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The concept of constrictive binding as it relates to hemicarceplexes and their hemicarcerands is analogous to the concept of slippage in the context of pseudorotaxanes and their dumbbell components. See: Ashton, P. R.; Baxter, I.; Fyfe, M. C. T.; Raymo, F. M.; Spencer, N.; Stoddart, J. F.; White, A. J. P.; Williams, D. J. J. Am. Chem. Soc. 1998, 120, 2297-2307.
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35
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85037515656
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note
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2 over Pd/C in EtOH) of the nitro groups in the ester gave (82%) the 5-substituted-MPD. equation presented
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-
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36
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85037504740
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note
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3 was always maintained at 3 mM. All samples were sealed and monitored for their proton signals on a 400 MHz NMR spectrometer at 300 K.
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37
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85037496827
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note
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3 for 24 h prior to its use.
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38
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85037507863
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note
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4.
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