Transition metal complexes as bifunctional carriers of polar organometallics: Their application to large molecule modifications and to hydrocarbon activation

Pure and Applied Chemistry

Volumn 68, Issue 1, 1996, Pages 1-8

  Floriani, Carlo ^a  

^a UNIVERSITY OF LAUSANNE   (Switzerland)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0001912668     PISSN: 00334545     EISSN: None     Source Type: Journal    
DOI: 10.1351/pac199668010001     Document Type: Article

References (77)

1. B. H. Lipshutz and S. Sengupta In Organic Reactions, L. A. Paquette, Ed.; Vol. 41, Chapter 2, Wiley, New York (1992). B. H. Lipshutz In Organometallics in Synthesis, a Manual, M. Schlosser, Ed.; Chapter 4, Wiley, New York (1994).
2. B. H. Lipshutz and S. Sengupta In Organic Reactions, L. A. Paquette, Ed.; Vol. 41, Chapter 2, Wiley, New York (1992). B. H. Lipshutz In Organometallics in Synthesis, a Manual, M. Schlosser, Ed.; Chapter 4, Wiley, New York (1994).
3. M. T. Reetz In Organotitanium Reagents in Organic Synthesis, Springer, Berlin, Germany (1986). M. T. Reetz, R. Steinbach, J. Westermann, R. Peter and B. Wenderoth, Chem. Ber. 118, 1441 (1985). M. T. Reetz and B. Wenderoth, Tetrahedron Lett. 23, 5259 (1982). R. J. Morris and G. S. Girolami, Organometallics 10, 792 (1991). R. W. Quan, G. C. Bazan, A. F. Kiely, W. P. Schaefer and J. E. Bercaw, J. Am. Chem. Soc. 116, 4489 (1994).
4. M. T. Reetz In Organotitanium Reagents in Organic Synthesis, Springer, Berlin, Germany (1986). M. T. Reetz, R. Steinbach, J. Westermann, R. Peter and B. Wenderoth, Chem. Ber. 118, 1441 (1985). M. T. Reetz and B. Wenderoth, Tetrahedron Lett. 23, 5259 (1982). R. J. Morris and G. S. Girolami, Organometallics 10, 792 (1991). R. W. Quan, G. C. Bazan, A. F. Kiely, W. P. Schaefer and J. E. Bercaw, J. Am. Chem. Soc. 116, 4489 (1994).
5. M. T. Reetz In Organotitanium Reagents in Organic Synthesis, Springer, Berlin, Germany (1986). M. T. Reetz, R. Steinbach, J. Westermann, R. Peter and B. Wenderoth, Chem. Ber. 118, 1441 (1985). M. T. Reetz and B. Wenderoth, Tetrahedron Lett. 23, 5259 (1982). R. J. Morris and G. S. Girolami, Organometallics 10, 792 (1991). R. W. Quan, G. C. Bazan, A. F. Kiely, W. P. Schaefer and J. E. Bercaw, J. Am. Chem. Soc. 116, 4489 (1994).
6. M. T. Reetz In Organotitanium Reagents in Organic Synthesis, Springer, Berlin, Germany (1986). M. T. Reetz, R. Steinbach, J. Westermann, R. Peter and B. Wenderoth, Chem. Ber. 118, 1441 (1985). M. T. Reetz and B. Wenderoth, Tetrahedron Lett. 23, 5259 (1982). R. J. Morris and G. S. Girolami, Organometallics 10, 792 (1991). R. W. Quan, G. C. Bazan, A. F. Kiely, W. P. Schaefer and J. E. Bercaw, J. Am. Chem. Soc. 116, 4489 (1994).
7. M. T. Reetz In Organotitanium Reagents in Organic Synthesis, Springer, Berlin, Germany (1986). M. T. Reetz, R. Steinbach, J. Westermann, R. Peter and B. Wenderoth, Chem. Ber. 118, 1441 (1985). M. T. Reetz and B. Wenderoth, Tetrahedron Lett. 23, 5259 (1982). R. J. Morris and G. S. Girolami, Organometallics 10, 792 (1991). R. W. Quan, G. C. Bazan, A. F. Kiely, W. P. Schaefer and J. E. Bercaw, J. Am. Chem. Soc. 116, 4489 (1994).
8. H. Fischer and H. Orth, Die Chemie des Pyrrols, p 20, Akademische Verlagsgesellschaft, Leipzig (1934). M. Dennstedt and J. Zimmermann, Chem. Ber. 20, 850 and 2449 (1887); 21, 1478 (1888). D. Dennstedt, Chem. Ber. 23, 1370 (1890). V. V. Chelintzev and B. V. Tronov, J. Russ. Phys. Chem. Soc. 48, 105 and 127 (1916). Th. Sabalitschka and H. Haase, Arch. Pharm. 226, 484 (1928). P. Rothemund and C. L. Gage, J. Am. Chem. Soc. 77, 3340 (1955).
