Metal-mediated transfer of electrons between two different C-C single bonds that function as electron-donor and electron-acceptor units

Angewandte Chemie - International Edition

Volumn 39, Issue 9, 2000, Pages 1685-1687

  Franceschi, Federico ^a   Solari, Euro ^a   Scopelliti, Rosario ^a   Floriani, Carlo ^a  

^a UNIVERSITY OF LAUSANNE   (Switzerland)

Author keywords

C C activation; C C cleavage; Electron transfer; Energy storage; Molecular batteries

Indexed keywords

METAL ION; NICKEL; PORPHYRINOGEN;

ARTICLE; CHEMICAL BOND; CHEMICAL REACTION; CHEMICAL STRUCTURE; ELECTRON TRANSPORT; MOLECULAR INTERACTION; OXIDATION REDUCTION REACTION;

EID: 0034595319     PISSN: 14337851     EISSN: None     Source Type: Journal    
DOI: 10.1002/(SICI)1521-3773(20000502)39:9<1685::AID-ANIE1685>3.0.CO;2-Q     Document Type: Article

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33. For experimental details see Supporting Information.
34. [4, b]
35. Kα) = (1.855 mm 1; crystal dimensions 0.20 × 0.14 × 0.10. For 13108 observed reflections (1>2σ(I)) and 1227 parameters, the conventional R is 0.0926 (wR2 = 0.1572 for 15798 independent reflections). Crystallographic data (excluding structure factors) for the structure reported in this paper have been deposited with the Cambridge Crystallographic Data Centre as supplementary publication no. CCDC-137426. Copies of the data can be obtained free of charge on application to CCDC, 12 Union Road, Cambridge CB21EZ, UK (fax: (+44)1223-336-033; e-mail: deposit@ccdc.cam.ac.uk).