Three-dimensional hexagonal structures from a novel self-complementary molecular building block

Journal of the American Chemical Society

Volumn 122, Issue 18, 2000, Pages 4394-4402

  Krishnamohan Sharma, C V ^a   Clearfield, Abraham ^a  

^a TEXAS A AND M UNIVERSITY   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

1,10 PHENANTHROLINE; NITRILOTRI(METHYLPHOSPHONIC ACID); PHOSPHONIC ACID DERIVATIVE; UNCLASSIFIED DRUG;

ARTICLE; COMPLEX FORMATION; CRYSTAL STRUCTURE; CRYSTALLIZATION; HYDROGEN BOND; MOLECULAR DYNAMICS; PROTEIN STRUCTURE; PROTON TRANSPORT; THERMOSTABILITY; X RAY CRYSTALLOGRAPHY; X RAY DIFFRACTION;

EID: 0034630852     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja9935512     Document Type: Article

References (57)

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2. For a very good overview of recent developments in crystal engineering see the following multiauthored volumes and review articles: (a) Crystal Engineering: From Molecules and Crystals To Materials; Braga, D., Orpen, A. G., Eds.; NATO ASI series; Kluwer: Dordecht, The Netherlands, 1999. (b) Weber, E., Ed. Design of Organic Solids; Topics in Current Chemistry; Springer-Verlag, Heidelberg, 1998; Vol. 198. (c) Comprehensive Supramolecular Chemistry: Atwood, J. L., Davies, J. E. D., MacNicol, D. D., Vogtle, F., Lehn, J.-M., Eds.; Pergamon: Oxford, 1996; Vol. 6. (d) Desiraju, G. R. Angew. Chem., Int. Ed. Engl. 1995, 34, 2311-2327. (e) Aakeroy, C. B. Acta Crystallogr. 1997, B53, 569-583. (f) Braga, D.; Grepioni, F.; Desiraju, G. R. Chem. Rev. 1998, 98, 1375-1405. (g) Bernstein, J.; Davis, R. E.; Shimoni, L.; Chang, N. Angew. Chem., Int. Ed. Engl. 1995, 34, 1555-1573. (h) MacDonald, J. C.; Whitesides, G. M. Chem. Rev. 1994, 94, 2383-2420. (i) Batten, S. R.; Robson, R. Angew. Chem., Int. Ed. Engl. 1998, 37, 1460-1494. (j) Zaworotko, M. J. Coordination Polymers. In Crystal Engineering: The Design and Applications of Functional Solids; Seddon, K. R., Zaworotko, M. J., Eds.; NATO ASI series; Kluwer; Dordecht, The Netherlands, 1998. (k) Hagrman, P. J.; Hagrman, D.; Zubieta, J. Angew. Chem., Int. Ed. Engl. 1999, 38, 2639- 2684. (l) Alivisatos, A. P.; Barbara, P. F.; Castelman, A. W.; Chang, J.; Dixon, D. A.; Klein, M. L.; McLendon, G. L.; Miller, J. S.; Ratner, M. A.; Rossky, P. J.; Stupp, S. I.; Thompson, M. E. Adv. Mater. 1998, 10, 1297- 1336.
3. For a very good overview of recent developments in crystal engineering see the following multiauthored volumes and review articles: (a) Crystal Engineering: From Molecules and Crystals To Materials; Braga, D., Orpen, A. G., Eds.; NATO ASI series; Kluwer: Dordecht, The Netherlands, 1999. (b) Weber, E., Ed. Design of Organic Solids; Topics in Current Chemistry; Springer-Verlag, Heidelberg, 1998; Vol. 198. (c) Comprehensive Supramolecular Chemistry: Atwood, J. L., Davies, J. E. D., MacNicol, D. D., Vogtle, F., Lehn, J.-M., Eds.; Pergamon: Oxford, 1996; Vol. 6. (d) Desiraju, G. R. Angew. Chem., Int. Ed. Engl. 1995, 34, 2311-2327. (e) Aakeroy, C. B. Acta Crystallogr. 1997, B53, 569-583. (f) Braga, D.; Grepioni, F.; Desiraju, G. R. Chem. Rev. 1998, 98, 1375-1405. (g) Bernstein, J.; Davis, R. E.; Shimoni, L.; Chang, N. Angew. Chem., Int. Ed. Engl. 1995, 34, 1555-1573. (h) MacDonald, J. C.; Whitesides, G. M. Chem. Rev. 1994, 94, 2383-2420. (i) Batten, S. R.; Robson, R. Angew. Chem., Int. Ed. Engl. 1998, 37, 1460-1494. (j) Zaworotko, M. J. Coordination Polymers. In Crystal Engineering: The Design and Applications of Functional Solids; Seddon, K. R., Zaworotko, M. J., Eds.; NATO ASI series; Kluwer; Dordecht, The Netherlands, 1998. (k) Hagrman, P. J.; Hagrman, D.; Zubieta, J. Angew. Chem., Int. Ed. Engl. 1999, 38, 2639- 2684. (l) Alivisatos, A. P.; Barbara, P. F.; Castelman, A. W.; Chang, J.; Dixon, D. A.; Klein, M. L.; McLendon, G. L.; Miller, J. S.; Ratner, M. A.; Rossky, P. J.; Stupp, S. I.; Thompson, M. E. Adv. Mater. 1998, 10, 1297- 1336.
