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Volumn 6, Issue 3, 2000, Pages 523-536

ZrIV-tetraphenylporphyrinates as nuclease mimics: Structural, kinetic and mechanistic studies on phosphate diester transesterification

Author keywords

Bioinorganic chemistry; Catalysts; Phospatases; Porphyrinoids; Zirconium

Indexed keywords

ORGANOPHOSPHATE; PORPHYRIN DERIVATIVE; UNCLASSIFIED DRUG; ZIRCONIUM; ZIRCONIUM TETRAPHENYLPORPHYRIN;

EID: 0034603066     PISSN: 09476539     EISSN: None     Source Type: Journal    
DOI: None     Document Type: Article
Times cited : (4)

References (106)
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    • note
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    • d = 0.5(1) mM.
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    • -] the first order background rate constants were extrapolated to the conditions used in the catalysed reactions.
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    • 1/[4].
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    • -1 without correction for the different solvents.
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    • note
    • 2 (4) reacts rapidly with water to produce hydroxocomplexes with liberation of two equivalents of HCl, which serve as an additional source of protons together with H-2 (predominantly being in the dissociated form).


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.