9. H. Fischer and H. Orth, Die Chemie des Pyrrols, p 20, Akademische Verlagsgesellschaft, Leipzig (1934). M. Dennstedt and J. Zimmermann, Chem. Ber. 20, 850 and 2449 (1887); 21, 1478 (1888). D. Dennstedt, Chem. Ber. 23, 1370 (1890). V. V. Chelintzev and B. V. Tronov, J. Russ. Phys. Chem. Soc. 48, 105 and 127 (1916). Th. Sabalitschka and H. Haase, Arch. Pharm. 226, 484 (1928). P. Rothemund and C. L. Gage, J. Am. Chem. Soc. 77, 3340 (1955).
10. H. Fischer and H. Orth, Die Chemie des Pyrrols, p 20, Akademische Verlagsgesellschaft, Leipzig (1934). M. Dennstedt and J. Zimmermann, Chem. Ber. 20, 850 and 2449 (1887); 21, 1478 (1888). D. Dennstedt, Chem. Ber. 23, 1370 (1890). V. V. Chelintzev and B. V. Tronov, J. Russ. Phys. Chem. Soc. 48, 105 and 127 (1916). Th. Sabalitschka and H. Haase, Arch. Pharm. 226, 484 (1928). P. Rothemund and C. L. Gage, J. Am. Chem. Soc. 77, 3340 (1955).
11. H. Fischer and H. Orth, Die Chemie des Pyrrols, p 20, Akademische Verlagsgesellschaft, Leipzig (1934). M. Dennstedt and J. Zimmermann, Chem. Ber. 20, 850 and 2449 (1887); 21, 1478 (1888). D. Dennstedt, Chem. Ber. 23, 1370 (1890). V. V. Chelintzev and B. V. Tronov, J. Russ. Phys. Chem. Soc. 48, 105 and 127 (1916). Th. Sabalitschka and H. Haase, Arch. Pharm. 226, 484 (1928). P. Rothemund and C. L. Gage, J. Am. Chem. Soc. 77, 3340 (1955).
12. H. Fischer and H. Orth, Die Chemie des Pyrrols, p 20, Akademische Verlagsgesellschaft, Leipzig (1934). M. Dennstedt and J. Zimmermann, Chem. Ber. 20, 850 and 2449 (1887); 21, 1478 (1888). D. Dennstedt, Chem. Ber. 23, 1370 (1890). V. V. Chelintzev and B. V. Tronov, J. Russ. Phys. Chem. Soc. 48, 105 and 127 (1916). Th. Sabalitschka and H. Haase, Arch. Pharm. 226, 484 (1928). P. Rothemund and C. L. Gage, J. Am. Chem. Soc. 77, 3340 (1955).
13. H. Fischer and H. Orth, Die Chemie des Pyrrols, p 20, Akademische Verlagsgesellschaft, Leipzig (1934). M. Dennstedt and J. Zimmermann, Chem. Ber. 20, 850 and 2449 (1887); 21, 1478 (1888). D. Dennstedt, Chem. Ber. 23, 1370 (1890). V. V. Chelintzev and B. V. Tronov, J. Russ. Phys. Chem. Soc. 48, 105 and 127 (1916). Th. Sabalitschka and H. Haase, Arch. Pharm. 226, 484 (1928). P. Rothemund and C. L. Gage, J. Am. Chem. Soc. 77, 3340 (1955).
14. H. Fischer and H. Orth, Die Chemie des Pyrrols, p 20, Akademische Verlagsgesellschaft, Leipzig (1934). M. Dennstedt and J. Zimmermann, Chem. Ber. 20, 850 and 2449 (1887); 21, 1478 (1888). D. Dennstedt, Chem. Ber. 23, 1370 (1890). V. V. Chelintzev and B. V. Tronov, J. Russ. Phys. Chem. Soc. 48, 105 and 127 (1916). Th. Sabalitschka and H. Haase, Arch. Pharm. 226, 484 (1928). P. Rothemund and C. L. Gage, J. Am. Chem. Soc. 77, 3340 (1955).
15. D. Jacoby, C. Floriani, A. Chiesi-Villa and C. Rizzoli, J. Chem. Soc., Chem. Commun. 220 (1991). J. Jubb, D. Jacoby, C. Floriani, A. Chiesi-Villa and C. Rizzoli, Inorg. Chem. 31, 1306 (1992). E. Solari, F. Musso, C. Floriani, A. Chiesi-Villa and C. Rizzoli J. Chem. Soc., Dalton Trans. 2015 (1994).
16. D. Jacoby, C. Floriani, A. Chiesi-Villa and C. Rizzoli, J. Chem. Soc., Chem. Commun. 220 (1991). J. Jubb, D. Jacoby, C. Floriani, A. Chiesi-Villa and C. Rizzoli, Inorg. Chem. 31, 1306 (1992). E. Solari, F. Musso, C. Floriani, A. Chiesi-Villa and C. Rizzoli J. Chem. Soc., Dalton Trans. 2015 (1994).
17. D. Jacoby, C. Floriani, A. Chiesi-Villa and C. Rizzoli, J. Chem. Soc., Chem. Commun. 220 (1991). J. Jubb, D. Jacoby, C. Floriani, A. Chiesi-Villa and C. Rizzoli, Inorg. Chem. 31, 1306 (1992). E. Solari, F. Musso, C. Floriani, A. Chiesi-Villa and C. Rizzoli J. Chem. Soc., Dalton Trans. 2015 (1994).