4. For a very good overview of recent developments in crystal engineering see the following multiauthored volumes and review articles: (a) Crystal Engineering: From Molecules and Crystals To Materials; Braga, D., Orpen, A. G., Eds.; NATO ASI series; Kluwer: Dordecht, The Netherlands, 1999. (b) Weber, E., Ed. Design of Organic Solids; Topics in Current Chemistry; Springer-Verlag, Heidelberg, 1998; Vol. 198. (c) Comprehensive Supramolecular Chemistry: Atwood, J. L., Davies, J. E. D., MacNicol, D. D., Vogtle, F., Lehn, J.-M., Eds.; Pergamon: Oxford, 1996; Vol. 6. (d) Desiraju, G. R. Angew. Chem., Int. Ed. Engl. 1995, 34, 2311-2327. (e) Aakeroy, C. B. Acta Crystallogr. 1997, B53, 569-583. (f) Braga, D.; Grepioni, F.; Desiraju, G. R. Chem. Rev. 1998, 98, 1375-1405. (g) Bernstein, J.; Davis, R. E.; Shimoni, L.; Chang, N. Angew. Chem., Int. Ed. Engl. 1995, 34, 1555-1573. (h) MacDonald, J. C.; Whitesides, G. M. Chem. Rev. 1994, 94, 2383-2420. (i) Batten, S. R.; Robson, R. Angew. Chem., Int. Ed. Engl. 1998, 37, 1460-1494. (j) Zaworotko, M. J. Coordination Polymers. In Crystal Engineering: The Design and Applications of Functional Solids; Seddon, K. R., Zaworotko, M. J., Eds.; NATO ASI series; Kluwer; Dordecht, The Netherlands, 1998. (k) Hagrman, P. J.; Hagrman, D.; Zubieta, J. Angew. Chem., Int. Ed. Engl. 1999, 38, 2639- 2684. (l) Alivisatos, A. P.; Barbara, P. F.; Castelman, A. W.; Chang, J.; Dixon, D. A.; Klein, M. L.; McLendon, G. L.; Miller, J. S.; Ratner, M. A.; Rossky, P. J.; Stupp, S. I.; Thompson, M. E. Adv. Mater. 1998, 10, 1297- 1336.
5. For a very good overview of recent developments in crystal engineering see the following multiauthored volumes and review articles: (a) Crystal Engineering: From Molecules and Crystals To Materials; Braga, D., Orpen, A. G., Eds.; NATO ASI series; Kluwer: Dordecht, The Netherlands, 1999. (b) Weber, E., Ed. Design of Organic Solids; Topics in Current Chemistry; Springer-Verlag, Heidelberg, 1998; Vol. 198. (c) Comprehensive Supramolecular Chemistry: Atwood, J. L., Davies, J. E. D., MacNicol, D. D., Vogtle, F., Lehn, J.-M., Eds.; Pergamon: Oxford, 1996; Vol. 6. (d) Desiraju, G. R. Angew. Chem., Int. Ed. Engl. 1995, 34, 2311-2327. (e) Aakeroy, C. B. Acta Crystallogr. 1997, B53, 569-583. (f) Braga, D.; Grepioni, F.; Desiraju, G. R. Chem. Rev. 1998, 98, 1375-1405. (g) Bernstein, J.; Davis, R. E.; Shimoni, L.; Chang, N. Angew. Chem., Int. Ed. Engl. 1995, 34, 1555-1573. (h) MacDonald, J. C.; Whitesides, G. M. Chem. Rev. 1994, 94, 2383-2420. (i) Batten, S. R.; Robson, R. Angew. Chem., Int. Ed. Engl. 1998, 37, 1460-1494. (j) Zaworotko, M. J. Coordination Polymers. In Crystal Engineering: The Design and Applications of Functional Solids; Seddon, K. R., Zaworotko, M. J., Eds.; NATO ASI series; Kluwer; Dordecht, The Netherlands, 1998. (k) Hagrman, P. J.; Hagrman, D.; Zubieta, J. Angew. Chem., Int. Ed. Engl. 1999, 38, 2639- 2684. (l) Alivisatos, A. P.; Barbara, P. F.; Castelman, A. W.; Chang, J.; Dixon, D. A.; Klein, M. L.; McLendon, G. L.; Miller, J. S.; Ratner, M. A.; Rossky, P. J.; Stupp, S. I.; Thompson, M. E. Adv. Mater. 1998, 10, 1297- 1336.
