Novel C-C and C-C-P coupling reactions using an allenylidenerhodium complex as a precursor

Journal of the American Chemical Society

Volumn 118, Issue 10, 1996, Pages 2495-2496

  Wiedemann, Ralf ^a   Steinert, Paul ^a   Gevert, Olaf ^a   Werner, Helmut ^a  

^a UNIVERSITY OF WÜRZBURG   (Germany)

Author keywords

[No Author keywords available]

Indexed keywords

ALKENE DERIVATIVE; ORGANOPHOSPHORUS COMPOUND; POLYENE;

ARTICLE; CATALYSIS; DRUG SYNTHESIS; NUCLEAR MAGNETIC RESONANCE; REACTION ANALYSIS; X RAY ANALYSIS;

EID: 0029927413     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja953911v     Document Type: Article

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7. Rh-P = 135.1 Hz).
8. Molecular structure of complex 4. Principal bond lengths (A) and interbond angles (deg): Rh-C1 2.143(5), Rh-C36 1.814(6), Rh-P1 2.359-(1), Rh-P2 2.340(1). C1-C2 1.481(6), C1-C4 1.308(6). C2-C3 1.311-(7), C4-C5 1.332(6), C36-O 1.166(8), P1-Rh-P2 164.92(4), C1-Rh-C36 165.8(2), C1-Rh-P1 91.8(1), C1-Rh-P2 93.0(1), P1-Rh-C36 89.1(2), P2-Rh-C36 89.7(2), Rh-C1-C2 116.9(3), Rh-C1-C4 127.0-(3), Rh-C36-O 172.6(5), C1-C2-C3 126.2(5), C2-C1-C4 116.0(4), C1-C4-C5 177.5(5).
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13. +].
14. Molecular structure of complex 6. Principal bond lengths (Å) and interbond angles (deg): Rh-P1 2.295(1), Rh-C1 2.170(4), Rh-C2 2.046-(3), Rh-CB 2.024(3), Rh-C1 2.388(1), C1-P2 1.752(3), C1-C2 1.455-(4), C2-C3 1.429(4). C3-C4 1.276(4), C4-C5 1.327(4), Pl-Rh-C1 94.93(4), P2-C1-C2 126.1(2), C1-C2-C3 116.7(3), C2-C3-C4 144.2-(3), C3-C4-C5 177.3(4).
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