Thermochemistry of Oxo Transfer from Coordinated Nitrite in the Dinitro(5,10,15,20-tetrakis(o-pivalamidophenyl)porphinato)iron(III) Anion

Inorganic Chemistry

Volumn 36, Issue 9, 1997, Pages 1904-1911

  Frangione, Melanie ^a   Port, Jennifer ^a   Baldiwala, Murtuza ^a   Judd, Andrew ^a   Galley, John ^a   DeVega, Magrey ^a   Linna, Kara ^a   Caron, Leigh ^a   Anderson, Elizabeth ^a   Goodwin, John A ^a,b  

^a ECKERD COLLEGE   (United States)

^b Wall College of Business   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0001364915     PISSN: 00201669     EISSN: None     Source Type: Journal    
DOI: 10.1021/ic9608915     Document Type: Article

References (42)

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2. Tovrog, B. S.; Diamond, S. E.; Mares, F. J. Am. Chem. Soc. 1979, 101, 270-272. Diamond, S. E.; Mares, F.; Szalkiewicz, A.; Muccigrosso, D. A.; Solar, J. P. J. Am. Chem. Soc. 1982, 104, 4266-4268. Pipes, D. W.; Meyer, T. J. Inorg. Chem. 1984, 23, 2466-2472. Younathan, J. N.; Wood, S. K.; Meyer, T. J. Inorg. Chem. 1992, 31, 3280-3285. Toth, J. E.; Anson, F. C. J. Am. Chem. Soc. 1989, 111, 2444-2451. Rhodes, M. R.; Barley, M. H.; Meyer, T. J. Inorg. Chem. 1991, 30, 629-635. Keene, F. R.; Salmon, D. J.; Walsh, J. L.; Abruna, H. D.; Meyer, T. J. Inorg. Chem. 1980, 19, 1896-1903.
3. Tovrog, B. S.; Diamond, S. E.; Mares, F. J. Am. Chem. Soc. 1979, 101, 270-272. Diamond, S. E.; Mares, F.; Szalkiewicz, A.; Muccigrosso, D. A.; Solar, J. P. J. Am. Chem. Soc. 1982, 104, 4266-4268. Pipes, D. W.; Meyer, T. J. Inorg. Chem. 1984, 23, 2466-2472. Younathan, J. N.; Wood, S. K.; Meyer, T. J. Inorg. Chem. 1992, 31, 3280-3285. Toth, J. E.; Anson, F. C. J. Am. Chem. Soc. 1989, 111, 2444-2451. Rhodes, M. R.; Barley, M. H.; Meyer, T. J. Inorg. Chem. 1991, 30, 629-635. Keene, F. R.; Salmon, D. J.; Walsh, J. L.; Abruna, H. D.; Meyer, T. J. Inorg. Chem. 1980, 19, 1896-1903.
4. Tovrog, B. S.; Diamond, S. E.; Mares, F. J. Am. Chem. Soc. 1979, 101, 270-272. Diamond, S. E.; Mares, F.; Szalkiewicz, A.; Muccigrosso, D. A.; Solar, J. P. J. Am. Chem. Soc. 1982, 104, 4266-4268. Pipes, D. W.; Meyer, T. J. Inorg. Chem. 1984, 23, 2466-2472. Younathan, J. N.; Wood, S. K.; Meyer, T. J. Inorg. Chem. 1992, 31, 3280-3285. Toth, J. E.; Anson, F. C. J. Am. Chem. Soc. 1989, 111, 2444-2451. Rhodes, M. R.; Barley, M. H.; Meyer, T. J. Inorg. Chem. 1991, 30, 629-635. Keene, F. R.; Salmon, D. J.; Walsh, J. L.; Abruna, H. D.; Meyer, T. J. Inorg. Chem. 1980, 19, 1896-1903.
5. Tovrog, B. S.; Diamond, S. E.; Mares, F. J. Am. Chem. Soc. 1979, 101, 270-272. Diamond, S. E.; Mares, F.; Szalkiewicz, A.; Muccigrosso, D. A.; Solar, J. P. J. Am. Chem. Soc. 1982, 104, 4266-4268. Pipes, D. W.; Meyer, T. J. Inorg. Chem. 1984, 23, 2466-2472. Younathan, J. N.; Wood, S. K.; Meyer, T. J. Inorg. Chem. 1992, 31, 3280-3285. Toth, J. E.; Anson, F. C. J. Am. Chem. Soc. 1989, 111, 2444-2451. Rhodes, M. R.; Barley, M. H.; Meyer, T. J. Inorg. Chem. 1991, 30, 629-635. Keene, F. R.; Salmon, D. J.; Walsh, J. L.; Abruna, H. D.; Meyer, T. J. Inorg. Chem. 1980, 19, 1896-1903.
6. Tovrog, B. S.; Diamond, S. E.; Mares, F. J. Am. Chem. Soc. 1979, 101, 270-272. Diamond, S. E.; Mares, F.; Szalkiewicz, A.; Muccigrosso, D. A.; Solar, J. P. J. Am. Chem. Soc. 1982, 104, 4266-4268. Pipes, D. W.; Meyer, T. J. Inorg. Chem. 1984, 23, 2466-2472. Younathan, J. N.; Wood, S. K.; Meyer, T. J. Inorg. Chem. 1992, 31, 3280-3285. Toth, J. E.; Anson, F. C. J. Am. Chem. Soc. 1989, 111, 2444-2451. Rhodes, M. R.; Barley, M. H.; Meyer, T. J. Inorg. Chem. 1991, 30, 629-635. Keene, F. R.; Salmon, D. J.; Walsh, J. L.; Abruna, H. D.; Meyer, T. J. Inorg. Chem. 1980, 19, 1896-1903.