6. For a very good overview of recent developments in crystal engineering see the following multiauthored volumes and review articles: (a) Crystal Engineering: From Molecules and Crystals To Materials; Braga, D., Orpen, A. G., Eds.; NATO ASI series; Kluwer: Dordecht, The Netherlands, 1999. (b) Weber, E., Ed. Design of Organic Solids; Topics in Current Chemistry; Springer-Verlag, Heidelberg, 1998; Vol. 198. (c) Comprehensive Supramolecular Chemistry: Atwood, J. L., Davies, J. E. D., MacNicol, D. D., Vogtle, F., Lehn, J.-M., Eds.; Pergamon: Oxford, 1996; Vol. 6. (d) Desiraju, G. R. Angew. Chem., Int. Ed. Engl. 1995, 34, 2311-2327. (e) Aakeroy, C. B. Acta Crystallogr. 1997, B53, 569-583. (f) Braga, D.; Grepioni, F.; Desiraju, G. R. Chem. Rev. 1998, 98, 1375-1405. (g) Bernstein, J.; Davis, R. E.; Shimoni, L.; Chang, N. Angew. Chem., Int. Ed. Engl. 1995, 34, 1555-1573. (h) MacDonald, J. C.; Whitesides, G. M. Chem. Rev. 1994, 94, 2383-2420. (i) Batten, S. R.; Robson, R. Angew. Chem., Int. Ed. Engl. 1998, 37, 1460-1494. (j) Zaworotko, M. J. Coordination Polymers. In Crystal Engineering: The Design and Applications of Functional Solids; Seddon, K. R., Zaworotko, M. J., Eds.; NATO ASI series; Kluwer; Dordecht, The Netherlands, 1998. (k) Hagrman, P. J.; Hagrman, D.; Zubieta, J. Angew. Chem., Int. Ed. Engl. 1999, 38, 2639- 2684. (l) Alivisatos, A. P.; Barbara, P. F.; Castelman, A. W.; Chang, J.; Dixon, D. A.; Klein, M. L.; McLendon, G. L.; Miller, J. S.; Ratner, M. A.; Rossky, P. J.; Stupp, S. I.; Thompson, M. E. Adv. Mater. 1998, 10, 1297- 1336.
7. For a very good overview of recent developments in crystal engineering see the following multiauthored volumes and review articles: (a) Crystal Engineering: From Molecules and Crystals To Materials; Braga, D., Orpen, A. G., Eds.; NATO ASI series; Kluwer: Dordecht, The Netherlands, 1999. (b) Weber, E., Ed. Design of Organic Solids; Topics in Current Chemistry; Springer-Verlag, Heidelberg, 1998; Vol. 198. (c) Comprehensive Supramolecular Chemistry: Atwood, J. L., Davies, J. E. D., MacNicol, D. D., Vogtle, F., Lehn, J.-M., Eds.; Pergamon: Oxford, 1996; Vol. 6. (d) Desiraju, G. R. Angew. Chem., Int. Ed. Engl. 1995, 34, 2311-2327. (e) Aakeroy, C. B. Acta Crystallogr. 1997, B53, 569-583. (f) Braga, D.; Grepioni, F.; Desiraju, G. R. Chem. Rev. 1998, 98, 1375-1405. (g) Bernstein, J.; Davis, R. E.; Shimoni, L.; Chang, N. Angew. Chem., Int. Ed. Engl. 1995, 34, 1555-1573. (h) MacDonald, J. C.; Whitesides, G. M. Chem. Rev. 1994, 94, 2383-2420. (i) Batten, S. R.; Robson, R. Angew. Chem., Int. Ed. Engl. 1998, 37, 1460-1494. (j) Zaworotko, M. J. Coordination Polymers. In Crystal Engineering: The Design and Applications of Functional Solids; Seddon, K. R., Zaworotko, M. J., Eds.; NATO ASI series; Kluwer; Dordecht, The Netherlands, 1998. (k) Hagrman, P. J.; Hagrman, D.; Zubieta, J. Angew. Chem., Int. Ed. Engl. 1999, 38, 2639- 2684. (l) Alivisatos, A. P.; Barbara, P. F.; Castelman, A. W.; Chang, J.; Dixon, D. A.; Klein, M. L.; McLendon, G. L.; Miller, J. S.; Ratner, M. A.; Rossky, P. J.; Stupp, S. I.; Thompson, M. E. Adv. Mater. 1998, 10, 1297- 1336.
8. For a very good overview of recent developments in crystal engineering see the following multiauthored volumes and review articles: (a) Crystal Engineering: From Molecules and Crystals To Materials; Braga, D., Orpen, A. G., Eds.; NATO ASI series; Kluwer: Dordecht, The Netherlands, 1999. (b) Weber, E., Ed. Design of Organic Solids; Topics in Current Chemistry; Springer-Verlag, Heidelberg, 1998; Vol. 198. (c) Comprehensive Supramolecular Chemistry: Atwood, J. L., Davies, J. E. D., MacNicol, D. D., Vogtle, F., Lehn, J.-M., Eds.; Pergamon: Oxford, 1996; Vol. 6. (d) Desiraju, G. R. Angew. Chem., Int. Ed. Engl. 1995, 34, 2311-2327. (e) Aakeroy, C. B. Acta Crystallogr. 1997, B53, 569-583. (f) Braga, D.; Grepioni, F.; Desiraju, G. R. Chem. Rev. 1998, 98, 1375-1405. (g) Bernstein, J.; Davis, R. E.; Shimoni, L.; Chang, N. Angew. Chem., Int. Ed. Engl. 1995, 34, 1555-1573. (h) MacDonald, J. C.; Whitesides, G. M. Chem. Rev. 1994, 94, 2383-2420. (i) Batten, S. R.; Robson, R. Angew. Chem., Int. Ed. Engl. 1998, 37, 1460-1494. (j) Zaworotko, M. J. Coordination Polymers. In Crystal Engineering: The Design and Applications of Functional Solids; Seddon, K. R., Zaworotko, M. J., Eds.; NATO ASI series; Kluwer; Dordecht, The Netherlands, 1998. (k) Hagrman, P. J.; Hagrman, D.; Zubieta, J. Angew. Chem., Int. Ed. Engl. 1999, 38, 2639- 2684. (l) Alivisatos, A. P.; Barbara, P. F.; Castelman, A. W.; Chang, J.; Dixon, D. A.; Klein, M. L.; McLendon, G. L.; Miller, J. S.; Ratner, M. A.; Rossky, P. J.; Stupp, S. I.; Thompson, M. E. Adv. Mater. 1998, 10, 1297- 1336.
