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0343754415
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note
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The synthesis of 4 will be published elsewhere.
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37
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0031698504
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Assuming a cylindrical shape of the OPV dendrimers at the air -water interface, a degree of flatting of the poly(propylene imine) core can be calculated from the molecular area by considering the transversal section of the dendrimer part to be a circle (see also ref 3). Radii of 10.2, 19.9, and 41.8 Å for G1, G3, and G5, respectively, were calculated indicating a high degree of flatting of the dendritic core at the air/water interface: Scherrenberg, R.; Coussens, B.; van Vliet, P.; Edourd, G.; Brackman, J.; de Brabander, E. M. M.; Mortensen, K. Macromolecules 1998, 31, 456.
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38
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0342883629
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note
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No dye could be extracted from the water layer when no OPV dendrimer was present in the chloroform layer.
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39
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