18. (a) D. Jacoby, C. Floriani, A. Chiesi-Villa and C. Rizzoli, J. Chem. Soc., Chem. Commun. 790 (1991).
19. (b) D. Jacoby, C. Floriani, A. Chiesi-Villa and C. Rizzoli, J. Am. Chem. Soc. 115, 3595 (1993).
20. (c) A. Rosa, G. Ricciardi, M. Rosi, A. Sgamellotti and C. Floriani, J. Chem. Soc., Dalton Trans. 3759 (1993).
21. (d) D. Jacoby, S. Isoz, C. Floriani, K. Schenk, A. Chiesi-Villa and C. Rizzoli, Organometallics, in press,
22. (e) S. De Angelis, E. Solari, C. Floriani, A. Chiesi-Villa and C. Rizzoli, Organometallics, in press.
23. U. Piarulli, C. Floriani, A. Chiesi-Villa and C. Rizzoli J. Chem. Soc., Chem. Commun. 895 (1994). S. De Angelis, E. Solari, C. Floriani, A. Chiesi-Villa and C. Rizzoli, J Am. Chem. Soc, 116, 5691 and 5702 (1994). C. Floriani In Transition Metals in Supramolecular Chemistry, L. Fabbrizzi and A. Poggi, Eds., p. 191-209, Nato ASI Series, Kluwer, Dordrecht (1994).
24. U. Piarulli, C. Floriani, A. Chiesi-Villa and C. Rizzoli J. Chem. Soc., Chem. Commun. 895 (1994). S. De Angelis, E. Solari, C. Floriani, A. Chiesi-Villa and C. Rizzoli, J Am. Chem. Soc, 116, 5691 and 5702 (1994). C. Floriani In Transition Metals in Supramolecular Chemistry, L. Fabbrizzi and A. Poggi, Eds., p. 191-209, Nato ASI Series, Kluwer, Dordrecht (1994).
25. U. Piarulli, C. Floriani, A. Chiesi-Villa and C. Rizzoli J. Chem. Soc., Chem. Commun. 895 (1994). S. De Angelis, E. Solari, C. Floriani, A. Chiesi-Villa and C. Rizzoli, J Am. Chem. Soc, 116, 5691 and 5702 (1994). C. Floriani In Transition Metals in Supramolecular Chemistry, L. Fabbrizzi and A. Poggi, Eds., p. 191-209, Nato ASI Series, Kluwer, Dordrecht (1994).
26. (a) D. Jacoby, C. Floriani, A. Chiesi-Villa and C. Rizzoli. J. Am. Chem. Soc. 115, 7025 (1993).
27. (b) D. Jacoby. S. Isoz, C. Floriani. A. Chiesi-Villa, and C. Rizzoli J. Am. Chem. Soc. 117, 2793 (1995).
28. (c) C. Floriani In Stereoselective Reactions of Metal-Activated Molecules, H. Werner and J. Sundermeyer, Eds., p. 97-106, Vieweg, Wiesbaden (1995).
29. C. M. Kretz, E. Gallo, E. Solari, C. Floriani, A. Chiesi-Villa and C. Rizzoli, J. Am. Chem. Soc. 116, 10775 (1994). D. Jacoby, S. Isoz, C. Floriani, A. Chiesi-Villa and C. Rizzoli, J. Am. Chem. Soc. 117, 2805 (1995). S. De Angelis, E. Solari, C. Floriani, A. Chiesi-Villa and C. Rizzoli, Angew. Chem., Int. Ed. Engl. 34, 1092 (1995).
30. C. M. Kretz, E. Gallo, E. Solari, C. Floriani, A. Chiesi-Villa and C. Rizzoli, J. Am. Chem. Soc. 116, 10775 (1994). D. Jacoby, S. Isoz, C. Floriani, A. Chiesi-Villa and C. Rizzoli, J. Am. Chem. Soc. 117, 2805 (1995). S. De Angelis, E. Solari, C. Floriani, A. Chiesi-Villa and C. Rizzoli, Angew. Chem., Int. Ed. Engl. 34, 1092 (1995).
31. C. M. Kretz, E. Gallo, E. Solari, C. Floriani, A. Chiesi-Villa and C. Rizzoli, J. Am. Chem. Soc. 116, 10775 (1994). D. Jacoby, S. Isoz, C. Floriani, A. Chiesi-Villa and C. Rizzoli, J. Am. Chem. Soc. 117, 2805 (1995). S. De Angelis, E. Solari, C. Floriani, A. Chiesi-Villa and C. Rizzoli, Angew. Chem., Int. Ed. Engl. 34, 1092 (1995).