9. For a very good overview of recent developments in crystal engineering see the following multiauthored volumes and review articles: (a) Crystal Engineering: From Molecules and Crystals To Materials; Braga, D., Orpen, A. G., Eds.; NATO ASI series; Kluwer: Dordecht, The Netherlands, 1999. (b) Weber, E., Ed. Design of Organic Solids; Topics in Current Chemistry; Springer-Verlag, Heidelberg, 1998; Vol. 198. (c) Comprehensive Supramolecular Chemistry: Atwood, J. L., Davies, J. E. D., MacNicol, D. D., Vogtle, F., Lehn, J.-M., Eds.; Pergamon: Oxford, 1996; Vol. 6. (d) Desiraju, G. R. Angew. Chem., Int. Ed. Engl. 1995, 34, 2311-2327. (e) Aakeroy, C. B. Acta Crystallogr. 1997, B53, 569-583. (f) Braga, D.; Grepioni, F.; Desiraju, G. R. Chem. Rev. 1998, 98, 1375-1405. (g) Bernstein, J.; Davis, R. E.; Shimoni, L.; Chang, N. Angew. Chem., Int. Ed. Engl. 1995, 34, 1555-1573. (h) MacDonald, J. C.; Whitesides, G. M. Chem. Rev. 1994, 94, 2383-2420. (i) Batten, S. R.; Robson, R. Angew. Chem., Int. Ed. Engl. 1998, 37, 1460-1494. (j) Zaworotko, M. J. Coordination Polymers. In Crystal Engineering: The Design and Applications of Functional Solids; Seddon, K. R., Zaworotko, M. J., Eds.; NATO ASI series; Kluwer; Dordecht, The Netherlands, 1998. (k) Hagrman, P. J.; Hagrman, D.; Zubieta, J. Angew. Chem., Int. Ed. Engl. 1999, 38, 2639- 2684. (l) Alivisatos, A. P.; Barbara, P. F.; Castelman, A. W.; Chang, J.; Dixon, D. A.; Klein, M. L.; McLendon, G. L.; Miller, J. S.; Ratner, M. A.; Rossky, P. J.; Stupp, S. I.; Thompson, M. E. Adv. Mater. 1998, 10, 1297- 1336.
10. For a very good overview of recent developments in crystal engineering see the following multiauthored volumes and review articles: (a) Crystal Engineering: From Molecules and Crystals To Materials; Braga, D., Orpen, A. G., Eds.; NATO ASI series; Kluwer: Dordecht, The Netherlands, 1999. (b) Weber, E., Ed. Design of Organic Solids; Topics in Current Chemistry; Springer-Verlag, Heidelberg, 1998; Vol. 198. (c) Comprehensive Supramolecular Chemistry: Atwood, J. L., Davies, J. E. D., MacNicol, D. D., Vogtle, F., Lehn, J.-M., Eds.; Pergamon: Oxford, 1996; Vol. 6. (d) Desiraju, G. R. Angew. Chem., Int. Ed. Engl. 1995, 34, 2311-2327. (e) Aakeroy, C. B. Acta Crystallogr. 1997, B53, 569-583. (f) Braga, D.; Grepioni, F.; Desiraju, G. R. Chem. Rev. 1998, 98, 1375-1405. (g) Bernstein, J.; Davis, R. E.; Shimoni, L.; Chang, N. Angew. Chem., Int. Ed. Engl. 1995, 34, 1555-1573. (h) MacDonald, J. C.; Whitesides, G. M. Chem. Rev. 1994, 94, 2383-2420. (i) Batten, S. R.; Robson, R. Angew. Chem., Int. Ed. Engl. 1998, 37, 1460-1494. (j) Zaworotko, M. J. Coordination Polymers. In Crystal Engineering: The Design and Applications of Functional Solids; Seddon, K. R., Zaworotko, M. J., Eds.; NATO ASI series; Kluwer; Dordecht, The Netherlands, 1998. (k) Hagrman, P. J.; Hagrman, D.; Zubieta, J. Angew. Chem., Int. Ed. Engl. 1999, 38, 2639- 2684. (l) Alivisatos, A. P.; Barbara, P. F.; Castelman, A. W.; Chang, J.; Dixon, D. A.; Klein, M. L.; McLendon, G. L.; Miller, J. S.; Ratner, M. A.; Rossky, P. J.; Stupp, S. I.; Thompson, M. E. Adv. Mater. 1998, 10, 1297- 1336.
