, 1227.
26. For binding experiments utilizing fluorescent probes, see: M. D. Greaves and V. M. Rotello, J. Am. Chem. Soc., 1997, 119, 10569; D. C. Myles and K. Motesharei, J. Am. Chem. Soc., 1994, 116 ,7413; K. Inoue, K. Kinoshita, H. Nakahara and T. Tanigaki, Macromolecules, 1990, 23, 1227.
27. For binding experiments utilizing fluorescent probes, see: M. D. Greaves and V. M. Rotello, J. Am. Chem. Soc., 1997, 119, 10569; D. C. Myles and K. Motesharei, J. Am. Chem. Soc., 1994, 116 ,7413; K. Inoue, K. Kinoshita, H. Nakahara and T. Tanigaki, Macromolecules, 1990, 23, 1227.
28. a is for comparison purposes, as this system is obviously not in the standard state.
29. R. Deans, F. Ilhan and V. M. Rotello, Macromolecules, 1999, 32, 4956.
30. For stress-strain effects on hydrogen bonding, see: M. J. Loboda and J. A. Seifferly, J. Mater. Res., 1996, 11, 391; M. Kawagoe and M. Morita, J. Mater. Sci., 1994, 29, 6041; R. E. Taylorsmith and R. A. Register, Macromolecules, 1993, 26, 2802.
31. For stress-strain effects on hydrogen bonding, see: M. J. Loboda and J. A. Seifferly, J. Mater. Res., 1996, 11, 391; M. Kawagoe and M. Morita, J. Mater. Sci., 1994, 29, 6041; R. E. Taylorsmith and R. A. Register, Macromolecules, 1993, 26, 2802.
32. For stress-strain effects on hydrogen bonding, see: M. J. Loboda and J. A. Seifferly, J. Mater. Res., 1996, 11, 391; M. Kawagoe and M. Morita, J. Mater. Sci., 1994, 29, 6041; R. E. Taylorsmith and R. A. Register, Macromolecules, 1993, 26, 2802.