32. S. De Angelis, E. Solari, C. Floriani, A. Chiesi-Villa and C. Rizzoli, J. Chem. Soc., Dalton Trans. 2467 (1994).
33. D. J. Cardin, M. F. Lappert and C. L. Raston, Chemistry of Organozirconium and Hafnium Compounds, Wiley, New York (1986). S. L. Buchwald and R. B. Nielsen, Chem. Rev. 88, 1047 (1988). E.-I. Negishi In Comprehensive Organic Synthesis, L. A. Paquette, Ed., Vol. 5, p. 1163, Pergamon, Oxford (1991). E.-I. Negishi and T. Takahashi, Acc. Chem. Res. 27, 124 (1994) and references therein. N. E. Schore In Comprehensive Organic Synthesis, L. A. Paquette, Ed., Vol. 5, p 1037, Pergamon, Oxford (1991). G. Erker, C. Krüger and G. Müller, Adv. Organomet. Chem. 24, 1 (1985) and references therein. R. F. Jordan, Adv. Organomet. Chem. 32, 325 (1991).
34. D. J. Cardin, M. F. Lappert and C. L. Raston, Chemistry of Organozirconium and Hafnium Compounds, Wiley, New York (1986). S. L. Buchwald and R. B. Nielsen, Chem. Rev. 88, 1047 (1988). E.-I. Negishi In Comprehensive Organic Synthesis, L. A. Paquette, Ed., Vol. 5, p. 1163, Pergamon, Oxford (1991). E.-I. Negishi and T. Takahashi, Acc. Chem. Res. 27, 124 (1994) and references therein. N. E. Schore In Comprehensive Organic Synthesis, L. A. Paquette, Ed., Vol. 5, p 1037, Pergamon, Oxford (1991). G. Erker, C. Krüger and G. Müller, Adv. Organomet. Chem. 24, 1 (1985) and references therein. R. F. Jordan, Adv. Organomet. Chem. 32, 325 (1991).
35. D. J. Cardin, M. F. Lappert and C. L. Raston, Chemistry of Organozirconium and Hafnium Compounds, Wiley, New York (1986). S. L. Buchwald and R. B. Nielsen, Chem. Rev. 88, 1047 (1988). E.-I. Negishi In Comprehensive Organic Synthesis, L. A. Paquette, Ed., Vol. 5, p. 1163, Pergamon, Oxford (1991). E.-I. Negishi and T. Takahashi, Acc. Chem. Res. 27, 124 (1994) and references therein. N. E. Schore In Comprehensive Organic Synthesis, L. A. Paquette, Ed., Vol. 5, p 1037, Pergamon, Oxford (1991). G. Erker, C. Krüger and G. Müller, Adv. Organomet. Chem. 24, 1 (1985) and references therein. R. F. Jordan, Adv. Organomet. Chem. 32, 325 (1991).
36. D. J. Cardin, M. F. Lappert and C. L. Raston, Chemistry of Organozirconium and Hafnium Compounds, Wiley, New York (1986). S. L. Buchwald and R. B. Nielsen, Chem. Rev. 88, 1047 (1988). E.-I. Negishi In Comprehensive Organic Synthesis, L. A. Paquette, Ed., Vol. 5, p. 1163, Pergamon, Oxford (1991). E.-I. Negishi and T. Takahashi, Acc. Chem. Res. 27, 124 (1994) and references therein. N. E. Schore In Comprehensive Organic Synthesis, L. A. Paquette, Ed., Vol. 5, p 1037, Pergamon, Oxford (1991). G. Erker, C. Krüger and G. Müller, Adv. Organomet. Chem. 24, 1 (1985) and references therein. R. F. Jordan, Adv. Organomet. Chem. 32, 325 (1991).
37. D. J. Cardin, M. F. Lappert and C. L. Raston, Chemistry of Organozirconium and Hafnium Compounds, Wiley, New York (1986). S. L. Buchwald and R. B. Nielsen, Chem. Rev. 88, 1047 (1988). E.-I. Negishi In Comprehensive Organic Synthesis, L. A. Paquette, Ed., Vol. 5, p. 1163, Pergamon, Oxford (1991). E.-I. Negishi and T. Takahashi, Acc. Chem. Res. 27, 124 (1994) and references therein. N. E. Schore In Comprehensive Organic Synthesis, L. A. Paquette, Ed., Vol. 5, p 1037, Pergamon, Oxford (1991). G. Erker, C. Krüger and G. Müller, Adv. Organomet. Chem. 24, 1 (1985) and references therein. R. F. Jordan, Adv. Organomet. Chem. 32, 325 (1991).
38. D. J. Cardin, M. F. Lappert and C. L. Raston, Chemistry of Organozirconium and Hafnium Compounds, Wiley, New York (1986). S. L. Buchwald and R. B. Nielsen, Chem. Rev. 88, 1047 (1988). E.-I. Negishi In Comprehensive Organic Synthesis, L. A. Paquette, Ed., Vol. 5, p. 1163, Pergamon, Oxford (1991). E.-I. Negishi and T. Takahashi, Acc. Chem. Res. 27, 124 (1994) and references therein. N. E. Schore In Comprehensive Organic Synthesis, L. A. Paquette, Ed., Vol. 5, p 1037, Pergamon, Oxford (1991). G. Erker, C. Krüger and G. Müller, Adv. Organomet. Chem. 24, 1 (1985) and references therein. R. F. Jordan, Adv. Organomet. Chem. 32, 325 (1991).