11. For a very good overview of recent developments in crystal engineering see the following multiauthored volumes and review articles: (a) Crystal Engineering: From Molecules and Crystals To Materials; Braga, D., Orpen, A. G., Eds.; NATO ASI series; Kluwer: Dordecht, The Netherlands, 1999. (b) Weber, E., Ed. Design of Organic Solids; Topics in Current Chemistry; Springer-Verlag, Heidelberg, 1998; Vol. 198. (c) Comprehensive Supramolecular Chemistry: Atwood, J. L., Davies, J. E. D., MacNicol, D. D., Vogtle, F., Lehn, J.-M., Eds.; Pergamon: Oxford, 1996; Vol. 6. (d) Desiraju, G. R. Angew. Chem., Int. Ed. Engl. 1995, 34, 2311-2327. (e) Aakeroy, C. B. Acta Crystallogr. 1997, B53, 569-583. (f) Braga, D.; Grepioni, F.; Desiraju, G. R. Chem. Rev. 1998, 98, 1375-1405. (g) Bernstein, J.; Davis, R. E.; Shimoni, L.; Chang, N. Angew. Chem., Int. Ed. Engl. 1995, 34, 1555-1573. (h) MacDonald, J. C.; Whitesides, G. M. Chem. Rev. 1994, 94, 2383-2420. (i) Batten, S. R.; Robson, R. Angew. Chem., Int. Ed. Engl. 1998, 37, 1460-1494. (j) Zaworotko, M. J. Coordination Polymers. In Crystal Engineering: The Design and Applications of Functional Solids; Seddon, K. R., Zaworotko, M. J., Eds.; NATO ASI series; Kluwer; Dordecht, The Netherlands, 1998. (k) Hagrman, P. J.; Hagrman, D.; Zubieta, J. Angew. Chem., Int. Ed. Engl. 1999, 38, 2639-2684. (l) Alivisatos, A. P.; Barbara, P. F.; Castelman, A. W.; Chang, J.; Dixon, D. A.; Klein, M. L.; McLendon, G. L.; Miller, J. S.; Ratner, M. A.; Rossky, P. J.; Stupp, S. I.; Thompson, M. E. Adv. Mater. 1998, 10, 1297- 1336.
12. For a very good overview of recent developments in crystal engineering see the following multiauthored volumes and review articles: (a) Crystal Engineering: From Molecules and Crystals To Materials; Braga, D., Orpen, A. G., Eds.; NATO ASI series; Kluwer: Dordecht, The Netherlands, 1999. (b) Weber, E., Ed. Design of Organic Solids; Topics in Current Chemistry; Springer-Verlag, Heidelberg, 1998; Vol. 198. (c) Comprehensive Supramolecular Chemistry: Atwood, J. L., Davies, J. E. D., MacNicol, D. D., Vogtle, F., Lehn, J.-M., Eds.; Pergamon: Oxford, 1996; Vol. 6. (d) Desiraju, G. R. Angew. Chem., Int. Ed. Engl. 1995, 34, 2311-2327. (e) Aakeroy, C. B. Acta Crystallogr. 1997, B53, 569-583. (f) Braga, D.; Grepioni, F.; Desiraju, G. R. Chem. Rev. 1998, 98, 1375-1405. (g) Bernstein, J.; Davis, R. E.; Shimoni, L.; Chang, N. Angew. Chem., Int. Ed. Engl. 1995, 34, 1555-1573. (h) MacDonald, J. C.; Whitesides, G. M. Chem. Rev. 1994, 94, 2383-2420. (i) Batten, S. R.; Robson, R. Angew. Chem., Int. Ed. Engl. 1998, 37, 1460-1494. (j) Zaworotko, M. J. Coordination Polymers. In Crystal Engineering: The Design and Applications of Functional Solids; Seddon, K. R., Zaworotko, M. J., Eds.; NATO ASI series; Kluwer; Dordecht, The Netherlands, 1998. (k) Hagrman, P. J.; Hagrman, D.; Zubieta, J. Angew. Chem., Int. Ed. Engl. 1999, 38, 2639- 2684. (l) Alivisatos, A. P.; Barbara, P. F.; Castelman, A. W.; Chang, J.; Dixon, D. A.; Klein, M. L.; McLendon, G. L.; Miller, J. S.; Ratner, M. A.; Rossky, P. J.; Stupp, S. I.; Thompson, M. E. Adv. Mater. 1998, 10, 1297-1336.