7. Tovrog, B. S.; Diamond, S. E.; Mares, F. J. Am. Chem. Soc. 1979, 101, 270-272. Diamond, S. E.; Mares, F.; Szalkiewicz, A.; Muccigrosso, D. A.; Solar, J. P. J. Am. Chem. Soc. 1982, 104, 4266-4268. Pipes, D. W.; Meyer, T. J. Inorg. Chem. 1984, 23, 2466-2472. Younathan, J. N.; Wood, S. K.; Meyer, T. J. Inorg. Chem. 1992, 31, 3280-3285. Toth, J. E.; Anson, F. C. J. Am. Chem. Soc. 1989, 111, 2444-2451. Rhodes, M. R.; Barley, M. H.; Meyer, T. J. Inorg. Chem. 1991, 30, 629-635. Keene, F. R.; Salmon, D. J.; Walsh, J. L.; Abruna, H. D.; Meyer, T. J. Inorg. Chem. 1980, 19, 1896-1903.
8. Castro, C. E. J. Am. Chem. Soc. 1996, 118, 3984-3985.
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10. Mashuta, M.; Scheidt, W. R. University of Notre Dame, personal communication, 1992.
11. IITpivPP(NO]; however, stopped-flow kinetics of the reaction of 1 with nitric oxide and thiophenols show a much faster decay of the intermediate than in the reaction with triphenylphosphine.
12. Goodwin, J. A.; Stanbury, D. M. Unpublished results, July 1991.
13. Nasri, H.; Haller, K.; Wang, W.; Huynh, B. H.; Scheidt, W. R. Inorg. Chem. 1993, 31, 3459-3467.
14. 2 to form XO.
15. Review of the literature to July 1996 revealed no previous measurements of this type.
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22. 19 was used as an approximation.
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24. -1. The final spectrum depends on nitrite concentration, but the identity of product(s) and details of this decomposition reaction are as yet unknown.
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26. 3 solution are consistent with the value of the equilibrium constant determined here. A reviewer has pointed out the possibility of employing more weakly coordinating anions to avoid these complications. Considering the complications in spectral stability under the conditions of excess perchlorate, it appears that other competing association equilibria from contaminant water or solvent would continue to dominate the system in the absence of a more strongly coordinating ligand.
27. 3 solution are consistent with the value of the equilibrium constant determined here. A reviewer has pointed out the possibility of employing more weakly coordinating anions to avoid these complications. Considering the complications in spectral stability under the conditions of excess perchlorate, it appears that other competing association equilibria from contaminant water or solvent would continue to dominate the system in the absence of a more strongly coordinating ligand.
28. Settin, M.; Fanning, J. C. Inorg. Chem. 1988, 27, 1431-1435.
29. Yoshimura, T. Inorg. Chim. Acta 1984, 83, 17-21.
30. 2. The correct values are reported in Table 2, and their consistency with other reported values is apparent.
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32. Eberson, L. Acta Chem. Scand. 1984, B38, 439-459.
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35. Kadish, K. M. In Iron Porphyrins; Lever, A. B. P., Gray, H. B., Eds.; Addison-Wesley: Reading, MA, 1983; Part II.
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38. The NBS Tables of Chemical Thermodynamic Properties; Lide, D. R., Ed.; Journal of Physical and Chemical Reference Data 11, Supplement 2; American Chemical Society and the American Institute for Physics: Washington, DC, 1974; p 311.
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42. This value was derived from evaluation of ΔH° values of half-reactions: Holm, R. Chem. Rev. 1987, 87, 1401-1499. An estimated correction of 5 kcal/mol = TΔS° at 25 °C was made in arriving at this ΔG° approximation.