39. D. J. Cardin, M. F. Lappert and C. L. Raston, Chemistry of Organozirconium and Hafnium Compounds, Wiley, New York (1986). S. L. Buchwald and R. B. Nielsen, Chem. Rev. 88, 1047 (1988). E.-I. Negishi In Comprehensive Organic Synthesis, L. A. Paquette, Ed., Vol. 5, p. 1163, Pergamon, Oxford (1991). E.-I. Negishi and T. Takahashi, Acc. Chem. Res. 27, 124 (1994) and references therein. N. E. Schore In Comprehensive Organic Synthesis, L. A. Paquette, Ed., Vol. 5, p 1037, Pergamon, Oxford (1991). G. Erker, C. Krüger and G. Müller, Adv. Organomet. Chem. 24, 1 (1985) and references therein. R. F. Jordan, Adv. Organomet. Chem. 32, 325 (1991).
40. M. Schlosser, Organoalkali Reagents In Organometallics in Synthesis, M. Schlosser, Ed., Chapter 1, Wiley, New York (1994).
41. (b) As a general reference to organoalkali metal complexes: E. Weiss, Angew. Chem., Int. Ed. Engl. 32, 1501 (1993).
42. J. Schwartz and J. A. Labinger, Angew. Chem., Int. Ed. Engl. 15, 333 (1976). E.-I. Neghishi and T. Takahashi, Aldrichimica Acta 18, 31 (1985). D. J. Cardin, M. F. Lappert and C. L. Raston, In Comprehensive Organometallic Chemistry, G. Wilkinson, F. G. A. Stone and E. W. Abel, Eds., Vol. 3; Chapter 23.2, p 45, Pergamon, Oxford (1981). J. Schwartz, Pure Appl. Chem. 52, 733 (1980).
43. J. Schwartz and J. A. Labinger, Angew. Chem., Int. Ed. Engl. 15, 333 (1976). E.-I. Neghishi and T. Takahashi, Aldrichimica Acta 18, 31 (1985). D. J. Cardin, M. F. Lappert and C. L. Raston, In Comprehensive Organometallic Chemistry, G. Wilkinson, F. G. A. Stone and E. W. Abel, Eds., Vol. 3; Chapter 23.2, p 45, Pergamon, Oxford (1981). J. Schwartz, Pure Appl. Chem. 52, 733 (1980).
44. J. Schwartz and J. A. Labinger, Angew. Chem., Int. Ed. Engl. 15, 333 (1976). E.-I. Neghishi and T. Takahashi, Aldrichimica Acta 18, 31 (1985). D. J. Cardin, M. F. Lappert and C. L. Raston, In Comprehensive Organometallic Chemistry, G. Wilkinson, F. G. A. Stone and E. W. Abel, Eds., Vol. 3; Chapter 23.2, p 45, Pergamon, Oxford (1981). J. Schwartz, Pure Appl. Chem. 52, 733 (1980).
45. J. Schwartz and J. A. Labinger, Angew. Chem., Int. Ed. Engl. 15, 333 (1976). E.-I. Neghishi and T. Takahashi, Aldrichimica Acta 18, 31 (1985). D. J. Cardin, M. F. Lappert and C. L. Raston, In Comprehensive Organometallic Chemistry, G. Wilkinson, F. G. A. Stone and E. W. Abel, Eds., Vol. 3; Chapter 23.2, p 45, Pergamon, Oxford (1981). J. Schwartz, Pure Appl. Chem. 52, 733 (1980).
46. For a general review on the homologation reaction of alcohols and related species, see: G. P. Chiusoli, G. Salerno and M. Foa, In Reactions of Coordinated Ligands, P. S. Braterman, Ed., Vol. 1, Chapter 7, Plenum, New York (1986). G. W. Parshall and S. D. Ittel, Homogeneous Catalysis, 2nd ed.; Wiley, New York (1992). H. M. Colquhoun, D. J. Thompson and M. V. Twigg, Carbonylation, Plenum, New York (1991).
47. For a general review on the homologation reaction of alcohols and related species, see: G. P. Chiusoli, G. Salerno and M. Foa, In Reactions of Coordinated Ligands, P. S. Braterman, Ed., Vol. 1, Chapter 7, Plenum, New York (1986). G. W. Parshall and S. D. Ittel, Homogeneous Catalysis, 2nd ed.; Wiley, New York (1992). H. M. Colquhoun, D. J. Thompson and M. V. Twigg, Carbonylation, Plenum, New York (1991).
48. For a general review on the homologation reaction of alcohols and related species, see: G. P. Chiusoli, G. Salerno and M. Foa, In Reactions of Coordinated Ligands, P. S. Braterman, Ed., Vol. 1, Chapter 7, Plenum, New York (1986). G. W. Parshall and S. D. Ittel, Homogeneous Catalysis, 2nd ed.; Wiley, New York (1992). H. M. Colquhoun, D. J. Thompson and M. V. Twigg, Carbonylation, Plenum, New York (1991).