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30. d symmetry and complementary intermolecular interactions. In this article, we tried to devise a new strategy of constructing generic 3D hexagonal open networks using a novel self-complementary molecular building block. However, see the following references and ref 6 for some very interesting 3D networks and open networks based on hydrogen bonding: (a) Brunet, P.; Simard, M.; Wuest, J. D. J. Am. Chem. Soc. 1997, 119, 2737-2738. (b) Bhyrappa, P.; Wilson, S. R.; Suslick, K. S. J. Am. Chem. Soc. 1997, 119, 8492-8502. (c) Ung, A. T.; Gizachew, D.; Bishop, R.; Scudder, M. L.; Dance, I. G.; Craig, D. C. J. Am. Chem. Soc. 1995, 117, 8745-8756. (d) Endo, K.; Sawaki, T.; Koyanagi, M.; Kobayashi, K.; Masuda, H.; Aoyama, Y. J. Am. Chem. Soc. 1995, 117, 8341-8352. (e) Martin, J. D.; Leafblad, B. Angew. Chem., Int. Ed. Engl. 1998, 37, 3318- 3320. (f) Aakeroy, C. B.; Beatty, A. M.; Leinen, D. S. Angew. Chem., Int. Ed. Engl. 1999, 38, 1815-1819. (g) Kumar, R. K.; Balasubramanian, S.; Goldberg, I. Chem. Commun. 1998, 1435-1436. (h) Kepert, C. J.; Hesek, D.; Beer, P. D.; Rosseinsky, M. J. Angew. Chem., Int. Ed. Engl. 1998, 37, 3158-3160. (i) Ranford, J. D.; Vittal, J. J.; Wu, D.; Yang, X. Angew. Chem., Int. Ed. Engl. 1999, 38, 3498-3501.
31. d symmetry and complementary intermolecular interactions. In this article, we tried to devise a new strategy of constructing generic 3D hexagonal open networks using a novel self-complementary molecular building block. However, see the following references and ref 6 for some very interesting 3D networks and open networks based on hydrogen bonding: (a) Brunet, P.; Simard, M.; Wuest, J. D. J. Am. Chem. Soc. 1997, 119, 2737-2738. (b) Bhyrappa, P.; Wilson, S. R.; Suslick, K. S. J. Am. Chem. Soc. 1997, 119, 8492-8502. (c) Ung, A. T.; Gizachew, D.; Bishop, R.; Scudder, M. L.; Dance, I. G.; Craig, D. C. J. Am. Chem. Soc. 1995, 117, 8745-8756. (d) Endo, K.; Sawaki, T.; Koyanagi, M.; Kobayashi, K.; Masuda, H.; Aoyama, Y. J. Am. Chem. Soc. 1995, 117, 8341-8352. (e) Martin, J. D.; Leafblad, B. Angew. Chem., Int. Ed. Engl. 1998, 37, 3318- 3320. (f) Aakeroy, C. B.; Beatty, A. M.; Leinen, D. S. Angew. Chem., Int. Ed. Engl. 1999, 38, 1815-1819. (g) Kumar, R. K.; Balasubramanian, S.; Goldberg, I. Chem. Commun. 1998, 1435-1436. (h) Kepert, C. J.; Hesek, D.; Beer, P. D.; Rosseinsky, M. J. Angew. Chem., Int. Ed. Engl. 1998, 37, 3158-3160. (i) Ranford, J. D.; Vittal, J. J.; Wu, D.; Yang, X. Angew. Chem., Int. Ed. Engl. 1999, 38, 3498-3501.
32. d symmetry and complementary intermolecular interactions. In this article, we tried to devise a new strategy of constructing generic 3D hexagonal open networks using a novel self-complementary molecular building block. However, see the following references and ref 6 for some very interesting 3D networks and open networks based on hydrogen bonding: (a) Brunet, P.; Simard, M.; Wuest, J. D. J. Am. Chem. Soc. 1997, 119, 2737-2738. (b) Bhyrappa, P.; Wilson, S. R.; Suslick, K. S. J. Am. Chem. Soc. 1997, 119, 8492-8502. (c) Ung, A. T.; Gizachew, D.; Bishop, R.; Scudder, M. L.; Dance, I. G.; Craig, D. C. J. Am. Chem. Soc. 1995, 117, 8745-8756. (d) Endo, K.; Sawaki, T.; Koyanagi, M.; Kobayashi, K.; Masuda, H.; Aoyama, Y. J. Am. Chem. Soc. 1995, 117, 8341-8352. (e) Martin, J. D.; Leafblad, B. Angew. Chem., Int. Ed. Engl. 1998, 37, 3318- 3320. (f) Aakeroy, C. B.; Beatty, A. M.; Leinen, D. S. Angew. Chem., Int. Ed. Engl. 1999, 38, 1815-1819. (g) Kumar, R. K.; Balasubramanian, S.; Goldberg, I. Chem. Commun. 1998, 1435-1436. (h) Kepert, C. J.; Hesek, D.; Beer, P. D.; Rosseinsky, M. J. Angew. Chem., Int. Ed. Engl. 1998, 37, 3158-3160. (i) Ranford, J. D.; Vittal, J. J.; Wu, D.; Yang, X. Angew. Chem., Int. Ed. Engl. 1999, 38, 3498-3501.
