A transition metal-hydroperoxo complex stabilized by hydrogen-bonding interaction: The first example of a hydroperoxopalladium species characterized by X-ray crystallography, (κ2-TpiPr)Pd(PPh3)(OOH) [TpiPr = hydrotris(3,5-diisopropylpyrazolyl)borato]

Chemistry Letters

Volumn , Issue 8, 1999, Pages 813-814

  Akita, Munetaka ^a   Miyaji, Taichi ^a   Hikichi, Shiro ^a   Moro Oka, Yoshihiko ^a  

^a TOKYO INSTITUTE OF TECHNOLOGY   (Japan)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0033245579     PISSN: 03667022     EISSN: None     Source Type: Journal    
DOI: 10.1246/cl.1999.813     Document Type: Article

References (24)

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17. 2):
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19. iPr= hydrotris(3,5-diisopropylpyrazolyl)borate; pz= pyrazolyl group.
20. 3; -60 °C) 20.6. Broad spectra were obtained at room temperature due to a ligand exchange process.
21. 0) and 600 parameters.
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24. M. Akita, Y. Takahashi, M. Hashimoto, S. Hikichi, and Y. Moro-oka, Angew. Chem., in press.