49. L. D. Durfee and I. P. Rothwell, Chem. Rev. 88, 1059 (1988). P. T. Wolczanski and J. E. Bercaw, Acc. Chem. Res. 13, 121 (1980). C. E. L. Headford and W. R. Roper, In Reactions of Coordinated Ligands, P.S. Braterman, Ed., Vol. 1, Ch. 8, Plenum, New York (1986). J. A. Labinger, Transition Metal Hydrides, A. Dedieu, Ed., VCH, Weinheim, Germany (1992).
50. L. D. Durfee and I. P. Rothwell, Chem. Rev. 88, 1059 (1988). P. T. Wolczanski and J. E. Bercaw, Acc. Chem. Res. 13, 121 (1980). C. E. L. Headford and W. R. Roper, In Reactions of Coordinated Ligands, P.S. Braterman, Ed., Vol. 1, Ch. 8, Plenum, New York (1986). J. A. Labinger, Transition Metal Hydrides, A. Dedieu, Ed., VCH, Weinheim, Germany (1992).
51. L. D. Durfee and I. P. Rothwell, Chem. Rev. 88, 1059 (1988). P. T. Wolczanski and J. E. Bercaw, Acc. Chem. Res. 13, 121 (1980). C. E. L. Headford and W. R. Roper, In Reactions of Coordinated Ligands, P.S. Braterman, Ed., Vol. 1, Ch. 8, Plenum, New York (1986). J. A. Labinger, Transition Metal Hydrides, A. Dedieu, Ed., VCH, Weinheim, Germany (1992).
52. L. D. Durfee and I. P. Rothwell, Chem. Rev. 88, 1059 (1988). P. T. Wolczanski and J. E. Bercaw, Acc. Chem. Res. 13, 121 (1980). C. E. L. Headford and W. R. Roper, In Reactions of Coordinated Ligands, P.S. Braterman, Ed., Vol. 1, Ch. 8, Plenum, New York (1986). J. A. Labinger, Transition Metal Hydrides, A. Dedieu, Ed., VCH, Weinheim, Germany (1992).
53. R. L. Miller, P. T. Wolczanski and A. L. Rheingold, J. Am. Chem. Soc. 115, 10422 (1993) and references therein. M. H. Chisholm, C. E. Hammond, V. J. Johnston, W. E. Streib and J. C. Huffman, J. Am. Chem. Soc. 114, 7056 (1992). B. C. Bates, Angew. Chem., Int. Ed. Engl. 32, 228 (1993).
54. R. L. Miller, P. T. Wolczanski and A. L. Rheingold, J. Am. Chem. Soc. 115, 10422 (1993) and references therein. M. H. Chisholm, C. E. Hammond, V. J. Johnston, W. E. Streib and J. C. Huffman, J. Am. Chem. Soc. 114, 7056 (1992). B. C. Bates, Angew. Chem., Int. Ed. Engl. 32, 228 (1993).
55. R. L. Miller, P. T. Wolczanski and A. L. Rheingold, J. Am. Chem. Soc. 115, 10422 (1993) and references therein. M. H. Chisholm, C. E. Hammond, V. J. Johnston, W. E. Streib and J. C. Huffman, J. Am. Chem. Soc. 114, 7056 (1992). B. C. Bates, Angew. Chem., Int. Ed. Engl. 32, 228 (1993).
56. K. Tatsumi, A. Nakamura, P. Hofmann, P. Stauffert and R. Hoffmann, J. Am. Chem. Soc. 107, 4440 (1985). B. D. Martin, S. A. Matchett, J. R. Norton and O. P. Anderson, J. Am. Chem. Soc. 107, 7952 (1985). D. M. Roddick and J. E. Bercaw, Chem. Ber. 122, 1579 (1989). P. Hofmann, P. Stauffert, M. Frede and K. Tatsumi, Chem. Ber. 122, 1559 (1989). P. Hofmann, P. Stauffert, K. Tatsumi, A. Nakamura and R. Hoffmann, Organometallics 4, 404 (1985). K. Tatsumi, A. Nakamura, P. Hofmann, R. Hoffmann, K. G. Moloy and T. J. Marks, J. Am. Chem. Soc. 108, 4467 (1986).
57. K. Tatsumi, A. Nakamura, P. Hofmann, P. Stauffert and R. Hoffmann, J. Am. Chem. Soc. 107, 4440 (1985). B. D. Martin, S. A. Matchett, J. R. Norton and O. P. Anderson, J. Am. Chem. Soc. 107, 7952 (1985). D. M. Roddick and J. E. Bercaw, Chem. Ber. 122, 1579 (1989). P. Hofmann, P. Stauffert, M. Frede and K. Tatsumi, Chem. Ber. 122, 1559 (1989). P. Hofmann, P. Stauffert, K. Tatsumi, A. Nakamura and R. Hoffmann, Organometallics 4, 404 (1985). K. Tatsumi, A. Nakamura, P. Hofmann, R. Hoffmann, K. G. Moloy and T. J. Marks, J. Am. Chem. Soc. 108, 4467 (1986).