33. d symmetry and complementary intermolecular interactions. In this article, we tried to devise a new strategy of constructing generic 3D hexagonal open networks using a novel self-complementary molecular building block. However, see the following references and ref 6 for some very interesting 3D networks and open networks based on hydrogen bonding: (a) Brunet, P.; Simard, M.; Wuest, J. D. J. Am. Chem. Soc. 1997, 119, 2737-2738. (b) Bhyrappa, P.; Wilson, S. R.; Suslick, K. S. J. Am. Chem. Soc. 1997, 119, 8492-8502. (c) Ung, A. T.; Gizachew, D.; Bishop, R.; Scudder, M. L.; Dance, I. G.; Craig, D. C. J. Am. Chem. Soc. 1995, 117, 8745-8756. (d) Endo, K.; Sawaki, T.; Koyanagi, M.; Kobayashi, K.; Masuda, H.; Aoyama, Y. J. Am. Chem. Soc. 1995, 117, 8341-8352. (e) Martin, J. D.; Leafblad, B. Angew. Chem., Int. Ed. Engl. 1998, 37, 3318- 3320. (f) Aakeroy, C. B.; Beatty, A. M.; Leinen, D. S. Angew. Chem., Int. Ed. Engl. 1999, 38, 1815-1819. (g) Kumar, R. K.; Balasubramanian, S.; Goldberg, I. Chem. Commun. 1998, 1435-1436. (h) Kepert, C. J.; Hesek, D.; Beer, P. D.; Rosseinsky, M. J. Angew. Chem., Int. Ed. Engl. 1998, 37, 3158-3160. (i) Ranford, J. D.; Vittal, J. J.; Wu, D.; Yang, X. Angew. Chem., Int. Ed. Engl. 1999, 38, 3498-3501.
34. d symmetry and complementary intermolecular interactions. In this article, we tried to devise a new strategy of constructing generic 3D hexagonal open networks using a novel self-complementary molecular building block. However, see the following references and ref 6 for some very interesting 3D networks and open networks based on hydrogen bonding: (a) Brunet, P.; Simard, M.; Wuest, J. D. J. Am. Chem. Soc. 1997, 119, 2737-2738. (b) Bhyrappa, P.; Wilson, S. R.; Suslick, K. S. J. Am. Chem. Soc. 1997, 119, 8492-8502. (c) Ung, A. T.; Gizachew, D.; Bishop, R.; Scudder, M. L.; Dance, I. G.; Craig, D. C. J. Am. Chem. Soc. 1995, 117, 8745-8756. (d) Endo, K.; Sawaki, T.; Koyanagi, M.; Kobayashi, K.; Masuda, H.; Aoyama, Y. J. Am. Chem. Soc. 1995, 117, 8341-8352. (e) Martin, J. D.; Leafblad, B. Angew. Chem., Int. Ed. Engl. 1998, 37, 3318-3320. (f) Aakeroy, C. B.; Beatty, A. M.; Leinen, D. S. Angew. Chem., Int. Ed. Engl. 1999, 38, 1815-1819. (g) Kumar, R. K.; Balasubramanian, S.; Goldberg, I. Chem. Commun. 1998, 1435-1436. (h) Kepert, C. J.; Hesek, D.; Beer, P. D.; Rosseinsky, M. J. Angew. Chem., Int. Ed. Engl. 1998, 37, 3158-3160. (i) Ranford, J. D.; Vittal, J. J.; Wu, D.; Yang, X. Angew. Chem., Int. Ed. Engl. 1999, 38, 3498-3501.
35. d symmetry and complementary intermolecular interactions. In this article, we tried to devise a new strategy of constructing generic 3D hexagonal open networks using a novel self-complementary molecular building block. However, see the following references and ref 6 for some very interesting 3D networks and open networks based on hydrogen bonding: (a) Brunet, P.; Simard, M.; Wuest, J. D. J. Am. Chem. Soc. 1997, 119, 2737-2738. (b) Bhyrappa, P.; Wilson, S. R.; Suslick, K. S. J. Am. Chem. Soc. 1997, 119, 8492-8502. (c) Ung, A. T.; Gizachew, D.; Bishop, R.; Scudder, M. L.; Dance, I. G.; Craig, D. C. J. Am. Chem. Soc. 1995, 117, 8745-8756. (d) Endo, K.; Sawaki, T.; Koyanagi, M.; Kobayashi, K.; Masuda, H.; Aoyama, Y. J. Am. Chem. Soc. 1995, 117, 8341-8352. (e) Martin, J. D.; Leafblad, B. Angew. Chem., Int. Ed. Engl. 1998, 37, 3318- 3320. (f) Aakeroy, C. B.; Beatty, A. M.; Leinen, D. S. Angew. Chem., Int. Ed. Engl. 1999, 38, 1815-1819. (g) Kumar, R. K.; Balasubramanian, S.; Goldberg, I. Chem. Commun. 1998, 1435-1436. (h) Kepert, C. J.; Hesek, D.; Beer, P. D.; Rosseinsky, M. J. Angew. Chem., Int. Ed. Engl. 1998, 37, 3158-3160. (i) Ranford, J. D.; Vittal, J. J.; Wu, D.; Yang, X. Angew. Chem., Int. Ed. Engl. 1999, 38, 3498-3501.
36. d symmetry and complementary intermolecular interactions. In this article, we tried to devise a new strategy of constructing generic 3D hexagonal open networks using a novel self-complementary molecular building block. However, see the following references and ref 6 for some very interesting 3D networks and open networks based on hydrogen bonding: (a) Brunet, P.; Simard, M.; Wuest, J. D. J. Am. Chem. Soc. 1997, 119, 2737-2738. (b) Bhyrappa, P.; Wilson, S. R.; Suslick, K. S. J. Am. Chem. Soc. 1997, 119, 8492-8502. (c) Ung, A. T.; Gizachew, D.; Bishop, R.; Scudder, M. L.; Dance, I. G.; Craig, D. C. J. Am. Chem. Soc. 1995, 117, 8745-8756. (d) Endo, K.; Sawaki, T.; Koyanagi, M.; Kobayashi, K.; Masuda, H.; Aoyama, Y. J. Am. Chem. Soc. 1995, 117, 8341-8352. (e) Martin, J. D.; Leafblad, B. Angew. Chem., Int. Ed. Engl. 1998, 37, 3318- 3320. (f) Aakeroy, C. B.; Beatty, A. M.; Leinen, D. S. Angew. Chem., Int. Ed. Engl. 1999, 38, 1815-1819. (g) Kumar, R. K.; Balasubramanian, S.; Goldberg, I. Chem. Commun. 1998, 1435-1436. (h) Kepert, C. J.; Hesek, D.; Beer, P. D.; Rosseinsky, M. J. Angew. Chem., Int. Ed. Engl. 1998, 37, 3158-3160. (i) Ranford, J. D.; Vittal, J. J.; Wu, D.; Yang, X. Angew. Chem., Int. Ed. Engl. 1999, 38, 3498-3501.
37. d symmetry and complementary intermolecular interactions. In this article, we tried to devise a new strategy of constructing generic 3D hexagonal open networks using a novel self-complementary molecular building block. However, see the following references and ref 6 for some very interesting 3D networks and open networks based on hydrogen bonding: (a) Brunet, P.; Simard, M.; Wuest, J. D. J. Am. Chem. Soc. 1997, 119, 2737-2738. (b) Bhyrappa, P.; Wilson, S. R.; Suslick, K. S. J. Am. Chem. Soc. 1997, 119, 8492-8502. (c) Ung, A. T.; Gizachew, D.; Bishop, R.; Scudder, M. L.; Dance, I. G.; Craig, D. C. J. Am. Chem. Soc. 1995, 117, 8745-8756. (d) Endo, K.; Sawaki, T.; Koyanagi, M.; Kobayashi, K.; Masuda, H.; Aoyama, Y. J. Am. Chem. Soc. 1995, 117, 8341-8352. (e) Martin, J. D.; Leafblad, B. Angew. Chem., Int. Ed. Engl. 1998, 37, 3318- 3320. (f) Aakeroy, C. B.; Beatty, A. M.; Leinen, D. S. Angew. Chem., Int. Ed. Engl. 1999, 38, 1815-1819. (g) Kumar, R. K.; Balasubramanian, S.; Goldberg, I. Chem. Commun. 1998, 1435-1436. (h) Kepert, C. J.; Hesek, D.; Beer, P. D.; Rosseinsky, M. J. Angew. Chem., Int. Ed. Engl. 1998, 37, 3158-3160. (i) Ranford, J. D.; Vittal, J. J.; Wu, D.; Yang, X. Angew. Chem., Int. Ed. Engl. 1999, 38, 3498-3501.
38. d symmetry and complementary intermolecular interactions. In this article, we tried to devise a new strategy of constructing generic 3D hexagonal open networks using a novel self-complementary molecular building block. However, see the following references and ref 6 for some very interesting 3D networks and open networks based on hydrogen bonding: (a) Brunet, P.; Simard, M.; Wuest, J. D. J. Am. Chem. Soc. 1997, 119, 2737-2738. (b) Bhyrappa, P.; Wilson, S. R.; Suslick, K. S. J. Am. Chem. Soc. 1997, 119, 8492-8502. (c) Ung, A. T.; Gizachew, D.; Bishop, R.; Scudder, M. L.; Dance, I. G.; Craig, D. C. J. Am. Chem. Soc. 1995, 117, 8745-8756. (d) Endo, K.; Sawaki, T.; Koyanagi, M.; Kobayashi, K.; Masuda, H.; Aoyama, Y. J. Am. Chem. Soc. 1995, 117, 8341-8352. (e) Martin, J. D.; Leafblad, B. Angew. Chem., Int. Ed. Engl. 1998, 37, 3318- 3320. (f) Aakeroy, C. B.; Beatty, A. M.; Leinen, D. S. Angew. Chem., Int. Ed. Engl. 1999, 38, 1815-1819. (g) Kumar, R. K.; Balasubramanian, S.; Goldberg, I. Chem. Commun. 1998, 1435-1436. (h) Kepert, C. J.; Hesek, D.; Beer, P. D.; Rosseinsky, M. J. Angew. Chem., Int. Ed. Engl. 1998, 37, 3158-3160. (i) Ranford, J. D.; Vittal, J. J.; Wu, D.; Yang, X. Angew. Chem., Int. Ed. Engl. 1999, 38, 3498-3501.
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