58. K. Tatsumi, A. Nakamura, P. Hofmann, P. Stauffert and R. Hoffmann, J. Am. Chem. Soc. 107, 4440 (1985). B. D. Martin, S. A. Matchett, J. R. Norton and O. P. Anderson, J. Am. Chem. Soc. 107, 7952 (1985). D. M. Roddick and J. E. Bercaw, Chem. Ber. 122, 1579 (1989). P. Hofmann, P. Stauffert, M. Frede and K. Tatsumi, Chem. Ber. 122, 1559 (1989). P. Hofmann, P. Stauffert, K. Tatsumi, A. Nakamura and R. Hoffmann, Organometallics 4, 404 (1985). K. Tatsumi, A. Nakamura, P. Hofmann, R. Hoffmann, K. G. Moloy and T. J. Marks, J. Am. Chem. Soc. 108, 4467 (1986).
59. K. Tatsumi, A. Nakamura, P. Hofmann, P. Stauffert and R. Hoffmann, J. Am. Chem. Soc. 107, 4440 (1985). B. D. Martin, S. A. Matchett, J. R. Norton and O. P. Anderson, J. Am. Chem. Soc. 107, 7952 (1985). D. M. Roddick and J. E. Bercaw, Chem. Ber. 122, 1579 (1989). P. Hofmann, P. Stauffert, M. Frede and K. Tatsumi, Chem. Ber. 122, 1559 (1989). P. Hofmann, P. Stauffert, K. Tatsumi, A. Nakamura and R. Hoffmann, Organometallics 4, 404 (1985). K. Tatsumi, A. Nakamura, P. Hofmann, R. Hoffmann, K. G. Moloy and T. J. Marks, J. Am. Chem. Soc. 108, 4467 (1986).
60. K. Tatsumi, A. Nakamura, P. Hofmann, P. Stauffert and R. Hoffmann, J. Am. Chem. Soc. 107, 4440 (1985). B. D. Martin, S. A. Matchett, J. R. Norton and O. P. Anderson, J. Am. Chem. Soc. 107, 7952 (1985). D. M. Roddick and J. E. Bercaw, Chem. Ber. 122, 1579 (1989). P. Hofmann, P. Stauffert, M. Frede and K. Tatsumi, Chem. Ber. 122, 1559 (1989). P. Hofmann, P. Stauffert, K. Tatsumi, A. Nakamura and R. Hoffmann, Organometallics 4, 404 (1985). K. Tatsumi, A. Nakamura, P. Hofmann, R. Hoffmann, K. G. Moloy and T. J. Marks, J. Am. Chem. Soc. 108, 4467 (1986).
61. K. Tatsumi, A. Nakamura, P. Hofmann, P. Stauffert and R. Hoffmann, J. Am. Chem. Soc. 107, 4440 (1985). B. D. Martin, S. A. Matchett, J. R. Norton and O. P. Anderson, J. Am. Chem. Soc. 107, 7952 (1985). D. M. Roddick and J. E. Bercaw, Chem. Ber. 122, 1579 (1989). P. Hofmann, P. Stauffert, M. Frede and K. Tatsumi, Chem. Ber. 122, 1559 (1989). P. Hofmann, P. Stauffert, K. Tatsumi, A. Nakamura and R. Hoffmann, Organometallics 4, 404 (1985). K. Tatsumi, A. Nakamura, P. Hofmann, R. Hoffmann, K. G. Moloy and T. J. Marks, J. Am. Chem. Soc. 108, 4467 (1986).
62. R. L. Jones and C. W. Rees, J. Chem. Soc. C 2249 and 2255 (1969) and references therein. F. W. Fowler, Angew. Chem., Int. Ed. Engl. 10, 135 (1971).
63. R. L. Jones and C. W. Rees, J. Chem. Soc. C 2249 and 2255 (1969) and references therein. F. W. Fowler, Angew. Chem., Int. Ed. Engl. 10, 135 (1971).
64. P. E. Fanwick, L. M. Kobriger, A. K. McMullen and I. P. Rothwell, J. Am. Chem. Soc. 108, 8095 (1986). J. Arnold, T. D. Tilley and A. L. Rheingold, J. Am. Chem. Soc. 108, 5355 (1986).
65. P. E. Fanwick, L. M. Kobriger, A. K. McMullen and I. P. Rothwell, J. Am. Chem. Soc. 108, 8095 (1986). J. Arnold, T. D. Tilley and A. L. Rheingold, J. Am. Chem. Soc. 108, 5355 (1986).
66. W. A. Howard, M. Waters and G. Parkin, J. Am. Chem. Soc. 115, 4917 (1993).
67. J. A. Davies, P. L. Watson, J. F. Liebman and A. Greenberg, Selective Hydrocarbon Activation, VCH, New York (1990). Activation and Functionalization of Alkanes, C. L. Hill, Ed., Wiley, New York (1989). A. E. Shilov, Activation of Saturated Hydrocarbons by Transition Metal Complexes, Reidel, Ingham, MA (1984). W. D. Jones and F. J. Feher, Acc. Chem. Res. 2, 91 (1989). A. D. Ryabov, Chem. Rev. 90, 403 (1990). A. Sen, Ace. Chem. Res. 21, 421 (1988). R. H. Crabtree, Chem. Rev. 85, 245 (1985).
68. J. A. Davies, P. L. Watson, J. F. Liebman and A. Greenberg, Selective Hydrocarbon Activation, VCH, New York (1990). Activation and Functionalization of Alkanes, C. L. Hill, Ed., Wiley, New York (1989). A. E. Shilov, Activation of Saturated Hydrocarbons by Transition Metal Complexes, Reidel, Ingham, MA (1984). W. D. Jones and F. J. Feher, Acc. Chem. Res. 2, 91 (1989). A. D. Ryabov, Chem. Rev. 90, 403 (1990). A. Sen, Ace. Chem. Res. 21, 421 (1988). R. H. Crabtree, Chem. Rev. 85, 245 (1985).
69. J. A. Davies, P. L. Watson, J. F. Liebman and A. Greenberg, Selective Hydrocarbon Activation, VCH, New York (1990). Activation and Functionalization of Alkanes, C. L. Hill, Ed., Wiley, New York (1989). A. E. Shilov, Activation of Saturated Hydrocarbons by Transition Metal Complexes, Reidel, Ingham, MA (1984). W. D. Jones and F. J. Feher, Acc. Chem. Res. 2, 91 (1989). A. D. Ryabov, Chem. Rev. 90, 403 (1990). A. Sen, Ace. Chem. Res. 21, 421 (1988). R. H. Crabtree, Chem. Rev. 85, 245 (1985).
70. J. A. Davies, P. L. Watson, J. F. Liebman and A. Greenberg, Selective Hydrocarbon Activation, VCH, New York (1990). Activation and Functionalization of Alkanes, C. L. Hill, Ed., Wiley, New York (1989). A. E. Shilov, Activation of Saturated Hydrocarbons by Transition Metal Complexes, Reidel, Ingham, MA (1984). W. D. Jones and F. J. Feher, Acc. Chem. Res. 2, 91 (1989). A. D. Ryabov, Chem. Rev. 90, 403 (1990). A. Sen, Ace. Chem. Res. 21, 421 (1988). R. H. Crabtree, Chem. Rev. 85, 245 (1985).
71. J. A. Davies, P. L. Watson, J. F. Liebman and A. Greenberg, Selective Hydrocarbon Activation, VCH, New York (1990). Activation and Functionalization of Alkanes, C. L. Hill, Ed., Wiley, New York (1989). A. E. Shilov, Activation of Saturated Hydrocarbons by Transition Metal Complexes, Reidel, Ingham, MA (1984). W. D. Jones and F. J. Feher, Acc. Chem. Res. 2, 91 (1989). A. D. Ryabov, Chem. Rev. 90, 403 (1990). A. Sen, Ace. Chem. Res. 21, 421 (1988). R. H. Crabtree, Chem. Rev. 85, 245 (1985).
72. J. A. Davies, P. L. Watson, J. F. Liebman and A. Greenberg, Selective Hydrocarbon Activation, VCH, New York (1990). Activation and Functionalization of Alkanes, C. L. Hill, Ed., Wiley, New York (1989). A. E. Shilov, Activation of Saturated Hydrocarbons by Transition Metal Complexes, Reidel, Ingham, MA (1984). W. D. Jones and F. J. Feher, Acc. Chem. Res. 2, 91 (1989). A. D. Ryabov, Chem. Rev. 90, 403 (1990). A. Sen, Ace. Chem. Res. 21, 421 (1988). R. H. Crabtree, Chem. Rev. 85, 245 (1985).
73. J. A. Davies, P. L. Watson, J. F. Liebman and A. Greenberg, Selective Hydrocarbon Activation, VCH, New York (1990). Activation and Functionalization of Alkanes, C. L. Hill, Ed., Wiley, New York (1989). A. E. Shilov, Activation of Saturated Hydrocarbons by Transition Metal Complexes, Reidel, Ingham, MA (1984). W. D. Jones and F. J. Feher, Acc. Chem. Res. 2, 91 (1989). A. D. Ryabov, Chem. Rev. 90, 403 (1990). A. Sen, Ace. Chem. Res. 21, 421 (1988). R. H. Crabtree, Chem. Rev. 85, 245 (1985).
74. B. von Maltzan, Angew. Chem., Int. Ed. Engl. 21, 785 (1982). C. D. Gutsche, Calixarenes, Royal Society of Chemistry, Cambridge, U. K. (1989).
75. B. von Maltzan, Angew. Chem., Int. Ed. Engl. 21, 785 (1982). C. D. Gutsche, Calixarenes, Royal Society of Chemistry, Cambridge, U. K. (1989).
76. M. J. Evans, H. J. Meadows and P. T. Hanusa, J. Am. Chem. Soc. 106, 4454 (1984). P. C. Wailes, H. Weigold and A. P. Bell, J. Organometal. Chem. 43, C29 (1972).
77. M. J. Evans, H. J. Meadows and P. T. Hanusa, J. Am. Chem. Soc. 106, 4454 (1984). P. C. Wailes, H. Weigold and A. P. Bell, J. Organometal. Chem. 43, C29 (1972).